Modified diene elastomer with reduced PDI and composition containing same

Patent metadata

Field	Value
Publication number	US-10562985-B2
Application number	US-201615740644-A
Country	US
Kind code	B2
Filing date	Jul 1, 2016
Priority date	Jul 2, 2015
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

A modified diene elastomer is provided. The elastomer comprises:
at least 70% by weight, with respect to the total weight of the modified diene elastomer, of a linear diene elastomer functionalized predominantly in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, the alkoxysilane group optionally bearing another functional group capable of interacting with a reinforcing filler, the alkoxysilane group bonded to the two branches of the diene elastomer via the silicon atom, the functionalized diene elastomer exhibiting a polydispersity index before fractionalization of less than or equal to 1.6; and more than 0 and up to 30% by weight, with respect to the total weight of the modified diene elastomer, of a star-branched diene elastomer exhibiting a polydispersity index before star-branching of less than or equal to 1.6, the Mooney viscosity of the modified diene elastomer varying from 30 to 80.

First claim

The invention claimed is:

1. A modified diene elastomer comprising:
a) at least 70% by weight, with respect to the total weight of the modified diene elastomer, of a linear diene elastomer functionalized predominantly in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, the alkoxysilane group optionally bearing another functional group capable of interacting with a reinforcing filler, the alkoxysilane group being bonded to the two branches of the diene elastomer via the silicon atom, the functionalized diene elastomer exhibiting a polydispersity index before functionalization of less than or equal to 1.6,
b) more than 0 and up to 30% by weight, with respect to the total weight of the modified diene elastomer, of a star-branched diene elastomer exhibiting a polydispersity index before star-branching of less than or equal to 1.6,
the Mooney viscosity of the modified diene elastomer varying from 30 to 80.

2. The modified diene elastomer according to claim 1 , wherein the other functional group capable of interacting with a reinforcing filler of the diene elastomer a) is a functional group chosen from primary, secondary or tertiary and cyclic or non-cyclic amines, isocyanates, imines, cyanos, thiols, carboxylates, epoxides and primary, secondary or tertiary phosphines.

3. The modified diene elastomer according to claim 1 , wherein the other functional group capable of interacting with a reinforcing filler of the diene elastomer a) is a tertiary amine functional group.

4. The modified diene elastomer according to claim 1 , wherein the functional group capable of interacting with a reinforcing filler of the diene elastomer a) and the silicon atom bonded to the elastomer are connected to one another via a spacer group defined as being a saturated or unsaturated, cyclic or non-cyclic, linear or branched, divalent C 1 -C 18 aliphatic hydrocarbon radical or a divalent C 6 -C 18 aromatic hydrocarbon radical, the spacer group optionally comprising one or more aromatic radicals and/or one or more heteroatoms.

5. The modified diene elastomer according to claim 4 , wherein the spacer group is a linear divalent C 1 -C 5 aliphatic hydrocarbon radical.

6. The modified diene elastomer according to claim 1 , wherein the alkoxysilane group is a methoxysilane or ethoxysilane group, optionally partially or completely hydrolysed to give silanol.

7. The modified diene elastomer according to claim 1 , wherein the modified diene elastomer comprises at least 80% by weight, with respect to the total weight of the modified diene elastomer, of the linear diene elastomer a) functionalized predominantly in the middle of the chain.

8. The modified diene elastomer according to claim 1 , wherein the modified diene elastomer comprises at most 20% by weight, with respect to the total weight of the modified diene elastomer, of the star-branched diene elastomer b).

9. The modified diene elastomer according to claim 1 , wherein the star-branched diene elastomer is a tin-based or silicon-based star-branched elastomer.

10. The modified diene elastomer according to claim 1 , wherein the star-branched diene elastomer b) is a star-branched diene elastomer comprising three or four branches.

11. The modified diene elastomer according to claim 1 , wherein the diene elastomer is a copolymer of butadiene and of a vinylaromatic monomer.

12. The modified diene elastomer according to claim 1 , wherein the diene elastomers a) and b) have, before functionalization and star-branching, the same microstructure and the same macrostructure.

13. A reinforced rubber composition based on at least one reinforcing filler and on an elastomer matrix comprising at least one modified diene elastomer as defined in claim 1 .

14. The reinforced rubber composition according to claim 13 , wherein the reinforcing filler(s) comprise(s) more than 50% by weight, with respect to the total weight of the reinforcing filler(s), of reinforcing inorganic filler.

15. The reinforced rubber composition according to claim 13 , wherein the reinforcing inorganic filler consists of silica.

16. A semi-finished article made of rubber for a tire, wherein the rubber comprises a crosslinkable or crosslinked rubber composition according to claim 13 .

17. The semi-finished article according to claim 16 , wherein the article is a tread.

18. A tire comprising a semi-finished article as defined in claim 17 .

Assignees

• Michelin & Cie

Inventors

• Dessendier Marie-Hélène
• Dire Charlotte
• Dorato Margarita
• Marechal Jean Marc
• Vaultier Florent

Classifications

• C08F36/02 Primary

  the radical having only two carbon-to-carbon double bonds · CPC title

• C08L9/06

  Copolymers with styrene · CPC title

• C08C19/25 Primary

  Incorporating silicon atoms into the molecule · CPC title

• C08L15/00

  Compositions of rubber derivatives (C08L11/00, C08L13/00 take precedence) · CPC title

• C08K3/36

  Silica · CPC title