Water pipe for mining operations

Patent metadata

Field	Value
Publication number	US-10584809-B2
Application number	US-201515768181-A
Country	US
Kind code	B2
Filing date	Oct 14, 2015
Priority date	Oct 14, 2015
Publication date	Mar 10, 2020
Grant date	Mar 10, 2020

Abstract

A water pipe for mining operations has an outer diameter of 20 to 200 millimeters and a wall thickness of 2 to 20 millimeters. The water pipe includes a composition containing 58 to 82 parts by weight poly(phenylene ether), 8 to 18 parts by weight of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene, 0 to 15 parts by weight of polystyrene selected from the group consisting of homopolystyrenes, rubber-modified polystyrenes, and combinations thereof, and 10 to 20 parts by weight of a flame retardant comprising an organophosphate ester, wherein parts by weight values are based on 100 parts by weight total of the poly(phenylene ether), the hydrogenated block copolymer, the polystyrene, and the flame retardant. The water pipe exhibits a desirable balance of impact strength, tensile strength, burst pressure resistance, static pressure resistance, and flame retardancy.

First claim

The invention claimed is:

1. A water pipe for mining operations
wherein the water pipe has an outer diameter of 20 to 200 millimeters and a wall thickness of 2 to 20 millimeters; and
wherein the water pipe comprises a composition comprising
58 to 82 parts by weight poly(phenylene ether),
8 to 18 parts by weight of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene,
0 to 15 parts by weight of polystyrene selected from the group consisting of homopolystyrenes, rubber-modified polystyrenes, and combinations thereof, and
10 to 20 parts by weight of a flame retardant comprising an organophosphate ester,

wherein parts by weight values are based on 100 parts by weight total of the poly(phenylene ether), the hydrogenated block copolymer, the polystyrene, and the flame retardant.

2. The water pipe of claim 1 , wherein the water pipe consists of the composition.

3. The water pipe of claim 1 , wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.4 to 0.5 deciliter per gram, determined by Ubbelohde viscometer at 25° C. in chloroform.

4. The water pipe of claim 1 , wherein the composition comprises 65 to 75 parts by weight of the poly(phenylene ether).

5. The water pipe of claim 1 , wherein the composition comprises 12 to 16 parts by weight of the hydrogenated block copolymer.

6. The water pipe of claim 1 , wherein the composition excludes the polystyrene.

7. The water pipe of claim 1 , wherein the flame retardant consists of the organophosphate ester.

8. The water pipe of claim 1 , wherein the organophosphate ester comprises bisphenol A bis(diphenyl phosphate).

9. The water pipe of claim 1 , wherein the composition consists of
58 to 82 parts by weight poly(phenylene ether),
8 to 18 parts by weight of the hydrogenated block copolymer,
0 to 15 parts by weight of the polystyrene selected from the group consisting of homopolystyrenes, rubber-modified polystyrenes, and combinations thereof,
10 to 20 parts by weight of the flame retardant, and
0 to 5 parts by weight of an additive selected from the group consisting of stabilizers, lubricants, processing aids, drip retardants, UV blockers, dyes, pigments, antioxidants, anti-static agents, mineral oil, metal deactivators, and combinations thereof.

10. The water pipe of claim 1 ,
wherein the water pipe consists of the composition;
wherein the poly(phenylene ether) comprises a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.4 to 0.5 deciliter per gram, determined by Ubbelohde viscometer at 25° C. in chloroform;
wherein the hydrogenated block copolymer is a polystyrene-poly(ethylene-propylene)-polystyrene triblock copolymer having a polystyrene content of 25 to 35 weight percent, based on the weight of the polystyrene-poly(ethylene-propylene)-polystyrene triblock copolymer, and wherein the polystyrene-poly(ethylene-propylene)-polystyrene triblock copolymer has a weight average molecular weight of 240,000 to 300,000 daltons, determined according to size exclusion chromatography using polystyrene standards;
wherein the flame retardant consists of the organophosphate ester, and wherein the organophosphate ester comprises bisphenol A bis(diphenyl phosphate); and
wherein the composition comprises
65 to 75 parts by weight of the poly(phenylene ether),
12 to 16 parts by weight of the hydrogenated block copolymer,
0 to 5 parts by weight of the polystyrene, and
12 to 16 parts by weight of the flame retardant.

11. The water pipe of claim 1 , wherein the hydrogenated block copolymer is a polystyrene-poly(ethylene-propylene)-polystyrene triblock copolymer having a polystyrene content of 25 to 35 weight percent, based on the weight of the polystyrene-poly(ethylene-propylene)-polystyrene triblock copolymer.

12. The water pipe of claim 11 , wherein the polystyrene-poly(ethylene-propylene)-polystyrene triblock copolymer has a weight average molecular weight of 240,000 to 300,000 daltons, determined by size exclusion chromatography using polystyrene standards.

13. The water pipe of claim 1 , wherein the composition comprises 1 to 15 parts by weight of the polystyrene.

14. The water pipe of claim 13 , wherein the polystyrene consists of the homopolystyrene.

15. The water pipe of claim 13 , wherein the polystyrene consists of the rubber-modified polystyrene.

16. The water pipe of claim 1 , wherein the pipe comprises a layer of the composition and an external layer surrounding and in contact with the layer of the composition.

17. The water pipe of claim 16 , wherein the external layer is a layer of a high-density polyethylene-based composition.

18. A water pipe for mining operations,
wherein the water pipe comprises a composition comprising
58 to 82 parts by weight poly(phenylene ether),
8 to 18 parts by weight of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene,
0 to 15 parts by weight of polystyrene selected from the group consisting of homopolystyrenes, rubber-modified polystyrenes, and combinations thereof, and
10 to 20 parts by weight of a flame retardant comprising an organophosphate ester,

wherein parts by weight values are based on 100 parts by weight total of the poly(phenylene ether), the hydrogenated block copolymer, the polystyrene, and the flame retardant.

Assignees

• Sabic Global Tech
• Sabic Global Technologies Bv

Inventors

• Chen Guangtao
• Na Ying
• Xu Yonglei

Classifications

• C08K5/521

  Esters of phosphoric acids, e.g. of H3PO4 · CPC title

• C08L25/10

  with conjugated dienes · CPC title

• C08L25/06

  Polystyrene · CPC title

• F16L9/12 Primary

  of plastics with or without reinforcement (F16L9/16 - F16L9/22 take precedence) · CPC title

• C08L53/025

  modified · CPC title