Preparation method of polyurethane resin

Patent metadata

Field	Value
Publication number	US-10570254-B2
Application number	US-201715798401-A
Country	US
Kind code	B2
Filing date	Oct 31, 2017
Priority date	Sep 8, 2017
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

A preparation method of a polyurethane resin including the following steps is provided. A liquid polyamine compound is placed in a continuous reaction system, and the liquid polyamine compound is circulated in the continuous reaction system. A solid bis(cyclic carbonate) and a solid catalyst are placed in the continuous reaction system to mix the solid bis(cyclic carbonate), solid catalyst, and liquid polyamine compound to form a heterogeneous mixture. The heterogeneous mixture is heated in the continuous reaction system in a microwave manner, such that the heterogeneous mixture reacts to form a polyurethane resin.

First claim

What is claimed is:

1. A preparation method of a polyurethane resin, comprising:
placing a liquid polyamine compound in a continuous reaction system and circulating the liquid polyamine compound in the continuous reaction system, wherein the continuous reaction system comprises:
a collection tank used to house the liquid polyamine compound, the solid bis(cyclic carbonate), and the solid catalyst; and
a microwave reactor comprising a reaction chamber and at least one magnetron, wherein the reaction chamber has an inlet and an outlet, the inlet and the outlet are respectively coupled to the collection tank, and the heterogeneous mixture receives a microwave generated by the at least one magnetron in the reaction chamber to be heated;

placing a solid bis(cyclic carbonate) and a solid catalyst in the continuous reactor system to mix the solid bis(cyclic carbonate), the solid catalyst, and the liquid polyamine compound to form a heterogeneous mixture; and
heating the heterogeneous mixture in the continuous reaction system in a microwave manner, such that the heterogeneous mixture reacts to form a polyurethane resin.

2. The preparation method of the polyurethane resin of claim 1 , wherein the continuous reaction system further comprises a first release port located between the outlet of the reaction chamber and the collection tank to remove the polyurethane resin from the first release port.

3. The preparation method of the polyurethane resin of claim 1 , wherein the continuous reaction system further comprises a controller, and the controller is coupled to the at least one magnetron to control a switch and an output power of each of the magnetrons.

4. The preparation method of the polyurethane resin of claim 1 , wherein the continuous reaction system further comprises a pump, and the pump is disposed between the collection tank and the inlet of the reaction chamber to feed the heterogeneous mixture into the reaction chamber.

5. The preparation method of the polyurethane resin of claim 4 , wherein the continuous reaction system further comprises a second release port located between the pump and the collection tank to remove the polyurethane resin from the second release port.

6. The preparation method of the polyurethane resin of claim 1 , wherein the liquid polyamine compound comprises an aliphatic diamine compound, an aromatic diamine compound, a polysiloxane diamine compound, or a combination thereof.

7. The preparation method of the polyurethane resin of claim 1 , wherein the solid bis(cyclic carbonate) comprises a bisphenol A-type pentacyclic carbonate resin, a soybean pentacyclic carbonate resin, or a combination thereof.

8. The preparation method of the polyurethane resin of claim 1 , wherein the solid catalyst comprises a metal halide.

9. The preparation method of the polyurethane resin of claim 1 , wherein a reaction temperature range of the heterogeneous mixture in the continuous reaction system is 100° C. to 150° C.

Assignees

• Univ Nat Tsing Hua
• Chang Chun Plastics Co Ltd
• Chang Chun Petrochemical Co Ltd

Inventors

• Wong David S H
• Chan Kan-Nan
• Yang Ping-Lin
• Tu An-Pang
• Lee En-Ko

Classifications

• B01J2208/00442

  Microwaves · CPC title

• B01J8/20

  with liquid as a fluidising medium · CPC title

• B01J2219/1215

  Single reactor · CPC title

• C08G71/04 Primary

  Polyurethanes · CPC title

• B01J8/1836

  Heating and cooling the reactor (B01J8/42 takes precedence) · CPC title