Deasphalting and hydroprocessing of steam cracker tar

Patent metadata

Field	Value
Publication number	US-10570342-B2
Application number	US-201715606026-A
Country	US
Kind code	B2
Filing date	May 26, 2017
Priority date	Jun 20, 2016
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

Systems and methods are provided for solvent deasphalting of steam cracker tar. The resulting deasphalted oil produced from the steam cracker tar can then be hydroprocessed, such as hydrotreated and/or hydrocracked in a fixed bed reactor. The solvent deasphalting can correspond to a mild or trim deasphalting or can correspond to solvent deasphalting at higher solvent to oil ratios. Performing a trim deasphalting can reduce or minimize the amount of deasphalting residue that is formed as a product from the deasphalting process.

First claim

The invention claimed is:

1. A method for processing a feedstock, comprising:
mixing a feedstock comprising a 550° F.+(˜288° C.+) fraction and having a hydrogen content of about 8.0 wt % or less with a paraffinic solvent in a solvent to feedstock volume ratio of 3.0 or less to form a mixture comprising at least a first phase comprising at least 50 vol % of the paraffinic solvent and at least 50 vol % of the feedstock, and a second phase;
separating at least a portion of the first phase from the mixture;
separating the at least a portion of the first phase to form a separated fraction having a higher vol % of feedstock than the at least a portion of the first phase and having a lower vol % of asphaltenes than the feedstock; and
hydroprocessing at least a portion of the separated fraction under hydroprocessing conditions to form a hydroprocessed effluent, the hydroprocessing comprising exposing the at least a portion of the separated fraction to a fixed bed of hydrotreating catalyst under hydrotreating conditions, the hydroprocessing conditions being sufficient for conversion of at least about 5 wt % of the at least a portion of the separated fraction relative to a conversion temperature of 700° F. (˜371° C.).

2. The method of claim 1 , wherein the hydroprocessing further comprises co-processing of a second feedstock having a S BN of about 80 or less.

3. The method of claim 1 , wherein separating at least a portion of the first phase from the mixture comprises separating the at least a portion of the first phase from the mixture using an extractor having the equivalent of two theoretical stages or less.

4. The method of claim 1 , wherein the second phase is immiscible in the first phase.

5. The method of claim 1 , wherein the separated fraction comprises 250 wppm or less of particulate fines.

6. The method of claim 1 , wherein the feedstock has a micro carbon residue of about 10 wt % to about 40 wt %.

7. The method of claim 1 , wherein the feedstock has a solubility number of at least about 100.

8. The method of claim 1 , wherein the feedstock has an insolubility number of at least about 80.

9. The method of claim 8 , wherein the insolubility number of the feedstock is lower than a solubility number of the feedstock by at least about 40.

10. The method of claim 1 , wherein the separated fraction has a solubility number of at least about 100.

11. The method of claim 10 , wherein the separated fraction has an insolubility number of about 60 to about 100.

12. The method of claim 10 , wherein the insolubility number of the separated fraction is lower than a solubility number of the separated fraction by at least about 60.

13. A method for processing a feedstock, comprising:
mixing a feedstock comprising a 550° F.+(˜288° C.+) fraction and having a hydrogen content of about 8.0 wt % or less with a paraffinic solvent in a solvent to feedstock volume ratio of 3.0 or less to form a mixture comprising at least a first phase comprising at least 50 vol % of the paraffinic solvent and at least 50 vol % of the feedstock, and a second phase;
separating at least a portion of the first phase from the mixture;
separating the at least a portion of the first phase to form a separated fraction having a higher vol % of feedstock than the at least a portion of the first phase and having a lower vol % of asphaltenes than the feedstock; and
hydroprocessing at least a portion of the separated fraction under hydroprocessing conditions to form a hydroprocessed effluent, the hydroprocessing comprising co-processing of a second feedstock having a solubility number (S BN ) of about 80 or less, the hydroprocessing conditions being sufficient for conversion of at least about 5 wt % of the at least a portion of the separated fraction relative to a conversion temperature of 700° F. (˜371° C.).

14. The method of claim 13 , wherein separating at least a portion of the first phase from the mixture comprises separating the at least a portion of the first phase from the mixture using an extractor having the equivalent of two theoretical stages or less.

15. The method of claim 13 , wherein the separated fraction comprises 250 wppm or less of particulate fines, or wherein the feedstock has a micro carbon residue of about 10 wt % to about 40 wt %, or a combination thereof.

16. The method of claim 13 , wherein the feedstock has a solubility number of at least about 100.

17. The method of claim 13 , wherein the feedstock has an insolubility number of at least about 80, or wherein the insolubility number of the feedstock is lower than a solubility number of the feedstock by at least about 40, or a combination thereof.

18. The method of claim 13 , wherein the separated fraction has a solubility number of at least about 100.

19. The method of claim 18 , wherein the separated fraction has an insolubility number of about 60 to about 100, or wherein the insolubility number of the separated fraction is lower than a solubility number of the separated fraction by at least about 60, or a combination thereof.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Hanks Patrick L
• Kovvali Anjaneya S
• Ferrughelli David T
• Pyl Steven
• Raman Sumathy

Classifications

• C10G21/003 Primary

  Solvent de-asphalting · CPC title

• C10G21/14

  Hydrocarbons · CPC title

• C10G67/0454

  Solvent desasphalting · CPC title

• C10G49/002

  Apparatus for fixed bed hydrotreatment processes · CPC title