Glass-ceramic, lithium ion conductor, battery, electronic device, and method for producing electrode

Patent metadata

Field	Value
Publication number	US-10559849-B2
Application number	US-201515514556-A
Country	US
Kind code	B2
Filing date	Nov 9, 2015
Priority date	Nov 10, 2014
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

A glass-ceramic includes an oxide containing lithium (Li), silicon (Si), and boron (B) and has an X-ray diffraction spectrum with two or more peaks appearing in the range 20°≤2θ≤25° and with two or more peaks appearing in the range 25°<2θ≤30°.

First claim

The invention claimed is:

1. A glass-ceramic comprising an oxide containing lithium (Li), silicon (Si), and boron (B),
the glass-ceramic having an X-ray diffraction spectrum with at least two peaks appearing in the range 20°≤2θ≤25° and with at least two peaks appearing in the range 25°<2θ≤30°; wherein
the oxide includes at least 69 mol % of an oxide of the lithium (Li),
the glass-ceramic having a Raman spectrum with a peak X appearing in the Ranan shift region of 920 cm-1 to 940 cm-1 and with a peak Y appearing in the Raman shift region of 820 cm-1 to 850 cm-1 and also having a ratio X/Y of an area intensity of the peak X to an area intensity of the peak Y of at least 2.0.

2. The glass-ceramic according to claim 1 , which has a 7Li nuclear spin-lattice relaxation time of at most 6 seconds as measured by a nuclear magnetic resonance method.

3. The glass-ceramic according claim 1 , wherein
the oxide comprises an oxide of the lithium (Li), an oxide of the silicon (Si), and an oxide of the boron (B),
the content of the oxide of the lithium (Li) is from 69 mol % to 73 mol % based on the total amount of the oxide of the lithium, the oxide of the silicon (Si), and the oxide of the boron (B),
the content of the oxide of the silicon (Si) is from 8 mol % to 40 mol % based on the total amount of the oxide of the lithium, the oxide of the silicon (Si), and the oxide of the boron (B), and
the content of the oxide of the boron (B) is from 10 mol % to 50 mol % based on the total amount of the oxide of the lithium, the oxide of the silicon (Si), and the oxide of the boron (B).

4. The glass-ceramic according to claim 1 , wherein
the oxide further contains at least one selected from the group consisting of sodium (Na), magnesium (Mg), aluminum (Al), phosphorus (P), potassium (K), calcium (Ca), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), gallium (Ga), germanium (Ge), selenium (Se), rubidium (Rb), sulfur (S), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), silver (Ag), indium (In), tin (Sn), antimony (Sb), cesium (Cs), barium (Ba), hafnium (Hf), tantalum (Ta), tungsten (W), lead (Pb), bismuth (Bi), gold (Au), lanthanum (La), neodymium (Nd), and europium (Eu).

5. A battery comprising a positive electrode, a negative electrode, and an electrolyte layer, wherein
at least one of the positive electrode, the negative electrode, and the electrolyte layer contains a glass-ceramic having an X-ray diffraction spectrum with at least two peaks appearing in the range 20°≤2θ≤25° and with at least two peaks appearing in the range 25°<2θ≤30°, wherein the glass-ceramic comprises an oxide containing lithium (Li), silicon (Si), and boron (B), and the oxide includes at least 69 mol % of an oxide of the lithium (Li),
the glass-ceramic having a Raman spectrum with a peak X appearing in the Raman shift region of 920 cm-1 and with a peak Y appearing in the Raman shift region of 820 cm-1 to 850 cm-1 and also having a ration X/Y of an area intensity of the peak X to an area intensity of the peak Y of at least 2.0.

