Processes for removing nitriles from a feed to an oligomerization zone

Patent metadata

Field	Value
Publication number	US-10563137-B2
Application number	US-201815987865-A
Country	US
Kind code	B2
Filing date	May 23, 2018
Priority date	Dec 15, 2015
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

Processes for regenerating adsorbent in a nitrile removal zone. The regenerant comprises a stream of hot liquid that may comprise a portion of the oligomerized effluent or a portion of a hydrotreated effluent. A spent regenerant comprising the desorbed nitriles may be processed along with the oligomerized effluent with existing separation equipment.

First claim

What is claimed is:

1. A process for removing nitriles from an oligomerization zone feed stream with an adsorbent and for desorbing nitriles from the adsorbent, the process comprising:
adsorbing nitriles from the feed stream in a nitrile removal zone having at least two vessel, each vessel comprising an adsorbent configured to selectively adsorb nitriles from the feed stream and provide a cleaned feed stream with a reduced amount of nitriles compared to the feed stream;
oligomerizing the cleaned feed stream in the oligomerization zone in the presence of a catalyst to provide an oligomerized effluent;
separating the oligomerized effluent in a separation zone into a plurality of product streams having different hydrocarbon compositions, including a stream comprising C8 to C12 hydrocarbons; and,
desorbing the nitriles from the nitrile removal zone with a hot liquid regenerant stream comprising the stream comprising C8 to C12 hydrocarbons,
wherein nitriles are adsorbed from the feed stream in first vessel of the nitrile removal zone while nitriles are being desorbed with the hot liquid regenerant stream in the second vessel of the nitrile removal zone, and,
wherein the regenerate stream is hydrotreated before the desorbing the nitriles from the nitrile removal zone.

2. The process of claim 1 wherein the feed stream comprises C3 to C7 hydrocarbons.

3. The process of claim 1 wherein the plurality of product streams comprise a C4− stream, a diesel stream, and a gasoline stream.

4. The process of claim 3 wherein the separation zone includes at least two columns and wherein a first column from the at least two columns provides the C4− stream and wherein a second column from the at least two columns provides the diesel stream and the gasoline stream.

5. The process of claim 4 wherein the spent regenerate stream and the oligomerized effluent are combined before being passed into the first column.

6. The process of claim 4 wherein the second column further provides the regenerate stream.

7. The process of claim 6 wherein the regenerate stream is obtained from a sidecut stream from the second column.

8. The process of claim 1 further comprising:
separating the spent regenerate stream into a least one stream with nitriles.

9. The process of claim 8 wherein the spent regenerate stream is separated in the separation zone with the oligomerized effluent.

10. A process for removing nitriles from an oligomerization zone feed stream with an adsorbent and for desorbing nitriles from the adsorbent the process comprising:
passing the feed stream comprising hydrocarbons and nitriles to a nitrile removal zone comprising at least two vessels, each vessel having an adsorbent configured to selectively adsorb nitriles from the feed stream and provide a cleaned feed stream with a reduced amount of nitriles compared to the feed stream;
passing the cleaned feed stream to the oligomerization zone and oligomerizing the cleaned feed stream in the presence of a catalyst to provide an oligomerized effluent;
passing the oligomerized effluent to a separation zone being configured to provide a plurality of product streams having different hydrocarbon compositions, the product streams including at least one C4− stream and at least one C8 to C12 stream;
hydrotreating, in a hydrotreating zone, the C8 to C12 stream in the presence of a catalyst configured to selective remove heteroatoms and provide a hydrotreated effluent; and,
passing a hot liquid regenerate stream comprising a portion of the hydrotreated effluent to the nitrile removal zone to desorb the nitriles and provide a spent regenerate stream,
wherein nitriles are adsorbed from the feed stream in first vessel of the nitrile removal zone while nitriles are being desorbed with the hot liquid regenerant stream in the second vessel of the nitrile removal zone.

11. The process of claim 10 wherein the feed stream comprises a C3 to C7 hydrocarbon feed stream.

12. The process of claim 10 wherein the separation zone comprises at least two columns, wherein a first column provides the C4-stream, and wherein a second column provides the C8 to C12 stream.

13. The process of claim 10 further comprising:
passing the spent regenerate stream to the first column of the separation zone.

14. The process of claim 10 wherein the feed stream comprises a portion of an effluent from a catalytic cracking zone.

Assignees

• Uop Llc

Inventors

• Luebke Charles P
• Fei Zhihao

Classifications

• C07C7/12

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title

• B01D2259/40092

  using hot liquid · CPC title

• C07C7/13

  by molecular-sieve technique · CPC title

• B01D2257/40

  Nitrogen compounds · CPC title

• C10G2300/1088

  Olefins · CPC title