Method for recovering scandium

Patent metadata

Field	Value
Publication number	US-10570480-B2
Application number	US-201515557583-A
Country	US
Kind code	B2
Filing date	Dec 8, 2015
Priority date	Mar 24, 2015
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

The invention provides a method for recovering scandium from an acidic solution containing scandium. The method having [a] a precipitation step wherein sodium sulfate is added into the acidic solution containing scandium to obtain a precipitate of a scandium double sulfate; [b] a neutralization step wherein pure water is added to the precipitate of a scandium double sulfate to dissolve the precipitate of a scandium double sulfate therein, and scandium hydroxide is obtained by adding a neutralizing agent into the dissolution liquid; and [c] a re-dissolution step wherein an acid is added to the scandium hydroxide obtained in the neutralization step, so that a scandium dissolution after purification, in which the scandium hydroxide is dissolved, is obtained.

First claim

The invention claimed is:

1. A method for recovering scandium, comprising:
obtaining a scandium solution after purification from an acidic solution containing scandium by a purification procedure including the following steps [A] to [C]; and
subsequently recovering scandium from the scandium solution obtained:
[A] a precipitation step of adding sodium sulfate to the acidic solution containing scandium to obtain a precipitate of double sulfates of scandium,
[B] a neutralization step of adding pure water to the precipitate of double sulfates of scandium obtained in the precipitation step to dissolve the precipitate and adding a neutralizing agent to a resulting solution to obtain scandium hydroxide, and
[C] a redissolution step of adding an acid to scandium hydroxide obtained in the neutralization step to obtain a scandium solution after purification having scandium hydroxide dissolved.

2. The method for recovering scandium according to claim 1 , comprising an enrichment step of generating a precipitate of scandium from the acidic solution containing scandium and adding an acid to the precipitate to dissolve the precipitate, wherein an acidic solution obtained in the enrichment step is subjected to a treatment in the purification procedure.

3. The method for recovering scandium according to claim 2 , wherein a neutralizing agent or oxalic acid is added to the acidic solution containing scandium to generate the precipitate of scandium and an acid is added to the precipitate to dissolve the precipitate in the enrichment step.

4. The method for recovering scandium according to claim 2 , wherein the enrichment step comprises:
a first enrichment step of adding a neutralizing agent to the acidic solution containing scandium to generate a precipitate of scandium and adding an acid to the precipitate to dissolve the precipitate; and
a second enrichment step of adding oxalic acid to the solution obtained in the first enrichment step to generate a precipitate of scandium oxalate and adding an acid to the precipitate to dissolve the precipitate.

5. The method for recovering scandium according to claim 1 , comprising an oxalate-formation step of adding oxalic acid to the scandium solution after purification to obtain a crystal of scandium oxalate, wherein
the crystal of scandium oxalate obtained in the oxalate-formation step is subjected to a treatment in a roasting step.

6. The method for recovering scandium according to claim 1 , wherein scandium hydroxide is obtained by adjusting a pH of the resulting solution in step [B] to a range of 8 to 9 by addition of a neutralizing agent in the neutralization step.

7. The method for recovering scandium according to claim 1 , wherein the acidic solution containing scandium is a scandium eluate obtained through
a leaching step of leaching the nickel oxide ore with sulfuric acid to obtain a leachate,
a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid,
sulfide and a post-sulfuration liquid, and
an ion exchange step of bringing the post-sulfuration liquid into contact with a chelating resin to allow scandium contained in the post-sulfuration liquid to be adsorbed by the chelating resin and thus to obtain the scandium eluate.

8. The method for recovering scandium according to claim 2 , comprising an oxalate-formation step of adding oxalic acid to the scandium solution after purification to obtain a crystal of scandium oxalate, wherein
the crystal of scandium oxalate obtained in the oxalate-formation step is subjected to a treatment in a roasting step.

9. The method for recovering scandium according to claim 3 , comprising an oxalate-formation step of adding oxalic acid to the scandium solution after purification to obtain a crystal of scandium oxalate, wherein
the crystal of scandium oxalate obtained in the oxalate-formation step is subjected to a treatment in a roasting step.

10. The method for recovering scandium according to claim 4 , comprising an oxalate-formation step of adding oxalic acid to the scandium solution after purification to obtain a crystal of scandium oxalate, wherein
the crystal of scandium oxalate obtained in the oxalate-formation step is subjected to a treatment in a roasting step.

11. The method for recovering scandium according to claim 2 , wherein scandium hydroxide is obtained by adjusting a pH of the resulting solution in step [B] to a range of 8 to 9 by addition of a neutralizing agent in the neutralization step.

12. The method for recovering scandium according to claim 3 , wherein scandium hydroxide is obtained by adjusting a pH of the resulting solution in step [B] to a range of 8 to 9 by addition of a neutralizing agent in the neutralization step.

13. The method for recovering scandium according to claim 4 , wherein scandium hydroxide is obtained by adjusting a pH of the resulting solution in step [B] to a range of 8 to 9 by addition of a neutralizing agent in the neutralization step.

14. The method for recovering scandium according to claim 5 , wherein scandium hydroxide is obtained by adjusting a pH of the resulting solution in step [B] to a range of 8 to 9 by addition of a neutralizing agent in the neutralization step.

15. The method for recovering scandium according to claim 8 , wherein scandium hydroxide is obtained by adjusting a pH of the resulting solution in step [B] to a range of 8 to 9 by addition of a neutralizing agent in the neutralization step.

16. The method for recovering scandium according to claim 2 , wherein the acidic solution containing scandium is a scandium eluate obtained through
a leaching step of leaching the nickel oxide ore with sulfuric acid under high temperature and high pressure to obtain a leachate,
a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid,
a sulfuration step of adding a sulfurizing agent to the post-neutralization liquid to obtain a nickel sulfide and a post-sulfuration liquid, and
an ion exchange step of bringing the post-sulfuration liquid into contact with a chelating resin to allow scandium contained in the post-sulfuration liquid to be adsorbed by the chelating resin and thus to obtain the scandium eluate.

17. The method for recovering scandium according to claim 3 , wherein the acidic solution containing scandium is a scandium eluate obtained through
a leaching step of leaching the nickel oxide ore with sulfuric acid to obtain a leachate,
a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid,
a sulfuration step of adding a sulfurizing agent to the post-neutralization liquid to obtain a nickel sulfide and a post-sulfuration liquid, and
an ion exchange step of bringing the post-sulfuration liquid into contact with a chelating resin to allow scandium contained in the post-sulfuration liquid to be adsorbed by the chelating resin and thus to obtain the scandium eluate.

18. The method for recovering scandium according to claim 4 , wherein the acidic solution containing scandium is a scandium eluate obtained through
a leaching step of leaching the nickel oxide ore with sulfuric acid to obtain a leachate,
a neutralization step of adding a neutralizing agent to the leachate to obtain a neutralized precipitate containing impurities and a post-neutralization liquid,
a sulfuration step of adding a sulfurizing agent

Assignees

• Sumitomo Metal Mining Co

Inventors

• Nagai Hidemasa
• Kudo Keiji
• Matsumoto Shin-Ya
• Kobayashi Hiroshi
• Asano Satoshi

Classifications

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• C22B59/00

  Obtaining rare earth metals · CPC title

• C22B3/42 Primary

  by ion-exchange extraction · CPC title

• Y02P10/234

  Cross-Sectional Technologies · mapped topic