Distillation column and use thereof for cleaning isocyanates

Patent metadata

Field	Value
Publication number	US-10576392-B2
Application number	US-201615772543-A
Country	US
Kind code	B2
Filing date	Sep 23, 2016
Priority date	Nov 2, 2015
Publication date	Mar 3, 2020
Grant date	Mar 3, 2020

Abstract

A distillation column for separating a multicomponent mixture into at least three fractions. The distillation column has at least one separating wall and at least one material exchange element ( 1 ) above the at least one separating wall. A device ( 10 ) for mixing the steam flows flowing upwards to the left and the right of the at least one separating wall is arranged between the at least one separating wall and the at least one material exchange element ( 1 ). The use of the distillation column for purifying isocyanates, in particular for toluene diisocyanate (TDI), is also described.

First claim

What is claimed is:

1. A distillation column for fractionating a multi-component mixture into at least 3 fractions, wherein the distillation column comprises at least one dividing wall and above the at least one dividing wall comprises at least one mass transfer element in which mass transfer between ascending vapor and descending liquid takes place, wherein between the at least one dividing wall and the at least one mass transfer element, or in case of the presence of a plurality of mass transfer elements between the at least one dividing wall and the lowest mass transfer element, an apparatus for mixing the vapor streams ascending left and right of the at least one dividing wall is arranged, the mixing apparatus being located in the distillation column at a location where vapor streams from the at least one dividing wall ascend without colliding with descending liquid.

2. The distillation column of claim 1 , wherein the apparatus for mixing the vapor streams ascending left and right of the at least one dividing wall is selected from the group consisting of mixer packings, corrugated sheet layers, straight baffle plates, sloping baffle plates, sieve trays, chimney trays, bubble-cap trays, valve trays, stators, tubes, channels, perforated sheets and combinations of the abovementioned apparatuses.

3. The distillation column of claim 1 , wherein the at least one mass transfer element arranged above the dividing wall is selected from the group consisting of dumped packing beds, structured mass transfer packings, bubble-cap trays, valve trays, sieve trays or combinations of the abovementioned apparatuses.

4. The distillation column of claim 1 , wherein one dividing wall is present.

5. The distillation column of claim 1 , wherein one mass transfer element is present.

6. The distillation column of claim 1 , wherein the at least one mass transfer element or, in case of the presence of a plurality of mass transfer elements, at least the lowest mass transfer element, extends over the entire cross section of the column body.

7. The distillation column of claim 1 , wherein arranged below the mass transfer element or, in case of the presence of a plurality of mass transfer elements, below the lowest mass transfer element, is a liquid collector for collecting the liquid effluxing from the at least one mass transfer element, wherein the liquid collector is configured such that the liquid collected in the liquid collector is passed the upper end of the at least one dividing wall.

8. The distillation column of claim 7 , in which the liquid collector is configured such that the liquid collected in the liquid collector is transferred into an annular channel and from there passed the upper end of the at least one dividing wall.

9. The distillation column of claim 1 , wherein arranged below the mass transfer element or, in case of the presence of a plurality of mass transfer elements below the lowest mass transfer element, is a liquid collector for collecting the liquid effluxing from the at least one mass transfer element, wherein the liquid collector is configured such that the liquid collected in the liquid collector is transferred into an annular channel and from there via an exit stub out from the inside of the distillation column via conduits located outside the column body to liquid distributors arranged adjacent to the at least one dividing wall.

10. The distillation column of claim 1 , where arranged below the mass transfer element or, in case of the presence of a plurality of mass transfer elements below the lowest mass transfer element, is a liquid collector for collecting the liquid effluxing from the at least one mass transfer element, wherein the liquid collector is configured such that the liquid collected in this liquid collector is transferred into an annular channel and from there via conduits located inside the column body to liquid distributors arranged adjacent to the at least one dividing wall.

11. A method of purifying isocyanates comprising introducing a crude isocyanate into the distillation column of claim 1 , wherein both fine purification of the isocyanate and removal of polymeric isocyanate fractions are carried out in the distillation column.

12. A method of purifying isocyanates comprising introducing a crude isocyanate into the distillation column of claim 1 , wherein fractionation of the isocyanate into various isomers occurs in the distillation column.

13. The method of claim 11 , in which the isocyanate is selected from the group consisting of tolylene diisocyanate, methylenediphenyl diisocyanate, hexamethylene diisocyanate, pentamethylene diisocyanate, isophoronediamine diisocyanate, m-xylylene diisocyanate and dicyclohexylmethane diisocyanate.

14. A distillation column for fractionating a multi-component mixture into at least 3 fractions, wherein the distillation column comprises at least one dividing wall and above the at least one dividing wall comprises at least one mass transfer element in which mass transfer between ascending vapor and descending liquid takes place, wherein between the at least one dividing wall and the at least one mass transfer element, or in case of the presence of a plurality of mass transfer elements between the at least one dividing wall and the lowest mass transfer element, an apparatus for mixing the vapor streams ascending left and right of the at least one dividing wall is arranged, the mixing apparatus being located in the distillation column at a location where vapor streams from the at least one dividing wall ascend without colliding with descending liquid,
wherein the apparatus for mixing the vapor streams ascending left and right of the at least one dividing wall is selected from the group consisting of mixer packings, corrugated sheet layers, straight baffle plates, sloping baffle plates, sieve trays, chimney trays, bubble-cap trays, valve trays, stators, tubes, channels, perforated sheets and a combination of any two or more thereof, and
wherein the at least one mass transfer element arranged above the dividing wall is selected from the group consisting of dumped packing beds, structured mass transfer packings, bubble-cap trays, valve trays, sieve trays, and a combination of any two or more thereof.

15. The distillation column of claim 14 , wherein one dividing wall is present and/or wherein one mass transfer element is present.

16. The distillation column of claim 14 , wherein the at least one mass transfer element or, in case of the presence of a plurality of mass transfer elements, at least the lowest mass transfer element, extends over the entire cross section of the column body.

17. The distillation column of claim 14 , wherein arranged below the mass transfer element or, in case of the presence of a plurality of mass transfer elements, below the lowest mass transfer element, is a liquid collector for collecting the liquid effluxing from the at least one mass transfer element, wherein the liquid collector is configured such that the liquid collected in the liquid collector is passed to the upper end of the at least one dividing wall.

18. The distillation column of claim 17 , in which the liquid collector is configured such that the liquid collected in the liquid collector is transferred into an annular channel and from there passed to the upper end of the at least one dividing wall.

19. The distillation column of claim 14 , wherein arranged below the mass transfer element or, in case of the presence of a plurality of mass transfer elements below the lowest mass transfer element, is a liquid collector

Assignees

• Covestro Deutschland Ag

Inventors

• Steffens Friedhelm
• Hedderich Wilfried
• Bausa Jürgen
• Beggel Franz
• Michele Volker

Classifications

• C07C263/20

  Separation; Purification · CPC title

• B01D3/141 Primary

  where at least one distillation column contains at least one dividing wall · CPC title

• B01D3/32

  Other features of fractionating columns {; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30} · CPC title

• C07C265/14

  containing at least two isocyanate groups bound to the same carbon skeleton · CPC title