Battery and method for producing a battery

Patent metadata

Field	Value
Publication number	US-10566615-B2
Application number	US-201615186912-A
Country	US
Kind code	B2
Filing date	Jun 20, 2016
Priority date	Dec 23, 2013
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

A method is disclosed for producing a battery preparing a first electrode by providing a substrate and depositing onto the substrate at least one silicon-based semiconductor layer of a specific porosity, in particular a doped micro-crystalline silicon layer that may comprise additions of Ge, Sn and/or C; treating the semiconductor layer using laser radiation for fully or partially varying the porosity, in particular by increasing the porosity of active regions for accommodating ions, in particular lithium-ions, or for reducing the porosity of inactive regions, for decreasing the ion-absorption capacity; arranging the first electrode together with a second electrode and an electrolyte within a housing; and contacting the two electrodes and connecting with external terminals accessible from outside the housing. Also disclosed is a battery made according to the disclosed method.

First claim

What is claimed is:

1. A method for producing a battery, comprising the steps of:
(a) preparing a first electrode by providing a substrate and depositing onto said substrate at least one silicon-based semiconductor layer of a specific porosity greater than zero, wherein the semiconductor layer includes gases and is of a specific doping;
(b) treating said semiconductor layer using laser radiation for micro-stabilizing said semiconductor layer by freeing the gases contained within said semiconductor layer to thereby increase said porosity of said semiconductor layer locally for generating active porous regions having a locally increased ion intake capacity;
(c) arranging said first electrode together with a second electrode and an electrolyte within a housing; and
(d) contacting said two electrodes and connecting with external terminals accessible from outside said housing.

2. The method of claim 1 , wherein said micro-stabilized semiconductor layer is a thin layer provided with a p-type or n-type doping being selected from the group consisting of nitrogen, phosphorous, arsenic, antimony, boron, aluminum, gallium and indium.

3. The method of claim 1 , wherein said semiconductor layer is locally irradiated by laser radiation to generate pores.

4. The method of claim 1 , wherein in step (a) a doping layer is deposited on the surface of the semiconductor layer, and in step (b) a local doping is generated by means of laser radiation, said local doping having a different ion-absorption capacity than any remaining regions of said semiconductor layer.

5. The method of claim 1 , wherein said semiconductor layer is irradiated by means of a laser for generating locally strengthened grid points by local laser crystallization.

6. The method of claim 1 , wherein said semiconductor layer in the shape of a three-dimensional skeleton having a grid width of 0.5 to 100 micrometers, is micro-stabilized.

7. The method of claim 1 , wherein said semiconductor layer is deposited by spraying, printing, or by a vacuum deposition method.

8. The method of claim 7 , wherein said semiconductor layer is deposited by means of PECVD using an excitation frequency in the range of 10 kHz to 500 MHz, or in the microwave range.

9. The method of claim 1 , wherein said electrode is combined with a second electrode configured as an air-cathode for generating a primary battery.

10. The method of claim 1 , wherein said battery is produced as a secondary battery, wherein between said electrodes a separator is arranged.

11. The method of claim 1 , wherein an alkaline electrolyte material is used for preparing said electrolyte.

12. The method of claim 1 , wherein a non-aqueous electrolyte material is used for preparing said electrolyte, said non-aqueous electrolyte material being selected from the group consisting of an ion-liquid, a mixture of a non-ion containing polar solvent and a cation and an anion, a conductive polymer, an oxidic ceramic, and mixtures thereof.

13. The method of claim 1 , wherein a flexible carrier material is provided which is soaked with an electrolyte material.

14. The method of claim 1 , wherein a gel is used for preparing said electrolyte.

Assignees

• Univ Stuttgart

Inventors

• Werner Juergen H
• Schubert Markus
• Koehler Juergen
• Garamoun Ahmed
• Saemann Christian

Classifications

• H01M4/661

  Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title

• H01M12/06

  with one metallic and one gaseous electrode · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/386 Primary

  Silicon or alloys based on silicon · CPC title