6. An electronic device having a battery comprising a positive electrode, a negative electrode, and an electrolyte layer and being configured to receive power supply from the battery, wherein
at least one of the positive electrode, the negative electrode, and the electrolyte layer contains a glass-ceramic having an X-ray diffraction spectrum with at least two peaks appearing in the range 20°≤2θ≤25° and with at least two peaks appearing in the range 25°<2θ≤30°, wherein the glass-ceramic comprises an oxide containing lithium (Li), silicon (Si), and boron (B), and the oxide includes at least 69 mol % of and oxide of the lithium (Li),
the glass-ceramic having a Raman spectrum with a peak X appearing in the Raman shift region of 920 cm-1 to 940 cm-1 and with a peak Y appearing in the Raman shift region of 820 cm-1 to 850 cm-1 and also having a ratio X/Y of an area intensity of the peak X to an area intensity of the peak Y of at least 2.0.

7. A lithium ion conductor comprising an oxide containing lithium (Li), silicon (Si), and boron (B),
the lithium ion conductor having an X-ray diffraction spectrum with at least two peaks appearing in the range 20°≤2θ≤25° and with at least two peaks appearing in the range 25°<2θ≤30°, wherein the oxide includes at least 69 mol % of an oxide of the lithium (Li),
the lithium ion conductor having a Raman spectrum with a peak X appearing in the Raman shift region of 920 cm-1 to 940 cm-1 and with a peak Y appearing in the Raman shift region of 820 cm-1 to 850 cm-1 and also having a ratio X/Y of an area intensity of the peak X to an area intensity of the peak Y of at least 2.0.

8. A lithium ion conductor comprising an oxide containing lithium (Li), silicon (Si), and boron (B),
the lithium ion conductor having an X-ray diffraction spectrum with a peak A appearing in the range 25°≤2θ≤26° and with a peak B appearing in the range 41°≤2θ≤42°.

9. The lithium ion conductor according to claim 8 , which has a ratio of the intensity of the peak A to the intensity of the peak B of 0.5 to 2.

10. A battery comprising a positive electrode, a negative electrode, and an electrolyte layer, wherein
at least one of the positive electrode, the negative electrode, and the electrolyte layer contains a lithium ion conductor having an X-ray diffraction spectrum with a peak A appearing in the range 25°≤2θ≤26° and with a peak B appearing in the range 41°≤2θ≤42°.

11. An electronic device having a battery comprising a positive electrode, a negative electrode, and an electrolyte layer and being configured to receive power supply from the battery, wherein
at least one of the positive electrode, the negative electrode, and the electrolyte layer contains a lithium ion conductor having an X-ray diffraction spectrum with a peak A appearing in the range 25°≤2θ≤26° and with a peak B appearing in the range 41°≤2θ≤42°.

12. A method for producing an electrode, the method comprising firing an electrode comprising an active material and a lithium ion conductor while pressurizing the electrode, wherein
the lithium ion conductor comprises an oxide containing lithium (Li), silicon (Si), and boron (B), and the oxide includes at least 69 mol % of an oxide of the lithium (Li),
the lithium ion conductor having a Raman spectrum with a peak X appearing in the Raman shift region of 920 cm-1 to 940 cm-1 and with a peak Y appearing in the Raman shift region of 820 cm-1 to 850 cm-1 and also having a ratio X/Y of an area intensity of the peak X to an area intensity of the peak Y of at least 2.0.

13. A method for producing an electrode, the method comprising firing an electrode comprising an active material and a lithium ion conductor while pressurizing the electrode, wherein the lithium ion conductor comprising an oxide containing lithium (Li), silicon (Si), and boron (B), the lithium ion conductor having an X-ray diffraction spectrum with a peak A appearing in the range 25°≤2θ≤26° and with a peak B appearing in the range 41°≤2θ≤42°.

Assignees

• Murata Manufacturing Co

Inventors

• Furukawa Keiko
• Furuya Tatsuya
• Kumita Hideyuki
• Miyaji Sae
• Shibata Harumi
• Suzuki Masamitsu
• Sudo Go
• Shimizu Keisuke

Classifications

• C03C4/18

  for ion-sensitive glass · CPC title

• C03C10/0054

  containing PbO, SnO2, B2O3 · CPC title

• H01B1/08

  oxides · CPC title

• C03C3/064

  containing boron · CPC title

• H01M2300/0068

  inorganic · CPC title