Nanocrystalline composite catalyst for storing/supplying hydrogen, nanocrystalline composite catalyst mixture for storing/supplying hydrogen, and method for supplying hydrogen

Patent metadata

Field	Value
Publication number	US-10584030-B2
Application number	US-201815870450-A
Country	US
Kind code	B2
Filing date	Jan 12, 2018
Priority date	Jul 15, 2015
Publication date	Mar 10, 2020
Grant date	Mar 10, 2020

Abstract

The present disclosure provides that a catalyst exhibits excellent catalytic activity in both a hydrogenation involving a hydrogen-storing body containing an aromatic compound, and a dehydrogenation involving a hydrogen-supplying body containing a hydrogen derivative of the aromatic compound, wherein the catalyst contains a nanocrystalline composite having two or more accumulated flake-like nanocrystalline pieces in a connected state, the flake-like nanocrystalline pieces each having a main surface and an end surface, and in that the nanocrystalline composite is configured such that, when two adjacent nanocrystalline pieces are viewed, an end surface of at least one of the nanocrystalline pieces is connected.

First claim

What is claimed is:

1. A nanocrystalline composite catalyst exhibiting catalytic activity in both a hydrogenation of a hydrogen-storing body containing an aromatic compound, and a dehydrogenation of a hydrogen-supplying body containing a hydrogen derivative of the aromatic compound,
wherein the catalyst contains
a nanocrystalline composite having two or more accumulated flake-like nanocrystalline pieces in a connected state, the flake-like nanocrystalline pieces each having a main surface and an end surface; and
a base material;

the nanocrystalline composite is configured such that, when two adjacent nanocrystalline pieces are viewed, an end surface of one nanocrystalline piece of the two adjacent nanocrystalline pieces is connected to a main surface of another nanocrystalline piece of the two adjacent nanocrystalline pieces, or end surfaces of both the two adjacent nanocrystalline pieces are connected to each other, and
at least one nanocrystalline piece forming the nanocrystalline composite is configured to be connected to a surface of the base material.

2. The nanocrystalline composite catalyst according to claim 1 , wherein the nanocrystalline composite is a nanocrystalline metal composite in which the nanocrystalline pieces forming the nanocrystalline composite contains one or more metals selected from the group consisting of Pd, Rh, Ru, Pt, Ag, and Au, or one or more alloys containing the one or more metals.

3. The nanocrystalline composite catalyst according to claim 1 , wherein the nanocrystalline composite is a nanocrystalline metal oxide composite in which the nanocrystalline pieces forming the nanocrystalline composite contains a metal oxide comprising an oxide of one or more metals selected from the group consisting of Cu, Ni, Co and Zn.

4. The nanocrystalline composite catalyst according to claim 3 , wherein the metal oxide is an oxide of Cu.

5. The nanocrystalline composite catalyst according to claim 4 , wherein the metal oxide is a Ni—Cu composite oxide.

6. A nanocrystalline composite catalyst mixture is obtained by mixing a first catalyst containing the nanocrystalline composite catalyst for storing/supplying hydrogen according to claim 3 with a second catalyst containing the nanocrystalline composite catalyst for storing/supplying hydrogen according to claim 3 .

7. A method for supplying hydrogen comprising a step of:
contacting the nanocrystalline composite catalyst according to claim 1 with a solution containing the hydrogen-supplying body, and
preparing a seed crystal material as the base material, preferentially growing the nanocrystalline pieces from the surface of the base material, and accumulating two or more nanocrystalline pieces on the surface of the base material in a connected state to integrally form the nanocrystalline composite,
wherein the catalyst promotes a dehydrogenation of the hydrogen-supplying body to extract the hydrogen by the contacting step.

8. The method for supplying hydrogen according to claim 7 , the method further comprising the steps of:
separating the catalyst from the solution; and
subjecting the catalyst after the separation to a reactivation treatment.

Assignees

• Furukawa Electric Co Ltd

Inventors

• Tsuzuki Yoshikazu
• Iizuka Kenji
• Wakae Mariko
• Kurusu Kazuhiko

Classifications

• B01J23/96

  of catalysts comprising metals, oxides or hydroxides of the noble metals · CPC title

• B01J23/94

  of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper · CPC title

• Y02P20/584

  Recycling of catalysts · CPC title

• B01J23/464

  Rhodium · CPC title

• B01J2231/76

  Dehydrogenation · CPC title