Method for producing conductive polymer-containing dispersion

Patent metadata

Field	Value
Publication number	US-10563071-B2
Application number	US-201414770196-A
Country	US
Kind code	B2
Filing date	Mar 11, 2014
Priority date	Mar 11, 2013
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

The present invention provides a method for producing a conductive polymer-containing dispersion, including: a polymerization step of polymerizing a monomer for obtaining a conjugated conductive polymer in a dispersion medium including the monomer and seed particles converted into a colloid protected by a polyanion.

First claim

The invention claimed is:

1. A method for producing a conductive polymer-containing dispersion, comprising:
preparing seed particles by polymerizing an ethylenically unsaturated monomer in a solution that comprises a polyanion so as to form a dispersion medium comprising the seed particles converted into a colloid protected by the polyanion;
adding a monomer to the dispersion medium; and
polymerizing the monomer in the dispersion medium to obtain a conjugated conductive polymer on the surface of the seed particles protected by the polyanion.

2. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the seed particles formed in the step of polymerizing the ethylenically unsaturated monomer comprise a polymer or a copolymer.

3. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein a particle diameter of d50 of the seed particles is 0.005 μm to 10 μm.

4. The method for producing a conductive polymer-containing dispersion according to claim 1 , comprising:
a second additive step, wherein additional seed particles converted into the colloid protected by the polyanion are added to the dispersion medium during the polymerization step.

5. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein a dispersion treatment is performed with respect to the generated conjugated conductive polymer during the polymerization step.

6. The method for producing a conductive polymer-containing dispersion according to claim 5 ,
wherein the dispersion treatment is performed by ultrasonic irradiation.

7. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the monomer for obtaining a conjugated conductive polymer is at least one selected from pyrrol which may have a substituent group, aniline which may have a substituent group, and thiophene which may have a substituent group.

8. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the monomer for obtaining a conjugated conductive polymer includes a compound denoted by Formula (I) described below,

wherein in Formula (I), R 1 and R 2 each independently represent a hydrogen atom, a hydroxyl group, an alkyl group having carbon atoms of 1 to 18 which may have a substituent group, an alkoxy group having carbon atoms of 1 to 18 which may have a substituent group, or an alkylthio group having carbon atoms of 1 to 18 which may have a substituent group, and alternatively represent an alicyclic ring having carbon atoms of 3 to 10 which may have a substituent group, an aromatic ring having carbon atoms of 6 to 10 which may have a substituent group, an oxygen atom-containing heterocyclic ring having carbon atoms of 2 to 10 which may have a substituent group, a sulfur atom-containing heterocyclic ring having carbon atoms of 2 to 10 which may have a substituent group, or a sulfur atom and oxygen atom-containing heterocyclic ring having carbon atoms of 2 to 10 which may have a substituent group in which R 1 and R 2 are bonded to each other in order to form a ring.

9. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the polyanion is a polymer having a group formed of a sulfonic acid or a salt thereof.

10. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein an anion group in the polyanion is 0.25 mol to 30 mol with respect to 1 mol of the monomer for obtaining a conjugated conductive polymer.

11. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the dispersion medium includes water, and
the polymerization is performed by using at least one oxidation agent selected from a peroxodisulfuric acid and a salt thereof.

12. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the polyanion is soluble in the dispersion medium and is able to coordinate on the seed particles in the dispersion medium.

13. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the amount of the ethylenically unsaturated monomer used with respect to 100 parts by mass of the amount of the polyanion used in the manufacturing of the seed particles converted into the colloid protected by the polyanion is 20 parts by mass to 90 parts by mass.

14. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the dispersion medium includes water or a mixed solvent of water and a water soluble solvent.

15. The method for producing a conductive polymer-containing dispersion according to claim 2 ,
wherein the ethylenically unsaturated monomer includes styrene.

16. The method for producing a conductive polymer-containing dispersion according to claim 9 ,
wherein the main chain of the polyanion is polyalkylene.

17. The method for producing a conductive polymer-containing dispersion according to claim 1 ,
wherein the polyanion is polystyrene sulfonic acid or salt thereof.

Assignees

• Showa Denko Kk

Inventors

• Tagawa Yasuyuki
• Murata Naoki
• Araki Motoaki
• Ohkubo Takashi

Classifications

• C08G2261/3223

  containing one or more sulfur atoms as the only heteroatom, e.g. thiophene · CPC title

• C08G75/06

  from cyclic thioethers · CPC title

• C08G61/126

  with a five-membered ring containing one sulfur atom in the ring · CPC title

• C08G2261/43

  Chemical oxidative coupling reactions, e.g. with FeCl3 · CPC title

• C09D5/24 Primary

  Electrically-conducting paints {(conductive materials H01B1/00)} · CPC title