Anaerobic aluminum-water electrochemical cell

Patent metadata

Field	Value
Publication number	US-10573944-B2
Application number	US-201816057186-A
Country	US
Kind code	B2
Filing date	Aug 7, 2018
Priority date	Dec 4, 2012
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

Provided is a method for generating an electrical current. The method includes: introducing water between the anode and at least one cathode of an electrochemical cell, to form an electrolyte; anaerobically oxidizing aluminum or an aluminum alloy at the anode; and electrochemically reducing water at the at least one cathode. The electrochemical cell includes: a plurality of electrode stacks, each electrode stack comprising an anode including the aluminum or aluminum alloy, and at least one cathode configured to be electrically coupled to the anode; one or more physical separators between each electrode stack adjacent to the cathode; a housing configured to hold the electrode stacks, the electrolyte, and the physical separators; and a water injection port in the housing. When the cell is in operation, the concentration of aluminum species in the electrolyte is maintained between at least 0.01 M to at most 0.7 M.

First claim

The invention claimed is:

1. A method for generating an electrical current, the method comprising: providing an electrochemical cell comprising: a plurality of electrode stacks, each electrode stack comprising a solid aluminum or aluminum alloy anode in the form of a plate, the plate having a first side and a second side opposite to the first side, and at least one cathode disposed directly next to the first side of the plate and at least one cathode disposed directly next to the second side of the plate, wherein the cathode on the first side and the cathode on the second side are configured to be electrically coupled to the anode; a housing configured to hold the electrode stacks; an electrolyte; the one or more physical separators; and a water injection port, in the housing, configured to introduce water into the housing, so that the water flows through the physical separators; introducing the electrolyte between the anode and the at least one cathode on the first side and between the anode and the at least one cathode on the second side in each electrode stack, the electrolyte formed from an hydroxide base and the water; anaerobically oxidizing the aluminum or aluminum alloy at the anode; and electrochemically reducing the water at the at least one cathode, wherein: when the cell is in operation, the concentration of aluminum species in the electrolyte is maintained between at least 0.01 M to at most 0.7 M.

2. The method according to claim 1 , wherein the concentration of aluminum species in the electrolyte is maintained between about 0.1 M to about 0.6 M.

3. The method according to claim 1 , wherein the concentration of aluminum species in the electrolyte is maintained between about 0.2 M to about 0.5 M.

4. The method according to claim 1 , wherein substantially no aluminum hydroxide precipitate is formed by homogeneous precipitation.

5. The method according to claim 1 , wherein hydroxide base has a concentration of at least about 0.1 M to at most 3 M.

6. The method according to claim 1 , wherein hydroxide base has a concentration of at least about 0.25 M to at most about 2.5 M.

7. The method according to claim 1 , wherein the water includes sodium chloride.

8. The method according to claim 1 , wherein the anode aluminum has a purity of at least 99.95 wt %.

9. The method according to claim 1 , wherein the anode aluminum has a purity of at least 99.99 wt %.

10. The method according to claim 1 , wherein the anode aluminum or aluminum alloy is substantially free of tin and boron.

11. The method according to claim 1 , wherein the cathode on the first side and/or the cathode on the second side is in the form of a solid plate.

12. The method according to claim 1 , wherein the cathode on the first side and/or the cathode on the second side is in the form of a sponge.

13. The method according to claim 1 , wherein the cathode on the first side and/or the cathode on the second side includes a nickel-molybdenum alloy.

14. The method according to claim 1 , wherein the cathode on the first side and/or the cathode on the second side has a surface characterized by an electrochemical roughness factor of at least 5.

15. The method according to claim 1 , wherein the cathode on the first side and/or the cathode on the second side has a surface characterized by an electrochemical roughness factor of at least 10.

16. The method according to claim 1 , wherein the aluminum or aluminum alloy is substantially free of aerobic oxidation.

17. The method of according to claim 1 , wherein the electrochemical cell further comprises a waste separation system in fluid communication with the housing, and a fuel injector in fluid communication with the waste separation system and the water injection port, the method further comprising; receiving the electrolyte and aluminum hydroxide waste from the electrochemical cell; separating the aluminum hydroxide waste from the electrolyte; receiving the electrolyte from the waste separation system; and providing the electrolyte to the water injection port.

18. The method according to claim 17 , wherein the fuel injector further receives water from a water supply.

Assignees

• Massachusetts Inst Technology

Inventors

• Mckay Ian Salmon
• Macdonald Ruaridh R
• Milnes Thomas B

Classifications

• H01M2300/0014

  Alkaline electrolytes · CPC title

• H01M4/9041

  Metals or alloys (H01M4/92 takes precedence) · CPC title

• H01M12/04 Primary

  composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type · CPC title

• H01M4/463 Primary

  Aluminium based · CPC title

• H01M12/02

  Details (of electrodes H01M4/00; of non-active parts H01M50/00) · CPC title