Modified HF alkylation reaction zone for ionic liquid alkylation

Patent metadata

Field	Value
Publication number	US-10584079-B2
Application number	US-201815877988-A
Country	US
Kind code	B2
Filing date	Jan 23, 2018
Priority date	Jul 23, 2015
Publication date	Mar 10, 2020
Grant date	Mar 10, 2020

Abstract

An alkylation process and apparatus are described. The alkylation process includes pre-mixing a paraffin stream with an ionic liquid catalyst stream from a settler. The premixed paraffin and ionic liquid catalyst stream is mixed in a low-efficiency pump to form a paraffin and ionic liquid catalyst mixture. An olefin feed stream is introduced into a riser reactor. The paraffin and ionic liquid catalyst mixture is introduced into the riser reactor to form a reaction mixture comprising alkylate and the ionic liquid catalyst. The reaction mixture is separated in a settler into an ionic liquid catalyst stream and a hydrocarbon stream.

First claim

What is claimed is:

1. An ionic liquid alkylation process utilizing an existing HF alkylation unit, the existing HF alkylation unit comprising an existing settler and an existing riser reactor, the process comprising:
modifying the existing HF alkylation unit by adding a pre-mixer and a low efficiency pump on a paraffin feed line, wherein the low efficiency pump comprises a high shear pump, a rotor-stator pump, or a cavitation reactor pump;
pre-mixing a paraffin stream with an ionic liquid catalyst stream resulted from the existing settler in the pre-mixer to form a pre-mixed paraffin and ionic liquid catalyst stream;
mixing the pre-mixed paraffin and ionic liquid catalyst stream in the low efficiency pump to form a paraffin and ionic liquid catalyst mixture, the low efficiency pump producing droplets of one or more of the paraffin or the ionic liquid catalyst in the paraffin and ionic liquid catalyst mixture;
introducing an olefin feed stream into the existing riser reactor;
introducing the paraffin and ionic liquid catalyst mixture into the existing riser reactor to form a reaction mixture comprising alkylate and the ionic liquid catalyst; and
separating the reaction mixture in the existing settler into the ionic liquid catalyst stream and a hydrocarbon stream.

2. The process of claim 1 wherein the hydrocarbon stream includes unreacted paraffin, and the process further comprising:
separating the hydrocarbon stream into alkylate product stream and a paraffin recycle stream;
wherein the paraffin recycle stream comprises at least a portion of the paraffin stream.

3. The process of claim 1 further comprising:
cooling at least one of the paraffin stream or the olefin feed stream from an initial temperature to a temperature less than the initial temperature.

4. The process of claim 1 wherein introducing the olefin feed stream into the existing riser reactor comprises introducing the olefin feed stream into the existing riser reactor at more than one location.

5. The process of claim 1 wherein the paraffin stream comprises an isoparaffin having from 4 to 10 carbon atoms.

6. The process of claim 1 wherein the olefin feed stream comprises an olefin having from 2 to 10 carbon atoms.

7. The process of claim 1 further comprising:
regenerating a portion of the ionic liquid catalyst stream before pre-mixing the paraffin stream with the ionic liquid catalyst stream.

8. The process of claim 1 wherein the existing settler further comprises a coalescing material.

9. The process of claim 1 further comprising introducing a slipstream of at least one of paraffin and ionic liquid catalyst into the bottom of the existing settler.

10. The process of claim 1 further comprising mixing the olefin feed stream with the paraffin and ionic liquid catalyst mixture before introducing the olefin feed stream into the existing riser reactor.

11. An ionic liquid alkylation process utilizing an existing HF alkylation unit, the existing HF alkylation unit comprising an existing settler and an existing riser reactor, the process comprising:
modifying the existing HF alkylation unit by adding a pre-mixer and a low efficiency pump on a paraffin feed line, wherein the low efficiency pump comprises a high shear pump, a rotor-stator pump, or a cavitation reactor pump;
pre-mixing an isoparaffin stream with an ionic liquid catalyst stream resulted from the existing settler in the pre-mixer to form a pre-mixed isoparaffin and ionic liquid catalyst stream, the isoparaffin stream comprising isoparaffins having from 4 to 10 carbon atoms;
mixing the pre-mixed isoparaffin and ionic liquid catalyst stream in the low efficiency pump to form an isoparaffin and ionic liquid catalyst mixture, the low efficiency pump producing droplets of one or more of the paraffin or the ionic liquid catalyst in the isoparaffin and ionic liquid catalyst mixture;
introducing an olefin feed stream to the existing riser reactor, the olefin feed stream comprising olefins having from 2 to 10 carbon atoms;
introducing the isoparaffin and ionic liquid catalyst mixture into the existing riser reactor to form a reaction mixture comprising alkylate, unreacted isoparaffin, and the ionic liquid catalyst;
introducing the reaction mixture into the existing settler;
separating the reaction mixture in the existing settler into the ionic liquid catalyst stream and a hydrocarbon stream comprising the alkylate and the unreacted isoparaffin; and
separating the hydrocarbon stream into an alkylate product stream and an isoparaffin recycle stream,
wherein the isoparaffin recycle stream comprises at least a portion of the isoparaffin stream.

12. The process of claim 11 further comprising:
cooling at least one of the isoparaffin stream or the olefin feed stream from an initial temperature to a temperature less than the initial temperature.

13. The process of claim 11 wherein introducing the olefin feed stream to the existing riser reactor comprises introducing the olefin feed stream to the existing riser reactor at more than one location.

14. The process of claim 11 further comprising:
regenerating a portion of the ionic liquid catalyst stream before pre-mixing the isoparaffin stream with the ionic liquid catalyst stream.

15. The process of claim 11 wherein the existing settler further comprises a coalescing material.

16. The process of claim 11 further comprising introducing a slipstream of isoparaffin, or a slipstream of ionic liquid catalyst, or a slipstream of isoparaffin and a slipstream of ionic liquid catalyst into the bottom of the existing settler, wherein the slipstream of isoparaffin, the slipstream of ionic liquid catalyst, and the slipstream of isoparaffin and the slipstream of ionic liquid catalyst are not the existing riser reactor effluent.

17. The process of claim 11 further comprising mixing the olefin feed stream with the isoparaffin and ionic liquid catalyst mixture before introducing the olefin feed stream to the existing riser reactor.

Assignees

• Uop Llc

Inventors

• Leeton Eric

Classifications

• C10L2290/543

  Distillation, fractionation or rectification for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title

• C07C2/60 Primary

  with halides · CPC title

• C10L1/06

  for spark ignition · CPC title

• C10L2270/023

  for gasoline engines · CPC title

• C10L2290/24

  Mixing, stirring of fuel components · CPC title