Flow batteries having an electrode with differing hydrophilicity on opposing faces and methods for production and use thereof

Patent metadata

Field	Value
Publication number	US-10573899-B2
Application number	US-201615297071-A
Country	US
Kind code	B2
Filing date	Oct 18, 2016
Priority date	Oct 18, 2016
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

Electrochemical cells, such as those present within flow batteries, can include at least one electrode with one face being more hydrophilic than is the other. Such electrodes can lessen the incidence of parasitic reactions by directing convective electrolyte circulation toward a separator in the electrochemical cell. Flow batteries containing the electrochemical cells can include: a first half-cell containing a first electrode with a first face and a second face that are directionally opposite one another, a second half-cell containing a second electrode with a first face and a second face that are directionally opposite one another, and a separator disposed between the first half-cell and the second half-cell. The first face of both the first and second electrodes is disposed adjacent to the separator. The first face of at least one of the first electrode and the second electrode is more hydrophilic than is the second face.

First claim

What is claimed is the following:

1. A flow battery cell comprising:
a first half-cell containing a first electrode with a first face and a second face that are directionally opposite one another, the second face of the first electrode being in interfacial contact with a first bipolar plate, the first bipolar plate comprising a first set of non-overlapping flow channels that interface with the first electrode;
a second half-cell containing a second electrode with a first face and a second face that are directionally opposite one another, the second face of the second electrode being in interfacial contact with a second bipolar plate, the second bipolar plate comprising a first set of non-overlapping flow channels that interface with the second electrode; and
a separator disposed between the first half-cell and the second half-cell;
wherein the first face of both the first and second electrodes is disposed adjacent to the separator, and the first face of both the first electrode and the second electrode is more hydrophilic than is the second face.

2. The flow battery cell of claim 1 , wherein at least one of the first electrode and the second electrode has a hydrophilicity gradient decreasing outwardly from the separator.

3. The flow battery cell of claim 2 , wherein the hydrophilicity gradient is a stepped gradient.

4. The flow battery cell of claim 1 , wherein at least one of the first electrode and the second electrode further comprises a conductive additive deposited upon the second face to a greater extent than upon the first face.

5. The flow battery cell of claim 1 , wherein at least one of the first electrode and the second electrode comprises a carbon electrode.

6. The flow battery cell of claim 5 , wherein at least one of the first electrode and the second electrode comprises a first carbon cloth and a second carbon cloth that are layered together such that the first carbon cloth is adjacent to the separator, and the first carbon cloth is more hydrophilic than is the second carbon cloth.

7. The flow battery cell of claim 5 , wherein the first surface of the carbon electrode is oxidized by plasma treatment to provide oxygenated functionalities on the first face, thereby rendering the first face more hydrophilic than the second surface of the same carbon electrode.

8. The flow battery cell of claim 5 , wherein the carbon electrode is functionalized upon the second face with a plurality of hydrophobic molecules to a greater extent than upon the first face, thereby rendering the first face more hydrophilic.

9. The flow battery cell of claim 5 , wherein the carbon electrode is functionalized upon the first face with a plurality of hydrophilic molecules to a greater extent than upon the second face, thereby rendering the first face more hydrophilic.

Assignees

• Lockheed Martin Energy Llc

Inventors

• Loretz Jeremy
• Puranam Srivatsava Venkataranga
• Vanbenschoten Helen Elizabeth

Classifications

• H01M4/8636 Primary

  with a gradient in another property than porosity (H01M4/861 takes precedence) · CPC title

• H01M4/8657

  layered · CPC title

• H01M4/8605

  Porous electrodes · CPC title

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/8642 Primary

  Gradient in composition · CPC title