Microbattery

Patent metadata

Field	Value
Publication number	US-10566617-B2
Application number	US-201615554062-A
Country	US
Kind code	B2
Filing date	Mar 2, 2016
Priority date	Mar 2, 2015
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

Disclosed is a microbattery having a substrate with a surface that includes an array of posts extending from the surface of the substrate to form a first electrode. An selectively-cured electrolyte forms a conformal coating over the surface of the substrate and the array of posts to provide a coated electrode. A second electrode substantially encases the coated electrode.

First claim

What is claimed is:

1. A microbattery comprising:
a substrate having a surface;
an array of posts extending from the surface of the substrate to form a first electrode;
a selectively-cured electrolyte that forms a conformal coating over the surface of the substrate and the array of posts to provide a coated electrode, wherein the selectively-cured electrolyte is a cured photoresist that comprises bisphenol A Novolac epoxy; and
a second electrode that substantially encases the coated electrode.

2. The microbattery of claim 1 wherein the selectively-cured electrolyte is a cured negative photoresist comprised of crosslinked epoxy.

3. The microbattery of claim 1 wherein an organic solvent of the bisphenol A Novolac epoxy is cyclopentanone.

4. The microbattery of claim 1 wherein the first electrode is made of silicon.

5. The microbattery of claim 1 wherein the first electrode has an electrical resistivity that ranges from around 0.001 Ω-cm to about 0.005 Ω-cm.

6. The microbattery of claim 1 wherein the first electrode has an electrical resistivity that ranges from 0.005 Ω-cm to about 0.1 Ω-cm.

7. The microbattery of claim 1 wherein the first electrode has an electrical resistivity that ranges from 0.1 Ω-cm to about 20 Ω-cm.

8. The microbattery of claim 1 wherein the first electrode is made of a lithium-storing metallic alloy.

9. The microbattery of claim 1 wherein the selectively-cured electrolyte is soaked in liquid electrolyte to increase ionic conductivity of the selectively-cured electrolyte.

10. The microbattery of claim 1 wherein the selectively-cured electrolyte includes pores in the range of 1 nm to about 10 nm to allow ingress of liquid electrolytes.

11. The microbattery of claim 1 wherein the selectively-cured electrolyte includes pores in the range of 10 nm to 100 nm to allow ingress of liquid electrolytes.

12. The microbattery of claim 1 wherein the second electrode comprises a composite mixture of active lithium-storage materials, ionically conducting materials, and electrically conductive materials.

13. The microbattery of claim 1 wherein the first electrode is made of germanium.

14. The microbattery of claim 1 wherein an areal energy density of around 42 mWh/cm 2 with around a 3 V working voltage is stored by the microbattery.

15. The microbattery of claim 1 wherein a volumetric energy density of around 850 mWh/cm 3 with around a 3 V working voltage is stored by the microbattery.

16. The microbattery of claim 1 wherein the array of posts has a pitch between posts that ranges from around 20 μm to around 2000 μm.

17. The microbattery of claim 16 wherein the pitch between posts has a minimum value that is around twice a diameter of each post making up the array of posts.

18. The microbattery of claim 1 wherein a diameter of each post of the array of posts ranges from about 10 μm to about 100 μm.

19. The microbattery of claim 1 wherein a diameter of each post of the array of posts ranges from 100 μm to about 300 μm.

20. The microbattery of claim 1 wherein a diameter of each post of the array of posts ranges from 300 μm to about 500 μm.

21. The microbattery of claim 1 wherein a diameter of each post of the array of posts ranges from 500 μm to about 1000 μm.

22. The microbattery of claim 1 wherein each post of the array of posts ranges in height from around 350 μm to around 450 μm.

23. The microbattery of claim 1 wherein each post of the array of posts ranges in height from around 100 μm to about 350 μm.

24. The microbattery of claim 1 wherein each post of the array of posts ranges in height from 350 μm to around 1000 μm.

25. The microbattery of claim 1 wherein a length of the first electrode and a width of the first electrode both range from about 1 mm to around 10 mm.

26. The microbattery of claim 1 wherein a length of the first electrode and a width of the first electrode both range from 10 mm to around 100 mm.

27. The microbattery of claim 1 wherein geometries of the first electrode include shapes in which a length of the first electrode is substantially unequal from a width of the first electrode.

28. A method for making a microbattery comprising:
providing a substrate;
fabricating an array of posts into the substrate to form a first electrode and leaving an etched surface about the array of posts;
coating the array of posts and the etched surface with a conformal coat of selectively-curable electrolyte;
curing the selectively-curable electrolyte to form a selectively cured electrolyte, wherein the selectively cured electrolyte is a cured photoresist that comprises bisphenol A Novolac epoxy; and
providing a second electrode that substantially encases the array of posts.

29. The method of making the microbattery of claim 28 wherein fabricating the array of posts is achieved by way of etching.

30. The method of making the microbattery of claim 29 further comprising patterning the substrate with an etch resist pattern of the array of posts before etching.

31. The method of making the microbattery of claim 29 wherein etching the array of posts is performed using deep-reactive ion etching (DRIE).

32. The method of making the microbattery of claim 28 further including cyclic charging and discharging the array of posts to 10% of 3700 mAh/gram.

33. The method of making the microbattery of claim 28 wherein the substrate has an electrical resistivity that ranges from around 0.001 Ω-cm to around 0.005 Ω-cm.

34. The method of making the microbattery of claim 28 wherein the first electrode has an electrical resistivity that ranges from 0.005 Ω-cm to about 0.1 Ω-cm.

35. The method of making the microbattery of claim 28 wherein the first electrode has an electrical resistivity that ranges from 0.1 Ω-cm to about 20 Ω-cm.

36. The method of making the microbattery of claim 28 further including soft baking a conformal coat of selectively-cured electrolyte before subjecting the energy-curable electrolyte to energy.

37. The method of making the microbattery of claim 28 wherein energy used to cure the selectively-curable electrolyte is ultra-violet (UV) light.

38. The method of making the microbattery of claim 28 wherein energy used to cure the selectively-curable electrolyte is heat energy.

39. The method of making the microbattery of claim 28 wherein chemical reaction curing is used to cure the selectively-curable electrolyte.

40. The method of making the microbattery of claim 28 wherein the selectively-curable electrolyte is a negative photoresist.

41. The method of making the microbattery of claim 28 further including soaking the array of posts with selectively-cured electrolyte in a liquid electrolyte.

42. The method of making the microbattery of claim 41 wherein the liquid electrolyte is propylene carbonate that contains 1 molar lithium perchlorate (LiClO 4 ).

43. The method of making the microbattery of claim 28 wherein the second electrode comprises a composite mixture of active lithium-storage materials, ionically conducting materials, and electrically conductive materials.

44. The method of m

Assignees

• Univ California

Inventors

• Hur Janet
• Smith Leland
• Dunn Bruce S
• Kim Chang-Jin

Classifications

• H01M4/0407

  by coating on an electrolyte layer · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/386 Primary

  Silicon or alloys based on silicon · CPC title