Systems and methods for separating hydrogen sulfide from carbon dioxide in a high-pressure mixed stream

Patent metadata

Field	Value
Publication number	US-10569219-B2
Application number	US-201615219882-A
Country	US
Kind code	B2
Filing date	Jul 26, 2016
Priority date	Sep 21, 2015
Publication date	Feb 25, 2020
Grant date	Feb 25, 2020

Abstract

Systems and methods for separating hydrogen sulfide from carbon dioxide in a high-pressure mixed stream are disclosed herein. The methods include receiving the high-pressure mixed stream in an oxidation reactor and at an inlet pressure of at least 0.3 megapascals. The high-pressure mixed stream includes 0.01 to 5 mole percent hydrogen sulfide and at least 90 mole percent carbon dioxide. The methods further include oxidizing the high-pressure mixed stream with an oxidant to generate a high-pressure oxidized stream, includes oxidized hydrogen sulfide and carbon dioxide, at an oxidation pressure of at least 0.3 megapascals. The methods also include separating the high-pressure oxidized stream into an oxidized hydrogen sulfide product and a carbon dioxide product and generating the carbon dioxide product at a pressure of at least 0.3 megapascals. The systems include the high-pressure mixed stream, an oxidation reactor, and a separation assembly.

First claim

The invention claimed is:

1. A method of separating hydrogen sulfide from carbon dioxide in a high-pressure mixed stream, the method comprising:
receiving the high-pressure mixed stream in an oxidation reactor, wherein the high-pressure mixed stream includes 0.01 to 5 mole percent hydrogen sulfide and at least 90 mole percent carbon dioxide, and further wherein the receiving includes receiving the high-pressure mixed stream at an inlet pressure of at least 3 megapascals;
oxidizing the high-pressure mixed stream with an oxidant to generate a high-pressure oxidized stream that includes oxidized hydrogen sulfide and carbon dioxide, wherein the oxidizing includes oxidizing at an oxidation pressure of at least 3 megapascals, wherein the oxidizing includes oxidizing with less than a stoichiometric amount of the oxidant such that at least one of:
(i) the high-pressure oxidized stream includes at least a threshold amount of hydrogen sulfide; and
(ii) the high-pressure oxidized stream includes less than 0.01 mole percent of the oxidant; and
subsequent to the oxidizing, separating the high-pressure oxidized stream into an oxidized hydrogen sulfide product and a carbon dioxide product, wherein the separating the high-pressure oxidized stream includes separating at a separation pressure of at least 3 megapascals, and further wherein the separating the high-pressure oxidized stream includes generating the carbon dioxide product at a carbon dioxide product pressure of at least 3 megapascals;
injecting the carbon dioxide product into a subterranean formation.

2. The method of claim 1 , wherein the injecting includes injecting as part of an enhanced oil recovery process, and further wherein, subsequent and at least partially responsive to the injecting, the method includes producing a product hydrocarbon stream from the subterranean formation.

3. The method of claim 1 , wherein, subsequent to the separating the high-pressure oxidized stream and prior to the injecting, the method further includes pressurizing the carbon dioxide product to an injection pressure of at least 6.5 megapascals.

4. The method of claim 3 , wherein at least one of:
(i) the carbon dioxide product is a liquid carbon dioxide product, and further wherein the pressurizing includes pressurizing the liquid carbon dioxide product; and
(ii) the carbon dioxide product is a supercritical carbon dioxide product, and further wherein the pressurizing includes pressurizing the supercritical carbon dioxide product.

5. The method of claim 1 , wherein the oxidizing includes oxidizing hydrogen sulfide to at least one of elemental sulfur and sulfur dioxide.

6. The method of claim 5 , wherein the oxidizing further includes limiting oxidation of the hydrogen sulfide to sulfur dioxide by regulating a concentration of oxidant within the oxidation reactor.

