Perovskite compounds for stable, high activity solid oxide fuel cell cathodes and other applications

Patent metadata

Field	Value
Publication number	US-10581085-B2
Application number	US-201615384482-A
Country	US
Kind code	B2
Filing date	Dec 20, 2016
Priority date	Dec 20, 2016
Publication date	Mar 3, 2020
Grant date	Mar 3, 2020

Abstract

Solid oxide fuel cells (SOFCs) are provided. A SOFC may comprise a cathode, an anode, and a solid oxide electrolyte between the anode and the cathode, wherein the cathode comprises a perovskite compound. The perovskite compound may be characterized by a log k* value which is less negative than about −6.0 cm/s; an energy above the convex hull of less than about 40 meV/(formula unit); a bandgap of about 0 and a charge transfer gap of about 0.

First claim

What is claimed is:

1. A solid oxide fuel cell (SOFC) comprising a cathode, an anode, and a solid oxide electrolyte between the anode and the cathode, wherein the cathode comprises a perovskite compound, wherein the perovskite compound is selected from
A (1−x) A′ x B y B′ y′ B″ y″ O 3 (Formula 1C), wherein 0≤x≤0.5, 0.125≤y≤1, 0≤y′≤0.875, 0≤y″≤0.875, y+y′+y″=1, and if x is zero, then y is not 1; wherein A is selected from Ba and Y; A′ is selected from Ca, Sr, Ba, Sm, Nd, Cd, and Sn, wherein A and A′ are different; B is selected from Cr, Mn, Fe, and Co; B′ is selected from Co, Ni, Zr, Nb, Ru, Hf, Ta, Re, Os, and Pt; and B″ is Zr, wherein B, B′, and B″ are different; and combinations thereof;
wherein the perovskite compound is characterized by a log k* value which is less negative than about −6.0 cm/s; an energy above the convex hull of less than about 40 meV/(formula unit); a bandgap of about 0 and a charge transfer gap of about 0,
and further wherein the perovskite compound is not Ba 0.5 Sr 0.5 Fe 0.9 Nb 0.1 O 3 and is not BaCo 0.4 Fe 0.4 Zr 0.2 O 3 .

2. The SOFC of claim 1 , wherein A is Y; or A′ is Cd or Sn; or B′ is selected from Ru, Hf, Ta, Re, and Os; or all three.

3. The SOFC of claim 1 , wherein the perovskite compound is selected from A (1−x) A′ x B (1−y) B′ y O 3 (Formula 2A), wherein 0≤x≤0.5, 0≤y≤0.875, and x and y are not both zero;
wherein A is selected from Ba and Y; A′ is selected from Ca, Sr, Ba, Sm, Nd, and Sn, wherein A and A′ are different; B is selected from Cr, Mn, Fe, and Co; and B′ is selected from Ni, Zr, Nb, Ru, Ta, Re, Os, and Pt.

4. The SOFC of claim 3 , wherein A is Y; or A′ is Sn; or B′ is selected from Ru, Ta, Re, and Os; or all three.

5. The SOFC of claim 1 , wherein the perovskite compound is selected from AB y B′ y ′B″ y″ O 3 (Formula 3A), wherein 0.125≤y≤0.875; 0.125≤y′≤0.875; and 0≤y″≤0.875; wherein A is selected from Ba and Y; B is Fe; B′ is selected from Co, Ni, Nb, Ru, Ta, Re, Os and Pt; and B″ is Zr.

6. The SOFC of claim 5 , wherein A is Ba; B is Fe; B′ is selected from Co, Nb, Ru, Ta, Re, Os and Pt; and B″ is Zr.

7. The SOFC of claim 6 , wherein B′ is selected from Ru, Ta, Re, and Os.

8. The SOFC of claim 5 , wherein the perovskite compound is selected from AB (1−y) B′ y O 3 (Formula 3B), wherein 0.125≤y≤0.875; wherein A is selected from Ba and Y; B is Fe; and B′ is selected from Ni, Nb, Ru, Ta, Re, Os, and Pt.

9. The SOFC of claim 8 , wherein A is Ba; B is Fe; and B′ is selected from Nb, Ru, Ta, Re, Os, and Pt.

10. The SOFC of claim 9 , wherein B′ is selected from Ru, Ta, Re, and Os.

11. The SOFC of claim 1 , wherein the perovskite compound is selected from A (1−x) A′ x B y B′ y′ B″ y″ O 3 (Formula 4A), wherein 0≤x≤0.5; 0.125≤y≤0.875; 0.125≤y′≤0.875; and 0≤y″≤0.75;
wherein A is Ba; A′ is selected from Cd, and Sn; B is Fe; B′ or B″ or both is selected from an element having an oxidation state which does not change under the operating conditions for driving the oxygen reduction reaction; and B″ is Zr, wherein B, B′ B″ are different.

