Macroporous oxygen carrier solid with a refractory feldspar/feldspathoid, method for the preparation thereof, and use thereof in a chemical-looping oxidation-reduction method
US-2019381488-A1 · Dec 19, 2019 · US
US10584869B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10584869-B2 |
| Application number | US-201514809306-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 27, 2015 |
| Priority date | Jul 27, 2015 |
| Publication date | Mar 10, 2020 |
| Grant date | Mar 10, 2020 |
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A heater having a planar metal sheet with a first and second surface. A metal oxide layer is formed on the first surface of the sheet and a combustion catalyst is impregnated into the metal oxide layer. A source of fuel and air is then supplied to the first side of the metal sheet resulting in catalytic combustion which heats the metal sheet. The metal sheet can serve as a cooking stove.
Opening claim text (preview).
The invention claimed is: 1. A heater comprising: a metal sheet having a first and second surfaces, a porous metal oxide layer formed directly on said first surface of said metal sheet, a combustion catalyst impregnated within said porous metal oxide layer, the catalyst effecting flameless catalytic combustion, a source of fuel, and a chamber which the first surface faces, wherein fuel interacts with the catalyst in the porous metal oxide layer and undergoes flameless catalytic combustion which generates heat, wherein the second surface is an exterior surface where cooking takes places and heat generated by the flameless catalytic combustion at the first surface of the sheet is conductively transferred through the metal sheet to the second surface raising the temperature of the second surface to a temperature suitable for cooking food. 2. The heater as defined in claim 1 wherein said metal sheet comprises a sheet of titanium metal or aluminum metal. 3. The heater as defined in claim 1 wherein said porous metal oxide layer comprises an oxide of the same metal forming the metal sheet. 4. The heater as defined in claim 3 wherein said metal oxide layer is formed by anodization of the first surface of said metal sheet. 5. The heater as defined in claim 3 wherein said metal oxide layer is formed by cathodization of the first surface of said metal sheet. 6. The heater as defined in claim 1 wherein said catalyst comprises platinum metal or rhodium metal. 7. The heater as defined in claim 1 wherein said fuel comprises hydrocarbon fuel. 8. The heater as defined in claim 7 wherein said fuel comprises JP-8 jet fuel. 9. The heater as defined in claim 1 and comprising a housing, said metal sheet being supported by said housing, and a fuel passageway and air passageway being formed through said housing, each passageway having an outlet in the chamber open to a first side of said metal sheet. 10. The heater as defined in claim 9 and comprising a heating element attached to said housing and surrounding a portion of said passageways which preheats the air and vaporizes said fuel entering the chamber via said passageways. 11. The heater as defined in claim 1 wherein said heater is configured as a cooking stove. 12. The heater according to claim 5 where the cathodization occurs from about 4 to about 5 A/dm 2 for from about 80 to about 100 minutes with oxalic acid to form porosity in the metal oxide layer. 13. The heater as defined in claim 11 , wherein the catalytic combustion reduces or eliminates carbon monoxide emissions during cooking. 14. The heater as defined in claim 1 , further comprising: a housing including an upper ring and a lower ring separated from each other by a plurality of spacers which form a slot for exhaust gases around the housing. 15. The heater as defined in claim 14 , further comprising: a plurality of threaded fasteners, with one fastener extending through each spacer, to secure the upper and lower rings together. 16. The heater as defined in claim 10 , further comprising: a porous foam positioned in the chamber proximate to the outlets of said passageways, wherein air intermixes with the vaporized fuel in the porous foam. 17. The heater as defined in claim 16 , wherein air/fuel mixture after passing through the porous foam impinges against the porous metal oxide layer.
heated by electrical means · CPC title
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