Transparent film, polarizing plate, and image displaying device

Patent metadata

Field	Value
Publication number	US-10585225-B2
Application number	US-201715726881-A
Country	US
Kind code	B2
Filing date	Oct 6, 2017
Priority date	Apr 10, 2015
Publication date	Mar 10, 2020
Grant date	Mar 10, 2020

Abstract

A transparent film includes: a base material; and at least one scratch resistant layer of which indentation hardness is 300 MPa or greater and of which a thickness is 50 to 1,000 nm on an outermost surface of the transparent film at one side or both sides of the base material, and a number of times of folding endurance of the transparent film measured by an MIT testing machine according to JIS P8115 (2001) is 1,000 times or greater.

First claim

What is claimed is:

1. A transparent film comprising:
a base material; and
at least one scratch resistant layer of which indentation hardness is 300 MPa or greater and of which a thickness is 50 to 1,000 nm on an outermost surface of the transparent film at one side or both sides of the base material,
wherein a number of times of folding endurance of the transparent film measured by an MIT testing machine according to Japanese Industrial Standards (JIS) P8115 (2001) is 1,000 times or greater,
wherein the scratch resistant layer comprises fine particles having a polygonal surface,
wherein a thickness of a fine particle of the fine particles is 50% or less of a thickness of the scratch resistant layer, and the particle size of the fine particles is 100 nm to 1,000 nm in a case where the particle size of the fine particles is converted into a diameter of a virtual circle having a smallest area among a plurality of virtual circles which pass through two arbitrary vertices of a projection portion obtained by projecting the polygonal surface of the fine particles in a direction in which a projection area becomes a maximum and includes the projection portion within the virtual circles, and
wherein the fine particles at least exist in an outermost surface area of the transparent film.

2. The transparent film according to claim 1 ,
wherein the scratch resistant layer comprises the fine particles and a binder resin.

3. The transparent film according to claim 2 ,
wherein a shortest distance between end portions of the adjacent ones of the fine particles at an outermost surface of the transparent film is 1 nm to 12 μm.

4. The transparent film according to claim 2 ,
wherein a dispersion degree of an average primary particle diameter of the fine particles is 10% or less.

5. The transparent film according to claim 2 , further comprising:
a relaxation layer between the scratch resistant layer and the base material.

6. The transparent film according to claim 1 ,
wherein the scratch resistant layer comprises the fine particles having indentation hardness of 400 MPa or greater, and a binder resin.

7. The transparent film according to claim 6 ,
wherein a shortest distance between end portions of the adjacent ones of the fine particles at an outermost surface of the transparent film is 1 nm to 12 μm.

8. The transparent film according to claim 6 ,
wherein a thickness of the base material is 50 μm or less, in a case where the fine particle having the polygonal surface is sandwiched between the virtual circle and a virtual plane parallel to the virtual circle and a distance between the virtual circle and the virtual plane is defined as the thickness of the fine particle, the fine particles are unevenly distributed in the outermost surface area of the transparent film, and a ratio of an area occupied by the fine particles to an area of the outermost surface of the transparent film is 30% or greater.

9. The transparent film according to claim 6 , further comprising:
a relaxation layer between the scratch resistant layer and the base material.

10. The transparent film according to claim 1 ,
wherein the scratch resistant layer comprises 80 mass % or greater of a cured product of a cross-linking compound in which a number of crosslinking groups in one molecule is 3 or more with respect to a total mass of the scratch resistant layer, and the transparent film further comprises a relaxation layer between the scratch resistant layer and the base material.

11. The transparent film according to claim 1 ,
wherein the transparent film has resistance to repetitive bending in which the number of times of folding endurance measured by an MIT testing machine according to JIS P8115 (2001) is 10,000 times or greater.

12. The transparent film according to claim 1 ,
wherein a haze of the transparent film measured based on JIS-K7136 (2000) is 2.0% or less.

13. The transparent film according to claim 1 , further comprising:
a relaxation layer between the scratch resistant layer and the base material.

14. The transparent film according to claim 13 ,
wherein indentation hardness of the relaxation layer is smaller than indentation hardness of the scratch resistant layer.

15. A polarizing plate comprising:
the transparent film according to claim 1 on an outermost surface of the polarizing plate.

16. A polarizing plate comprising:
the transparent film according to claim 1 on an outermost surface of the polarizing plate;
a polarizer; and
a transparent base material having resistance to repetitive bending in which a number of times of folding endurance measured by an MIT testing machine according to JIS P8115 (2001) is 1,000 times or greater, on an opposite surface of the polarizing plate so that the transparent film, the polarizer and the transparent base material are provided in this order.

17. An image displaying device comprising:
the transparent film according to claim 1 .

18. An image displaying device comprising:
the transparent film according to claim 1 on an outermost surface of the image displaying device on a viewing side; and
a scratch resistant layer which is same as the scratch resistant layer of the transparent film, on an outermost surface of the image displaying device opposite to the viewing side.

19. A transparent film comprising:
a base material; and
at least one scratch resistant layer of which indentation hardness is 300 MPa or greater and of which a thickness is 50 to 1,000 nm on an outermost surface of the transparent film at one side or both sides of the base material,
wherein a number of times of folding endurance of the transparent film measured by an MIT testing machine according to Japanese Industrial Standards (JIS) P8115 (2001) is 1,000 times or greater, and
wherein the scratch resistant layer comprises fine particles of which an average primary particle diameter is 100 nm to 1,000 nm and of which indentation hardness is 400 MPa or greater, and a binder resin, and a thickness of a fine particle of the fine particles is 50% or less of a thickness of the scratch resistant layer.

20. A transparent film comprising:
a base material; and
at least one scratch resistant layer of which indentation hardness is 300 MPa or greater and of which a thickness is 50 to 1,000 nm on an outermost surface of the transparent film at one side or both sides of the base material,
wherein a number of times of folding endurance of the transparent film measured by an MIT testing machine according to Japanese Industrial Standards (JIS) P8115 (2001) is 1,000 times or greater, and
wherein the scratch resistant layer comprises 80 mass % or greater of a cured product of a cross-linking compound in which a number of crosslinking groups in one molecule is 3 or more with respect to a total mass of the scratch resistant layer, and the transparent film further comprises a relaxation layer between the scratch resistant layer and the base material.

Assignees

• Fujifilm Corp

Inventors

• Asahi Miho
• Matsumoto Ayako
• Ibuki Shuntaro
• Watanabe Shinya
• Nakayama Hajime
• Shibata Naoya

Classifications

• G02B1/14

  Protective coatings, e.g. hard coatings · CPC title

• B32B27/18

  characterised by the use of special additives · CPC title

• G02B5/3083

  Birefringent or phase retarding elements (G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001) · CPC title

• G02F1/133502

  Antiglare, refractive index matching layers · CPC title

• G02B5/3033 Primary

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title