Active layer/membrane arrangement for a hydrogen production device and assembly comprising said arrangement suitable for a porous current collector and method for producing the arrangement

Patent metadata

Field	Value
Publication number	US-10563313-B2
Application number	US-201414910987-A
Country	US
Kind code	B2
Filing date	Jul 16, 2014
Priority date	Aug 23, 2013
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

An active layer/membrane assembly to be incorporated into a hydrogen production device comprises an active layer in contact with a membrane capable of exchanging ions, the active layer comprising catalyst particles and particles referred to as support particles, wherein the size of the support particles is greater than the thickness of the active layer, so that the support particles emerge from the active layer, at the surface opposite the surface in contact with the membrane. A unit comprising the assembly and a porous current collector, the assembly and the collector having a complementarity of surface finish is provided. A process for manufacturing the assembly is also provided.

First claim

The invention claimed is:

1. An active layer/membrane assembly intended to be incorporated into a hydrogen production device, said assembly comprising:
a collector;
an active layer in contact with a membrane capable of exchanging ions, said active layer comprising catalyst particles;
wherein the catalyst particles are particles based on iridium, or on iridium oxide; and
support particles in contact with the active layer;
wherein the support particles are titanium particles;
wherein at least one of the support particles is large enough to be partially incorporated in said active layer so that a portion of the at least one of said support particles emerges from a surface of said active layer in contact with the collector while a remaining portion of the least one of the support particles is within said active layer, wherein a size of the at least one support particle is larger than a thickness of said active layer;
wherein the surface of said active layer in contact with the collector is opposite to a surface of said active layer in contact with said membrane.

2. The active layer/membrane assembly as claimed in claim 1 , wherein the support particles have a size of greater than 1.2 micron, the thickness of the active layer being of the order of a micron.

3. The active layer/membrane assembly as claimed in claim 1 , wherein the membrane capable of exchanging ions comprises an ionomer.

4. The active layer/membrane assembly as claimed in claim 1 , wherein the degree of catalyst loading of said active layer is less than around 0.3 mg/cm 2 .

5. A unit comprising an active layer/membrane assembly as claimed in claim 1 , said collector having pores with a porosity such that the support particles emerging from said active layer penetrate at the surface into the pores of said collector.

6. The unit as claimed in claim 5 , wherein said collector is a porous titanium material.

7. The unit as claimed in claim 5 , wherein said collector is an assembly of grids.

8. A process for manufacturing an assembly as claimed in claim 1 , comprising:
the deposition of an active layer and particles referred to as support particles onto a membrane capable of exchanging ions;
contacting the active layer and particles with a collector on a side opposite the membrane capable of exchanging ions;
wherein the active layer comprises catalyst particles based on iridium, or on iridium oxide;
wherein the support particles comprise titanium particles;
wherein at least one of the support particles is large enough to be partially incorporated in said active layer so that a portion of the at least one of said support particles emerges from a surface of said active layer in contact with the collector while a remaining portion of the least one of the support particles is within said active layer, wherein a size of the at least one support particle is larger than a thickness of said active layer.

9. The process for manufacturing an assembly as claimed in claim 8 , wherein the production of said deposited active layer and particles comprises the production of an ink added to said membrane capable of exchanging ions, said ink comprising a powder of said catalyst particles and said support particles, an ionomer, and a mixture of water and alcohol.

10. The process for manufacturing an assembly as claimed in claim 9 , comprising: the spraying of the ink onto a polytetrafluoroethene support; the transfer by hot pressing onto said membrane capable of exchanging ions.

Assignees

• Commissariat Energie Atomique

Inventors

• Mayousse Eric
• Rozain Caroline

Classifications

• H01M4/9075

  Catalytic material supported on carriers, e.g. powder carriers (H01M4/8807, H01M4/881, H01M4/8814, H01M4/925 take precedence) · CPC title

• C25B13/08 Primary

  based on organic materials · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/0297

  Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other (H01M8/0271 takes precedence) · CPC title

• H01M4/881

  Electrolytic membranes · CPC title