Lithium sulfur nitrogen compound for anode barrier coating or solid electrolyte

Patent metadata

Field	Value
Publication number	US-10566653-B2
Application number	US-201615143241-A
Country	US
Kind code	B2
Filing date	Apr 29, 2016
Priority date	Aug 14, 2015
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

Provided is a lithium-conductive solid-state electrolyte material that comprises a sulfide compound of a composition that does not deviate substantially from a formula of Li9S3N. The compound's conductivity is greater than about 1×10−7 S/cm at about 25° C. and is in contact with a negative electroactive material. Also provided is an electrochemical cell that includes an anode layer, a cathode layer, and the electrolyte layer between the anode and cathode layers. In an example, the material's activation energy can be no greater than about 0.52 eV at about 25° C.

First claim

We claim:

1. A battery comprising:
a cathode;
a barrier layer comprising a sulfide compound having a formula of Li 9 S 3 N;
an anode comprising an anode material electrically coupled to the sulfide compound; and
an electrolyte layer comprising the sulfide compound,
wherein the electrolyte layer is between the cathode and the anode, and the barrier layer is between the electrolyte layer and the anode, and
wherein an electrically conductive pathway is present between the sulfide compound and the anode material.

2. The battery of claim 1 , wherein the sulfide compound has a conductivity greater than about 5×10 −7 S/cm at about 25° C.

3. The battery of claim 2 , wherein the conductivity of the sulfide compound is greater than about 1×10 −6 S/cm.

4. The battery of claim 1 , wherein the sulfide compound is in contact with metallic lithium at a temperature lower than a melting temperature for metallic lithium.

5. The battery of claim 1 , wherein the sulfide compound is in contact with a lithiated material having a voltage within about 400 mV from metallic lithium's voltage.

6. The battery of claim 1 , wherein the sulfide compound is present in an anode barrier coating.

7. The battery of claim 1 , wherein the sulfide compound is present in an electrolyte.

8. The battery of claim 1 , wherein the sulfide compound has a conductivity of at least 1.0×10 −4 S/cm at a temperature of about 300K.

Assignees

• Samsung Electronics Co Ltd
• Massachusetts Inst Technology

Inventors

• Miara Lincoln J
• Suzuki Naoki
• Richards William D
• Wang Yan E
• Kim Jae Chul
• Ceder Gerbrand

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0562 Primary

  Solid materials · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• Y02T10/7011

  Cross-Sectional Technologies · mapped topic