7. The method of claim 5 , wherein the oxidizing further includes regulating an oxidation temperature within the oxidation reactor to limit oxidation of the hydrogen sulfide to sulfur dioxide, wherein the regulating the oxidation temperature includes at least one of:
(i) increasing the temperature within the oxidation reactor responsive to the temperature within the oxidation reactor being less than a lower threshold oxidation temperature;
(ii) decreasing the temperature within the oxidation reactor responsive to the temperature within the oxidation reactor being greater than an upper threshold oxidation temperature;
(iii) increasing the temperature within the oxidation reactor responsive to a concentration of sulfur dioxide within the high-pressure oxidized stream being less than 1 percent of an initial hydrogen sulfide concentration within the high-pressure mixed stream; and
(iv) decreasing the temperature within the oxidation reactor responsive to the concentration of sulfur dioxide within the high-pressure oxidized stream being greater than 5 percent of the initial hydrogen sulfide concentration.

8. The method of claim 1 , wherein the oxidizing includes oxidizing within an oxidation catalyst bed.

9. The method of claim 1 , wherein the oxidizing includes oxidizing via a catalytic direct oxidation process.

10. The method of claim 9 , wherein the oxidant includes oxygen gas.

11. The method of claim 1 , wherein the oxidant is a reactant that includes iron oxide, and further wherein the high-pressure mixed stream includes less than 1 mole percent hydrogen sulfide.

12. The method of claim 1 , wherein the oxidant includes a liquid oxidant, and further wherein the high-pressure mixed stream includes greater than 1 mole percent hydrogen sulfide.

13. The method of claim 1 , wherein, subsequent to the separating the high-pressure oxidized stream, the method further includes decreasing a residual concentration of hydrogen sulfide within the carbon dioxide product to less than 0.01 mole percent.

14. The method of claim 1 , wherein the method further includes providing the oxidant to the oxidation reactor.

15. The method of claim 14 , wherein the method further includes monitoring a concentration of the oxidant in the high-pressure oxidized stream, and further wherein the method includes at least one of:
(i) increasing a flow rate of the oxidant to the oxidation reactor responsive to the concentration of the oxidant in the high-pressure oxidized stream being less than a threshold minimum oxidant concentration; and
(ii) decreasing the flow rate of the oxidant to the oxidation reactor responsive to the concentration of the oxidant in the high-pressure oxidized stream being greater than a threshold maximum oxidant concentration.

16. The method of claim 1 , wherein the method includes performing at least the receiving, the oxidizing, and the separating the high-pressure oxidized stream without at least one of:
(i) compressing the carbon dioxide; and
(ii) mechanically increasing a pressure of the carbon dioxide.

17. A system for separating hydrogen sulfide from carbon dioxide in a high-pressure mixed stream, the system comprising:
the high-pressure mixed stream, which includes 0.01 to 5 mole percent hydrogen sulfide and at least 90 mole percent carbon dioxide and has a threshold pressure of at least 3 megapascals;
an oxidation reactor configured to receive the high-pressure mixed stream and to oxidize the high-pressure mixed stream with an oxidant to generate a high-pressure oxidized stream that includes oxidized hydrogen sulfide and carbon dioxide and has the threshold pressure, wherein the oxidizing includes oxidizing with less than a stoichiometric amount of the oxidant such that at least one of:
(i) the high-pressure oxidized stream includes at least a threshold amount of hydrogen sulfide; and
(ii) the high-pressure oxidized stream includes less than 0.01 mole percent of the oxidant; and
a separation assembly configured to separate the high-pressure oxidized stream into an oxidized hydrogen sulfide product and a carbon dioxide product, wherein the carbon dioxide product has the threshold pressure,
wherein the system further includes injecting the carbon dioxide product into a subterranean formation.

18. The system of claim 17 , wherein the system further includes an injection assembly configured to inject the carbon dioxide product into an injection well that extends within a subterranean formation.

19. The system of claim 18 , wherein the system further includes a production well configured to produce a product hydrocarbon stream from the subterranean formation.

20. The system of claim 18 , wherein the injection assembl

Assignees

• Northrop P Scott
• Exxonmobil Upstream Res Co

Inventors

• Northrop P Scott

Classifications

• C09K8/594

  Compositions used in combination with injected gas {, e.g. CO2 orcarbonated gas}(C09K8/592 takes precedence) · CPC title

• B01D53/8612

  Hydrogen sulfide · CPC title

• B01D2255/20707

  Titanium · CPC title

• B01D2256/22

  Carbon dioxide · CPC title

• C01B17/0404

  by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process · CPC title