Adhesive member to be adhesively fixed through pressure

Patent metadata

Field	Value
Publication number	US-10570320-B2
Application number	US-201615551062-A
Country	US
Kind code	B2
Filing date	Mar 7, 2016
Priority date	Mar 6, 2015
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

Provided is an adhesive member to be adhesively fixed through pressure which has both position adjustability and adhesiveness and is capable of producing a sufficient adhesive strength in addition to the position adjustability. The adhesive member comprises a support, a pressure-sensitive adhesive layer provided on one surface of the support, and a plurality of protrusion elements arranged, in spaced-apart relation to each other, on a principal surface of the pressure-sensitive adhesive layer on a side opposite to the support. Each of the protrusion elements is composed of an aggregation of a plurality of cohesive particles, wherein the adhesive member has a frictional force of 0.4 N/cm2 or less, with respect to a stainless steel plate serving as an adherend, as measured when the protrusion elements are in contact with a surface of the adherend, and a shear adhesive strength of 45 N/cm2 or more.

First claim

The invention claimed is:

1. An adhesive member to be adhesively fixed through pressure comprising:
a support;
a pressure-sensitive adhesive layer provided on one surface of the support; and
a plurality of protrusion elements arranged, in spaced-apart relation to each other, on a principal surface of the pressure-sensitive adhesive layer on a side opposite to the support,
wherein each of the protrusion elements is composed of an aggregation of a plurality of cohesive particles,
wherein each of the protrusion elements composed of the aggregation of the plurality of cohesive particles has an elastic modulus of 5 MPa or more, and
wherein the cohesive particles have an average particle size of 100 nm to 300 nm.

2. The adhesive member as recited in claim 1 , wherein each of the protrusion elements has a shear adhesive strength of 2 N/cm 2 or more, as measured under a load of 500 g.

3. The adhesive member as recited in claim 1 , wherein each of the plurality of cohesive particles comprises, as its component, alkyl acrylate ester or alkyl methacrylate ester.

4. The adhesive member as recited in claim 1 , wherein each of the plurality of cohesive particles has a core-shell structure made of a resin-based core material, and a resin-based shell material having an elastic modulus greater than that of the core material and wrapping around the core material.

5. The adhesive member as recited in claim 4 , wherein a ratio of a weight of the resin-based core material to a weight of the resin-based shell material is 80% or less.

6. The adhesive member as recited in claim 4 , wherein at least one of the core material and the shell material of the core-shell structure comprises, as its component, alkyl acrylate ester or alkyl methacrylate ester.

7. The adhesive member as recited in claim 6 , wherein:
the alkyl acrylate ester comprises at least one selected from the group consisting of ethyl acrylate, propyl acrylate, n-butyl acrylate, t-butyl acrylate, n-hexyl acrylate, cyclohexyl acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, and lauryl acrylate; and
the alkyl methacrylate ester comprises at least one selected from the group consisting of methyl methacrylate, ethyl methacrylate, propyl methacrylate, n-butyl methacrylate, t-butyl methacrylate, n-hexyl methacrylate, cyclohexyl methacrylate, 2-ethylhexyl methacrylate, n-octyl methacrylate, lauryl methacrylate, and isobornyl methacrylate.

8. The adhesive member as recited in claim 1 , wherein the protrusion elements are arranged on the principal surface in a dispersed manner.

9. The adhesive member as recited in claim 8 , wherein at least part of the protrusion elements are arranged on the principal surface in the form of dots.

10. The adhesive member as recited in claim 9 , wherein a maximum diameter of the at least part of the protrusion elements is in the range of 100 μm to 3 mm.

11. The adhesive member as recited in claim 8 , wherein an area ratio of the protrusion elements to the principal surface is 15% or more.

12. The adhesive member as recited in claim 1 , wherein the protrusion elements are arranged on the principal surface in a continuous state.

13. The adhesive member as recited in claim 12 , wherein at least part of the protrusion elements are arranged on the principal surface in the form of a stripe.

14. The adhesive member as recited in claim 13 , wherein each of the at least part of the protrusion elements has a line width of 100 μm or more.

