Composition having oil film retention function, anticorrosive agent using same, and insulated terminated electric wire

Patent metadata

Field	Value
Publication number	US-10559403-B2
Application number	US-201414779201-A
Country	US
Kind code	B2
Filing date	Sep 26, 2014
Priority date	Oct 17, 2013
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

A composition having an oil film retention function which an oil film can be stably retained on surfaces of various metals, an anticorrosive agent using same, and insulated terminated electric wire. A composition having oil film retention function for being added to base oil to be applied onto a metal surface and retaining base oil on metal surface, and composition contains a component that is an adduct of an azole compound and acidic alkyl phosphate ester including one or more compounds represented by General Formulae (1) (Chemical Formula 1) P(═O)(—OR 1 )(—OH) 2 . . . (1) or General Formula (2) (Chemical Formula 2) P(═O)(—OR 1 ) 2 (—OH) . . . (2) where R 1 represents an organic group having four or more carbon atoms, and component that is an adduct of a metal and/or organic amine compound and acidic alkyl phosphate ester including one or more compounds represented by General Formulae (1) or (2).

First claim

The invention claimed is:

1. An anticorrosive agent containing a base oil and a composition having an oil film retention function, wherein an amount of the composition having an oil film retention function in the anticorrosive agent is 10 mass % or more;
the composition having an oil film retention function consists of a component (a) and a component (b); wherein
the component (a) is an adduct of an azole compound and an acidic alkyl phosphate ester, where the acidic alkyl phosphate ester includes one or more compounds represented by
General Formula (1):(Chemical Formula 1)
P(═O)(—OR 1 )(—OH) 2   (1)

or General Formula (2):(Chemical Formula 2)
P(═O)(—OR 1 ) 2 (—OH)  (2)

where R 1 represents an organic group having four or more carbon atoms;
the component (b) is an adduct of a metal and an acidic alkyl phosphate ester having a common structure to that of the acidic alkyl phosphate ester used to form the adduct of component (a).

2. The anticorrosive agent according to claim 1 ,
wherein a content ratio of the component (a) to the component (b) in molar ratio is 1:9 to 9:1.

3. The anticorrosive agent according to claim 1 , wherein a pH of the composition having an oil film retention is 4 or more.

4. The anticorrosive agent according to claim 1 ,
wherein the azole compound is at least one selected from 1-[N,N-bis(2-ethylhexyl)aminomethyl]methylbenzotriazole, pyrrole, imidazole, pyrazole, 1,2,3-triazole, 1,2,4-triazole, tetrazole, isoindole, benzimidazole, indazole, 1H-benzotriazole, 2H-benzotriazole, imidazo[4,5-b]pyridine, indole, purine, pyrazolo[3,4-d]pyrimidine, triazolo[4,5-d]pyrimidine, and benzothiazole, or a derivative thereof.

5. The anticorrosive agent according to claim 1 ,
wherein the metal is at least one selected from alkali metals, alkaline earth metals, aluminum, titanium, and zinc.

6. An insulated terminated electric wire in which an electrical connection portion between a terminal fitting and an electric wire conductor is covered with the anticorrosive agent according to claim 1 .

Assignees

• Autonetworks Technologies Ltd
• Sumitomo Wiring Systems
• Sumitomo Electric Industries
• Univ Kyushu

Inventors

• Hase Tatsuya
• Hosokawa Takehiro
• Nakashima Kazuo
• Goto Kazuhiro
• Hirai Hiroki
• Ono Junichi
• Otsuka Takuji
• Nomura Hideki
• Mizoguchi Makoto

Classifications

• C10M2223/023

  used as base material · CPC title

• H01B3/20

  liquids, e.g. oils (silicone oils H01B3/46) · CPC title

• C10N2040/16

  Dielectric; Insulating oil {or insulators} · CPC title

• C10N2040/14

  Electric or magnetic purposes · CPC title

• C10N2010/08

  Groups 4 or 14 · CPC title