Organic semiconductor solution blends for switching ambipolar transport to N-type transport

Patent metadata

Field	Value
Publication number	US-10559754-B2
Application number	US-201715599816-A
Country	US
Kind code	B2
Filing date	May 19, 2017
Priority date	May 19, 2016
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

The present disclosure describes additives that attenuate a specific transport channel in ambipolar semiconductors to achieve unipolar characteristics. Carrier selective traps are included in the ambipolar semiconductors and are chosen on the basis of energetic preferences for holes or electrons and the relative positions of the molecular orbital energies of host polymer and the dopants. In one embodiment, a composition of matter useful as a current transport region in an organic semiconductor device comprises a semiconducting polymer; and means for accepting holes (e.g., a hole trapping compound) injected into the current transport region so as to impede conduction of the holes in the semiconducting polymer. This simple solution-processable method can improve the on and off current ratios (I ON /I OFF ) of OFETs by up to three orders of magnitude. Moreover, the treatment yields tailored blends that can be used to fabricate complementary inverters with excellent gain and low-power characteristics.

First claim

What is claimed is:

1. A composition of matter, comprising:
donor-acceptor copolymers each comprising a main chain section, the main chain section having a repeat unit that comprises a donor and an acceptor; and
hole trapping compounds combined with the donor-acceptor copolymers so as to switch ambipolar transport of the donor-acceptor copolymers to unipolar n-type transport.

2. The composition of matter of claim 1 , further comprising a solution comprising the hole trapping compounds and the donor-acceptor copolymers, wherein a total weight percentage (wt. %) of the hole trapping compounds in the solution is in a range of 0.005-50 wt. % based on a total weight of the solution.

3. The composition of matter of claim 2 , wherein the wt. % is in a range of 0.005-10 wt. %.

4. The composition of matter of claim 1 , further comprising a film cast from a solution, wherein:
a total weight (W CP ) of the donor-acceptor copolymers added in the solution and a total weight W HT of the hole trapping compounds added in the solution are such that [W CP /(W CP +W HT )]×100 is in a range of 5%-99%.

5. The composition of matter of claim 1 , wherein the hole trapping compounds each comprise at least one compound selected from Tetrathiafulvalene (TTF), a derivative of TTF, 1H-benzoimidazole (DMBI), a derivative of DMBI, Decamethylcobaltocene (DMC), a derivative of DMC, bicyclo[2,2,2]-octadiene-fused porphyrins, tetrabenzoporphyrin (BP or TBP), a derivative of BP, copper tetrabenzoporphyrin (CuBP), a derivative of CuBP, tetraethano-tetrabenzoporphyrin, a derivative of tetraethano-tetrabenzoporphyrin, copper tetraethano-tetrabenzoporphyrin, a derivative of copper tetraethano-tetrabenzoporphyrin, Spiro-MeOTAD, and a derivative of Spiro-MeOTAD.

6. The composition of matter of claim 5 , wherein:
the acceptor comprises a pyridine of the structure:

the donor comprises a dithiophene of the structure:

each R is independently hydrogen or a substituted or non-substituted alkyl, aryl, or alkoxy chain;
X is C, Si, Ge, N or P;
Ar is a substituted or non-substituted aromatic functional group or Ar is nothing and the valence of the pyridine ring is completed with hydrogen; and
the pyridine is regioregularly arranged along the conjugated main chain section.

7. The composition of claim 1 , wherein:
the acceptor comprises a fluorophenyl or fluorophenylene;
the donor comprises a dithiophene of the structure:

each R is independently hydrogen or a substituted or non-substituted alkyl, aryl, or alkoxy chain; and
X is C, Si, Ge, N or P.

8. The composition of matter of claim 1 , wherein each of the donor-acceptor copolymers are:
poly[4-(4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b′] dithiophen-2yl)-alt-[1,2,5] thiadiazolo[3,4-c]pyridine] (PCDTPT), or
5 poly[5-fluoro-[2,1,3]benzothiadiazole-4,7-diyl(4,4-dihexadecyl-4H-cyclopenta[2,1-b:3,4-Y] dithiophene-2,6-diyl)-5-fluoro-[2,1,3]benzothiadiazole-7,4-diyl(4,4-dihexadecyl-4Hcyclopenta[2,1-b:3,4-b′]dithiophene-2,6-diyl)] (PCDTFBT), or
a diketopyrrolopyrrole-thienothiophene copolymer DT-PDPP2T-TT.