15. The adhesive member as recited in claim 1 , which has a frictional force of about 0.4 N/cm 2 or less, with respect to a stainless steel plate serving as an adherend, as measured when the protrusion elements are in contact with a surface of the adherend.

16. The adhesive member as recited in claim 1 , which has a shear adhesive strength of about 45 N/cm 2 or more, with respect to a stainless steel plate serving as an adherend, as measured under a load of 2 kg.

17. The adhesive member as recited in claim 1 , wherein the pressure-sensitive adhesive layer has a plastic strain of 0.07 or more.

18. The adhesive member as recited in claim 1 , wherein a ratio of a thickness of the pressure-sensitive adhesive layer to a height dimension of each of the protrusion elements is 60 or more : 100.

19. The adhesive member as recited in claim 1 , wherein a height dimension of each of the protrusion elements on the principal surface is in the range of 1 μm to 100 μm.

20. The adhesive member as recited in claim 1 , wherein the support is one selected from the group consisting of a plasterboard, a lumber, a plywood, a steel plate, a tape, a sheet and a film.

21. The adhesive member as recited in claim 1 , wherein the other surface of the support is provided with a second pressure-sensitive adhesive or a curable adhesive.

22. The adhesive member as recited in claim 21 , wherein further comprises a plurality of protrusion elements on a principal surface of a layer of the second pressure-sensitive adhesive which is provided on the other surface of the support.

23. An adhesive member to be adhesively fixed through pressure comprising:
a support;
a pressure-sensitive adhesive layer provided on one surface of the support; and
a plurality of protrusion elements arranged, in spaced-apart relation to each other, on a principal surface of the pressure-sensitive adhesive layer on a side opposite to the support,
wherein the adhesive member to be adhesively fixed through pressure has:
a frictional force of about 0.4 N/cm 2 or less, with respect to a stainless steel plate serving as an adherend, as measured when the protrusion elements are in contact with a surface of the adherend; and
a shear adhesive strength of about 45 N/cm 2 or more, with respect to the stainless steel plate, as measured under a load of 2 kg,

wherein each of the protrusion elements is composed of an aggregation of a plurality of cohesive particles, and
wherein the cohesive particles have an average particle size of 100 nm to 300 nm.

24. The adhesive member as recited in claim 23 , wherein each of protrusion elements has a shear adhesive strength of about 2 N/cm 2 or more, as measured under a load of 500 g.

25. The adhesive member as recited in claim 23 , wherein each of the protrusion elements has an elastic modulus of 5 MPa or more.

26. The adhesive member as recited in claim 23 , wherein each of the plurality of cohesive particles comprises, as its component, alkyl acrylate ester or alkyl methacrylate ester.

27. The adhesive member as recited in claim 23 , wherein each of the plurality of cohesive particles has a core-shell structure made of a resin-based core material, and a resin-based shell material having an elastic modulus greater than that of the core material and wrapping around the core material.

28. The adhesive member as recited in claim 27 , wherein a ratio of a weight of the resin-based core material to a weight of the resin-based shell material is 80% or less.

29. The adhesive member as recited in claim 27 , wherein at least one of the core material and the shell material of the core-shell structure comprises, as its component, alkyl acrylate ester or alkyl methacrylate ester.

30. The adhesive member as recited in claim 29 , wherein:
the alkyl acrylate ester comprises at least one selected from the group consisting of ethyl acrylate, propyl acrylate, n-b

Assignees

• Nitto Denko Corp

Inventors

• Tani Kensuke
• Nagata Mizuho
• Mizobata Kaori
• Soga Masatsugu
• Masuda Ryota
• Satake Masayuki
• Okada Kenichi
• Kosaka Naofumi
• Shimokita Keisuke

Classifications

• C09J7/385 Primary

  Acrylic polymers · CPC title

• C09J7/387

  Block-copolymers · CPC title

• C09J7/203

  characterised by the structure of the release feature on the carrier layer · CPC title

• C09D7/45

  Anti-settling agents · CPC title

• C09J7/38 Primary

  Pressure-sensitive adhesives [PSA] · CPC title