Optical layered body

Patent metadata

Field	Value
Publication number	US-10564324-B2
Application number	US-201716317388-A
Country	US
Kind code	B2
Filing date	Jul 10, 2017
Priority date	Jul 13, 2016
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

The present invention aims to provide an optical layered body that has excellent interlayer adhesiveness, particularly even in outdoor use, and also has highly excellent anti-blocking properties. The present invention relates to an optical layered body including: a substrate film; a hard coat layer containing silica fine particles on at least one surface of the substrate film; and a dry film layer on a surface of the hard coat layer opposite to the substrate film side surface of the hard coat layer, wherein the silica fine particles are exposed on the dry film layer side surface of the hard coat layer; the dry film layer is directly formed on the surface of the hard coat layer on which the silica fine particles are exposed; the hard coat layer before the formation of the dry film layer has projections and depressions on the surface on which the dry film layer is to be formed; the hard coat layer has an average silica fine particle abundance in ten 0.2 μm×0.2 μm regions of 30 to 80% and a standard deviation of silica fine particle abundances in the 10 regions of 1 to 7, where the 10 regions are randomly selected from a cross section of the hard coat layer in the thickness direction within the range from the dry film layer side interface to 10% of the thickness in the thickness direction; and the hard coat layer has a silicon atom abundance A of 2 to 10% on the surface opposite to the substrate film side surface as determined by X-ray photoelectron spectroscopy.

First claim

The invention claimed is:

1. An optical layered body comprising:
a substrate film;
a hard coat layer containing silica fine particles on at least one surface of the substrate film; and
a dry film layer on a surface of the hard coat layer opposite to the substrate film side surface of the hard coat layer,
wherein the silica fine particles are exposed on the dry film layer side surface of the hard coat layer;
the dry film layer is directly formed on the surface of the hard coat layer on which the silica fine particles are exposed;
the hard coat layer before the formation of the dry film layer has projections and depressions on the surface on which the dry film layer is to be formed;
the hard coat layer has an average silica fine particle abundance in ten 0.2 μm×0.2 μm regions of 30 to 80% and a standard deviation of silica fine particle abundances in the 10 regions of 1 to 7, where the 10 regions are randomly selected from a cross section of the hard coat layer in the thickness direction within the range from the dry film layer side interface to 10% of the thickness in the thickness direction; and
the hard coat layer has a silicon atom abundance A of 3 to 10% on the surface opposite to the substrate film side surface as determined by X-ray photoelectron spectroscopy.

2. The optical layered body according to claim 1 ,
wherein the hard coat layer before the formation of the dry film layer has, on the surface on which the dry film layer is to be formed, an arithmetic average roughness Ra of the projections and depressions of 0.5 to 7.0 nm as determined in a 1 μm×1 μm measurement field of view, has an average inter-projection distance of the projections and depressions of 10 to 150 nm and a standard deviation of inter-projection distances of the projections and depressions of 40 nm or smaller, and have an arithmetic average roughness Ra of the projections and depressions of 0.5 to 7.0 nm as determined in a 0.12 mm×0.12 mm measurement field of view.

3. The optical layered body according to claim 1 ,
wherein the hard coat layer contains at least one selected from the group consisting of a silicon atom-containing organic compound and an ultraviolet absorber.

4. The optical layered body according to claim 3 ,
wherein the silicon atom-containing organic compound is a reactive silicon atom-containing organic compound.

5. The optical layered body according to claim 3 ,
wherein the ultraviolet absorber is a monomer-type ultraviolet absorber having a weight average molecular weight of 220 to 1100.

6. The optical layered body according to claim 1 ,
wherein the dry film layer includes a total of four or more alternately stacked high refractive index layers and low refractive index layers, the high refractive index layers having a refractive index of 2.2 to 2.4 and the low refractive index layers having a refractive index of 1.43 to 1.53.

Assignees

• Dainippon Printing Co Ltd
• Dexerials Corp

Inventors

• Horio Tomoyuki
• Nakashima Masataka
• Nakamura Hiroshi
• Nomura Takahisa
• Shinohara Seiji
• Matsui Kiyotaka
• Oshima Kentaro
• Kuboyama Satoshi
• Ono Yukihiro

Classifications

• B32B23/08

  of synthetic resin · CPC title

• G02B1/14

  Protective coatings, e.g. hard coatings · CPC title

• G02B5/003

  Light absorbing elements · CPC title

• B32B27/18

  characterised by the use of special additives · CPC title

• G02B1/115 Primary

  Multilayers · CPC title