Spinel-Type Lithium Titanium Oxide/Graphene Composite and Method of Preparing the Same
US-2015360197-A1 · Dec 17, 2015 · US
US10559819B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10559819-B2 |
| Application number | US-201815945971-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 5, 2018 |
| Priority date | Mar 29, 2013 |
| Publication date | Feb 11, 2020 |
| Grant date | Feb 11, 2020 |
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A titanium oxide compound according to the present invention comprises bronze-type titanium oxide or titanium oxide mainly composed of bronze-type titanium oxide, and contains calcium and/or silicon. The titanium oxide compound contains 0.005 to 2.5 mass % inclusive of calcium or 0.15 to 0.55 mass % inclusive of silicon, or contains 0.005 to 1.2 mass % inclusive of calcium and 0.15 to 0.2 mass % inclusive of silicon, or contains 0.005 to 0.1 mass % inclusive of calcium and 0.15 to 0.5 mass % inclusive of silicon.
Opening claim text (preview).
The invention claimed is: 1. A titanium oxide compound comprising bronze-type titanium oxide or titanium oxide mainly composed of bronze-type titanium oxide, wherein the titanium oxide contains 0.005 to 2.5 mass % inclusive of calcium, an average aspect ratio of primary particles of the titanium oxide compound is in a range from 3.28 to 5.74, and the titanium oxide is in a form of plate-shaped crystals. 2. The titanium oxide compound according to claim 1 , wherein at least a part of the calcium exists as a solid solution in titanium oxide crystals. 3. The titanium oxide compound according to claim 1 , wherein pore volume of the titanium oxide compound is 0.01 to 0.5 mL/g, and specific surface area thereof is 1.0 to 20 m 2 /g. 4. An electrode, wherein at least part of an electrode active material of the electrode is the titanium oxide compound according to claim 1 . 5. A lithium ion secondary battery using the electrode according to claim 4 as positive electrode or negative electrode.
Solid solutions · CPC title
Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title
Oxides; Hydroxides · CPC title
as mixtures · CPC title
by d-values or two theta-values, e.g. as X-ray diagram · CPC title
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