Anaerobic aluminum-water electrochemical cell

Patent metadata

Field	Value
Publication number	US-10581127-B2
Application number	US-201816057285-A
Country	US
Kind code	B2
Filing date	Aug 7, 2018
Priority date	Dec 4, 2012
Publication date	Mar 3, 2020
Grant date	Mar 3, 2020

Abstract

An anaerobic aluminum-water electrochemical cell is provided. The electrochemical cell includes: a plurality of electrode stacks, each electrode stack comprising an aluminum or aluminum alloy anode, and at least one cathode configured to be electrically coupled to the anode and having a surface characterized by an electrochemical roughness factor of at least 5 and a mean pore diameter of at least 50 μm; one or more physical separators between each electrode stack adjacent to the cathode; a housing configured to hold the electrode stacks, an electrolyte, and the physical separators; and a water injection port, in the housing, configured to introduce water into the housing.

First claim

The invention claimed is:

1. An anaerobic aluminum-water electrochemical cell comprising:
a plurality of electrode stacks, each electrode stack comprising a solid aluminum or aluminum alloy anode in the form of a plate, the plate having a first side and a second side opposite to the first side, and at least one cathode disposed directly next to the first side of the plate and at least one cathode disposed directly next to the second side of the plate, wherein the cathode on the first side and the cathode on the second side are configured to be electrically coupled to the anode and the cathode on the first side and the cathode on the second side have a surface characterized by an electrochemical roughness factor of at least 5 and a mean pore diameter of at most 100 μm;
one or more physical separators, between each one of the electrode stacks, positioned between the cathode on the first side and the cathode on the second side of an adjacent electrode stack;
a housing configured to hold the electrode stacks, an electrolyte, and the one or more physical separators; and
a water injection port, in the housing, configured to introduce water into the housing, so that the water flows through the one or more physical separators.

2. The electrochemical cell according to claim 1 , wherein the surface of the cathode on the first side and/or the surface of the cathode on the second side has an electrochemical roughness factor of at least 10.

3. The electrochemical cell according to claim 1 , wherein the surface of the cathode on the first side and/or the surface of the cathode on the second side has an electrochemical roughness factor of at least 15.

4. The electrochemical cell according to claim 1 , wherein the surface of the cathode on the first side and/or the surface of the cathode on the second side has an electrochemical roughness factor of at least 20.

5. The electrochemical cell according to claim 1 , wherein the mean pore diameter of the cathode on the first side and/or the mean pore diameter of the cathode on the second side is at most 50 μm.

6. The electrochemical cell according to claim 1 , further comprising an amount of hydroxide base sufficient to form the electrolyte having a hydroxide base concentration of between 0.05 M to 3 M when the water is introduced between the anode and the at least one cathode of the electrochemical cell.

7. The electrochemical cell according to claim 1 , wherein the aluminum of the anode has a purity of at least 99.95 wt %.

8. The electrochemical cell according to claim 1 , wherein the aluminum or aluminum alloy of the anode is substantially free of titanium and boron.

9. An aluminum-water electrochemical system comprising:
an aluminum-water electrochemical cell according to claim 1 ;
a waste separation system in fluid communication with the housing and configured to receive electrolyte and aluminum hydroxide waste from the aluminum-water electrochemical cell and to separate the aluminum hydroxide waste from the electrolyte; and
a fuel injector, in fluid communication with the waste separation system and the water injection port, configured to receive the electrolyte from the waste separation system and to provide the electrolyte to the water injection port.

10. The electrochemical system according to claim 9 , wherein the fuel injector is further configured to receive the water from a water supply.

11. The electrochemical system according to claim 9 , further comprising the electrolyte, the electrolyte comprising at least one hydroxide base at a concentration of about 0.25 M to about 2 M.

12. The electrochemical system according to claim 11 , wherein the electrolyte includes water and sodium chloride.

13. A method for generating an electrical current comprising:
providing the electrochemical cell of claim 1 ;
introducing the water between the anode and the at least one cathode of the electrochemical cell, to form the electrolyte by mixing with other ingredients either prior to or after entering the housing;
anaerobically oxidizing the aluminum or an aluminum alloy; and
electrochemically reducing the water at the at least one cathode.

14. The method according to claim 13 , wherein the surface of the cathode on the first side and/or the surface of the cathode on the second side has an electrochemical roughness factor of at least 10.

15. The method according to claim 13 , wherein the surface of the cathode on the first side and/or the surface of the cathode on the second side has an electrochemical roughness factor of at least 15.

16. The method according to claim 13 , wherein the water includes sodium chloride.

17. The method according to claim 13 , wherein the electrolyte has a hydroxide base concentration of between 0.05 M to 3 M.

18. The method according to claim 13 , wherein the electrolyte has a hydroxide base concentration of between about 0.1 M to about 2.5 M.

Assignees

• Massachusetts Inst Technology

Inventors

• Mckay Ian Salmon
• Macdonald Ruaridh R
• Milnes Thomas B

Classifications

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M6/04

  Cells with aqueous electrolyte · CPC title

• H01M4/12

  of consumable metal or alloy electrodes (use of alloy compositions as active materials H01M4/38) · CPC title

• H01M4/463

  Aluminium based · CPC title

• H01M2300/0014

  Alkaline electrolytes · CPC title