12. The SOFC of claim 11 wherein B′ is selected from Co, Zr, Nb, Hf, Ta, and Re.

13. The SOFC of claim 11 , wherein the perovskite compound is selected from A (1−x) A′ x B y B′ y ′B″ y″ O 3 (Formula 4B), wherein 0.125≤x≤0.25; y=y′=0.125; and y″=0.75; wherein A is Ba; A′ is selected from Cd and Sn; B is Fe; B′ is Hf; and B″ is Zr.

14. A solid oxide fuel cell (SOFC) comprising a cathode, an anode, and a solid oxide electrolyte between the anode and the cathode, wherein the cathode comprises a perovskite compound, wherein the perovskite compound is characterized by a log k* value which is less negative than about −6.0 cm/s; an energy above the convex hull of less than about 40 meV/(formula unit); a bandgap of about 0 and a charge transfer gap of about 0, wherein the perovskite compound is selected from A (1−x) A′ x B y B′ y ′B″ y ″O 3 (Formula 5), wherein 0≤x≤0.25; 0.125≤y≤0.875; 0.125≤y′≤0.875; and 0≤y″≤0.75;
wherein A is Ba; A′ is Sn; B is Fe; B′ is selected from Co, Zr, Nb, Ru, Hf, Ta, Re, and Pt; and B″ is Zr, wherein B′ and B″ are different; and further wherein the perovskite compound is not BaCo 0.4 Fe 0.4 Zr 0.2 O 3 .

15. The SOFC of claim 14 , wherein B′ is selected from Hf, Ta, and Re.

16. A solid oxide fuel cell (SOFC) comprising a cathode, an anode, and a solid oxide electrolyte between the anode and the cathode, wherein the cathode comprises a perovskite compound, wherein the perovskite compound is characterized by a log k* value which is less negative than about −6.0 cm/s; an energy above the convex hull of less than about 40 meV/(formula unit); a bandgap of about 0 and a charge transfer gap of about 0, and further wherein the perovskite compound is selected from BaFe 0.75 Nb 0.25 O 3 ; BaFe 0.75 Ta 0.25 O 3 ; BaFe 0.125 Co 0.125 Zr 0.75 O 3 ; BaFe 0.875 Re 0.125 O 3 ; Ba 0.625 La 0.125 Zn 0.375 NiO 3 ; Ba 0.875 Sn 0.125 Fe 0.125 Zr 0.875 O 3 ; BaFe 0.75 Ru 0.25 O 3 ; BaFe 0.5 Pt 0.5 O 3 ; Ba 0.75 Sn 0.25 Fe 0.125 Hf 0.125 Zr 0.75 O 3 ; YFe 0.875 Ni 0.125 O 3 ; Ba 0.875 Cd 0.125 Fe 0.125 Hf 0.125 Zr 0.75 O 3 ; BaFe 0.5 Ru 0.5 O 3 ; BaFe 0.75 Os 0.25 O 3 ; Ba 0.75 Cd 0.25 Fe 0.125 Hf 0.125 Zr 0.75 O 3 ; YFe 0.875 Co 0.125 O 3 ; and combinations thereof.

17. An electrode comprising a perovskite compound selected from BaFe 0.75 Nb 0.25 O 3 ; BaFe 0.75 Ta 0.25 O 3 ; BaFe 0.125 Co 0.125 Zr 0.75 O 3 ; BaFe 0.875 Re 0.125 O 3 ; Ba 0.625 La 0.125 Zn 0.375 NiO 3 ; Ba 0.875 Sn 0.125 Fe 0.125 Zr 0.875 O 3 ; BaFe 0.75 Ru 0.25 O 3 ; BaFe 0.5 Pt 0.5 O 3 ; Ba 0.75 Sn 0.25 Fe 0.125 Hf 0.125 Zr 0.75 O 3 ; YFe 0.875 Ni 0.125 O 3 ; Ba 0.875 Cd 0.125 Fe 0.125 Hf 0.125 Zr 0.75 O 3 ; BaFe 0.5 Ru 0.5 O 3 ; BaFe 0.75 Os 0.25 O 3 ; Ba 0.75 Cd 0.25 Fe 0.125 Hf 0.125 Zr 0.75 O 3 ; YFe 0.875 Co 0.125 O 3 ; and combinations thereof.

Assignees

• Wisconsin Alumni Res Found

Inventors

• Jacobs Ryan Matthew
• Morgan Dane

Classifications

• H01M2004/8689

  Positive electrodes · CPC title

• H01M4/9033 Primary

  Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• Y02E60/50

  Fuel cells · CPC title