Titanium oxide aerogel composites

Patent metadata

Field	Value
Publication number	US-10569248-B2
Application number	US-201414773431-A
Country	US
Kind code	B2
Filing date	Mar 6, 2014
Priority date	Mar 6, 2013
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

The invention relates to titanium oxide aerogels, in particular to titanium oxide binary or ternary (e.g. titanium oxide-carbon) aerogel monoliths possessing ordered meso- and macroporosity. The porous scaffold can be made with or without addition of binders and/or surfactants. The aerogel obtained by this method has a specific surface area greater than 60 m2/g and porosity larger than 60%. The surface area ranges from 60 to 300 m2/g. The porosity can reach as high as 99.6%. The size of the titanium oxide crystals are between 5 nm and 100 nm. The aerogel contains 100% titanium oxide. The composite (binary or ternary) aerogel can be prepared by adding at least 10% carbon in the form of (carbon nanotubes, carbon nanofibers, carbon microfibers, exfoliated graphene, cellulose fibers, polymer fibers, metallic and metal oxide nano and microfibers etc.). The aerogel can be prepared with a predeterminable shape. It can be shaped in a mold having a shape of a cylinder, cube, sheet or sphere. The aerogel can be also transformed into a supported or self-standing film with a thickness. The material can be used as a self-cleaning filter e.g. in a solar-thermal water and air purification system, in mesoscopic solar cells e.g. dye sensitized solar cells, multifunctional filler in polymer composites, in ceramics, in metals, thermoelectric material to convert (waste) heat into electricity, heat insulation material and electrode material in lithium ion batteries and supercapacitors.

First claim

The invention claimed is:

1. An aerogel comprising at least 90% titanium oxide and having a porosity of at least 90%,
wherein crystallites of the titanium oxide are between 5 nm and 100 nm, and the crystallites assemble into elongated particles of several micrometers in length.

2. The aerogel according to claim 1 wherein the porosity is between 90% and 99.6%.

3. The aerogel according to claim 2 comprising 100% of titanium oxide.

4. The aerogel according to claim 1 having a specific surface area greater than 60 m 2 /g, wherein the aerogel is obtained by turbulent mixing of a titanium compound.

5. The aerogel according to claim 4 wherein the turbulent mixing is achieved with an external mixer with a brush with 300-2500 rpm.

6. A mesoscopic solar cell including an aerogel as defined in claim 1 .

7. A multifunctional filler including an aerogel as defined in claim 1 .

8. A thermoelectric material including an aerogel as defined in claim 1 .

9. A heat insulation material including an aerogel as defined in claim 1 .

10. An anode material for lithium ion batteries including an aerogel as defined in claim 1 .

11. A supercapacitor including an aerogel as defined in claim 1 .

12. A self-cleaning filter including an aerogel as defined in claim 1 .

13. The aerogel according to claim 1 , wherein at least 10% of the aerogel has slit shaped mesopores.

14. The aerogel according to claim 1 , wherein the aerogel includes at least 1% of carbon nanotubes, and wherein the carbon nanotubes and the titanium oxide form an interpenetrating structure.

15. A process for aerogel manufacturing comprising:
adding a titanium compound to a base solution having a concentration of 1-20 M,
turbulently mixing the titanium compound that is in the base solution,
thereby manufacturing an aerogel comprising at least 90% titanium oxide and having a porosity of at least 90%,
wherein crystallites of the titanium oxide are between 5 nm and 100 nm, and the crystallites assemble into elongated particles of several micrometers in length.

16. The process according to claim 15 wherein the turbulent mixing is achieved with an external mixer with a brush with 300-2500 rpm.

17. A method for controlling the porosity of an aerogel, the method comprising:
providing an initial aerogel product having a specific porosity,
applying a pressure on the aerogel product in order to reduce a volume,
such that the aerogel product comprises at least 90% titanium oxide and has a porosity of at least 90%, and wherein crystallites of the titanium oxide are between 5 nm and 100 nm, and the crystallites assemble into elongated particles of several micrometers in length.

18. The method according to claim 17 further comprising:
applying the pressure with a surface structured tool to create micro- and nanosized features on the product.

Assignees

• Ecole Polytechnique Fed Lausanne Epfl

Inventors

• Horváth Endre
• Forró László
• Magrez Arnaud

Classifications

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• Y02E10/542

  Dye sensitized solar cells · CPC title

• H01B1/08

  oxides · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2002/50

  Solid solutions · CPC title