Image sensor, stacked imaging device and imaging module

Patent metadata

Field	Value
Publication number	US-10566548-B2
Application number	US-201615572609-A
Country	US
Kind code	B2
Filing date	Apr 19, 2016
Priority date	May 19, 2015
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

An image sensor includes at least a first electrode, a second electrode, an organic photoelectric conversion layer, and a carrier blocking layer. The carrier blocking layer is formed of a material having the following structural formula (1), and has a thickness of from 5×10 −9 to 1.5×10 −7 m:

First claim

What is claimed is:

1. An image sensor comprising at least:
a first electrode;
a second electrode;
an organic photoelectric conversion layer; and
a carrier blocking layer,
wherein the carrier blocking layer is formed of a material having the following structural formula (1), and has a thickness of from 5×10 −9 to 1.5×10 −7 m:

wherein R 1 and R 2 are independently a group selected from H, an aryl group and an alkyl group,
the aryl group is a group selected from the group consisting of phenyl, biphenyl, terphenyl, naphthyl, naphthylphenyl, tolyl, xylyl, C 2 -C 6 alkyl-substituted phenyl, anthracenyl, anthracenylphenyl, phenanthryl, phenanthrylphenyl, pyrenyl, pyrenylphenyl, tetracenyl, tetracenylphenyl, fluoranthenyl, fluoranthenylphenyl, pyridinyl, pyridinylphenyl, quinolinyl, quinolylphenyl, acridinyl, acridinylphenyl, indol, indolylphenyl, imidazol, imidazolylphenyl, benzimidazole, benzimidazolylphenyl, thienyl, and thienyelphenyl,
the alkyl group is a group selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, and hexyl, which is a straight-chain alkyl group or a branched alkyl group, and
the second electrode is formed of a transparent conductive material, and the first electrode is formed of Al—Nd or ASC.

2. The image sensor according to claim 1 , wherein the first electrode serves as a cathode, and the second electrode serves as an anode, and the carrier blocking layer is arranged between the first electrode and the organic photoelectric conversion layer.

3. The image sensor according to claim 1 , wherein the carrier blocking layer has a light absorbance of 3% or less at 450 nm wavelength, 30% or less at 425 nm wavelength, and 80% or less at 400 nm wavelength.

4. The image sensor according to claim 1 , wherein the carrier blocking layer is formed of a material having a carrier mobility of 9×10 −4 cm 2 /V·s or higher.

5. The image sensor according to claim 1 , wherein when light of 560 nm wavelength is irradiated at 2 μW/cm 2 while applying −3 V between the second electrode and the first electrode and the irradiation of light is then stopped, T 0 is 10 milliseconds or less where T 0 is a time from a stop of the irradiation of light until a quantity of current decreases to 0.03×I 0 (I 0 : quantity of current flowing between the second electrode and the first electrode immediately before the stop of the irradiation of light).

6. A stacked imaging device comprising at least:
two image sensors as defined in claim 1 .

7. An imaging module comprising:
a plurality of image sensors as defined in claim 1 .

8. An imaging module comprising:
a plurality of stacked imaging devices as defined in claim 6 .

9. An image sensor comprising at least:
a first electrode;
a second electrode;
an organic photoelectric conversion layer; and
a carrier blocking layer,
wherein the carrier blocking layer is formed of a material having the following structural formula (2), and has a thickness of from 5×10 −9 to 1.5×10 −7 m:

wherein Ar 1 and Ar 2 are independently a substituted or unsubstituted aryl group, which is selected from the group consisting of phenyl, biphenyl, terphenyl, naphthyl, naphthylphenyl, tolyl, xylyl, C 2 -C 6 alkyl-substituted phenyl, anthracenyl, anthracenylphenyl, phenanthryl, phenanthrylphenyl, pyrenyl, pyrenylphenyl, tetracenyl, tetracenylphenyl, fluoranthenyl, fluoranthenylphenyl, pyridinyl, pyridinylphenyl, quinolinyl, quinolylphenyl, acridinyl, acridinylphenyl, indol, indolylphenyl, imidazol, imidazolylphenyl, benzimidazole, benzimidazolylphenyl, thienyl, and thienyelphenyl, and
the second electrode is formed of a transparent conductive material, and the first electrode is formed of Al—Nd or ASC.

10. An image sensor comprising at least:
a first electrode;
a second electrode;
an organic photoelectric conversion layer; and
a carrier blocking layer,

wherein the carrier blocking layer is formed of a material having the following structural formula (3), and has a thickness of from 5×10 −9 to 1.5×10 −7 m:

and
the second electrode is formed of a transparent conductive material, and the first electrode is formed of Al—Nd or ASC.

Assignees

• Sony Corp

Inventors

• Ujiie Yasuharu
• Murata Masaki
• Kumagai Yuya
• Mogi Hideaki
• HIRATA Shintarou

Classifications

• C07D495/04

  Ortho-condensed systems · CPC title

• H01B1/12

  organic substances {(organic macromolecular compounds or compositions C08)} · CPC title

• H01L2251/301

  Electricity · mapped topic

• H01L51/0074 Primary

  Electricity · mapped topic

• H01L51/0058

  Electricity · mapped topic