9. A composition of matter, comprising:
a first region including:
donor-acceptor copolymers each comprising a main chain section, the main chain section having a repeat unit that comprises a donor and an acceptor; and
hole trapping compounds combined with the donor-acceptor copolymers so as to reduce hole current in the donor-acceptor copolymers; and

a second region, attached to the first region, including additional donor-acceptor copolymers combined with electron acceptor compounds, the electron acceptor compounds accepting electrons and reducing electron current in the additional donor-acceptor copolymers.

10. The composition of matter of claim 9 , wherein the donor-acceptor copolymers in the first region and the additional donor-acceptor copolymers in the second region both comprise a backbone including the repeat unit including the donor and the acceptor.

11. The composition of matter of claim 1 , wherein the donor-acceptor copolymers are regioregular.

12. A device comprising the composition of matter of claim 1 , comprising:
an Organic Field Effect Transistor (OFET) comprising:
a source contact to the donor-acceptor copolymers;
a drain contact to the donor-acceptor copolymers;
a gate contact; and
a dielectric between the donor-acceptor copolymers and the gate contact.

13. The OFET of claim 12 , wherein a hole current between the source and the drain contact is reduced by at least a factor of 100 with at most a factor of 10 reduction in electron current between the source and the drain contacts, as compared to the OFET comprising a film comprising the pristine donor-acceptor copolymers without the hole trapping compounds.

14. The device of claim 12 , further comprising:
a second OFET comprising additional donor-acceptor copolymers combined with electron acceptor compounds, the electron acceptor compounds accepting electrons and reducing electron current in the additional donor-acceptor copolymers.

15. The device of claim 14 , wherein:
a weight and composition of the hole trapping compounds,
a weight and composition of the donor-acceptor copolymers, and
a weight of and composition of the electron acceptor compounds,
are such that each of the OFETs have a mobility in a saturation regime of at least 1 cm 2 V −1 s −1 and an ON/OFF ratio of at least 1000.

16. A logic gate comprising the OFETs of claim 14 .

17. The logic gate of claim 16 , wherein the logic gate is an inverter.

18. The composition of matter of claim 1 , wherein the hole trapping compounds have a HOMO level that is higher in energy (closer to vacuum) than the HOMO level of the donor-acceptor semiconducting copolymers.

19. The composition of matter of claim 18 , wherein a first portion of the donor-acceptor semiconducting copolymers are p-type doped and a second portion of the donor-acceptor semiconducting copolymers are combined with electron acceptor compounds having a LUMO level lower than the LUMO level of the donor-acceptor semiconducting polymers.

20. The composition of matter of claim 1 , wherein the ambipolar transport is switched so that the donor-acceptor copolymers comprise n-type donor-acceptor copolymers.

21. The composition of matter of claim 1 , wherein the hole trapping compounds comprise isolating regions so that the hole trapping compound only accept holes and do not substantially transport the holes.

22. The OFET of claim 12 , wherein the hole current is at most 10 −8 amps.

23. A composition of matter, comprising:
a film including:
donor-acceptor copolymers each comprising a main chain section, the main chain section having a repeat unit that comprises a donor and an acceptor; and

hole trapping compounds combined with the donor-acceptor copolymers so as to reduce hole current in the donor-acceptor copolymers, wherein:
the donor-acceptor copolymers and the hole trapping compounds are phase separated, and
the main chain axes of a plurality of the donor-acceptor copolymers are interconnected.

Assignees

• Univ California

Inventors

• Ford Michael J
• Wang Hengbin
• Bazan Guillermo C

Classifications

• C07D521/00 Primary

  Heterocyclic compounds containing unspecified hetero rings · CPC title

• H01L51/0035 Primary

  Electricity · mapped topic

• H01L51/0077

  Electricity · mapped topic

• H01L51/0545

  Electricity · mapped topic

• H10K85/40

  Organosilicon compounds, e.g. TIPS pentacene · CPC title