Laser-based ir spectroscopy for measuring sulfur trioxide in the exhaust gas of gas power plants
US-2018059013-A1 · Mar 1, 2018 · US
US10557378B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10557378-B2 |
| Application number | US-201615062806-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 7, 2016 |
| Priority date | Mar 7, 2016 |
| Publication date | Feb 11, 2020 |
| Grant date | Feb 11, 2020 |
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A system for regulating condensation of a flue gas in a steam generator is provided. The system includes a temperature controller and a flue gas analyzer. The temperature controller is configured to control a temperature of a component of the steam generator, the component being in heating-contact with the flue gas. The flue gas analyzer is configured to communicate with the temperature controller and to obtain a measurement of an amount of an acid-forming compound in the flue gas. The temperature controller adjusts the temperature of the component based at least in part on the measurement such that the temperature of the component is above an acid dew point of the flue gas when the component is in heating-contact with the flue gas.
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What is claimed is: 1. A system for regulating condensation of a flue gas in a steam generator, the system comprising: a temperature controller configured to control a temperature of a component of the steam generator, the temperature controller comprising a heater in heating contact with a working medium of the steam generator, the component being in heating-contact with the flue gas; a flue gas analyzer configured to communicate with the temperature controller and to obtain a measurement of an amount of an acid-forming compound in the flue gas, wherein the flue gas analyzer is further configured to obtain the measurement of the amount of the acid-forming compound at a predetermined location where the flue gas has a temperature between 400° C. and 800° C.; and wherein the temperature controller adjusts the temperature of the component based at least in part on the measurement such that the temperature of the component is above an acid dew point of the flue gas when the component is in heating-contact with the flue gas. 2. The system of claim 1 , wherein the temperature controller is further configured to keep the temperature of the component at or near a set temperature that is based at least in part on a desired margin of safety and the acid dew point. 3. The system of claim 1 , wherein the acid-forming compound is sulfur-trioxide. 4. The system of claim 1 , wherein the flue gas analyzer is further configured to obtain the measurement of the amount of the acid-forming compound when the flue gas has a temperature of 500° C. 5. The system of claim 1 , wherein the flue gas analyzer obtains the measurement of the acid-forming compound via a Raman process. 6. The system of claim 5 , wherein the Raman process is a stimulated Raman process and the flue gas analyzer comprises two or more laser diodes. 7. The system of claim 1 , wherein the flue gas analyzer obtains the measurement of the acid-forming compound via IR absorption. 8. The system of claim 1 , wherein the component forms a conduit that contains a working-medium, and the temperature controller controls the temperature of the component via controlling a temperature of the working-medium. 9. A method for regulating condensation of a flue gas in a steam generator, the method comprising: obtaining a measurement of an amount of an acid-forming compound in the flue gas at a predetermined location via a flue gas analyzer, the flue gas being in heating-contact with one or more components of the steam generator, wherein the measurement of the amount of the acid-forming compound is obtained by the flue gas analyzer at the predetermined location where the flue gas has a temperature between 400° C. and 800° C.; and controlling a temperature of the one or more components via a temperature controller in communication with the flue gas analyzer, the temperature controller comprising a heater in heating contact with a working medium of the steam generator; wherein, at least in part based on the measurement of the amount of the acid-forming compound in the flue gas, the temperature of the one or more components is maintained above an acid dew point of the flue gas. 10. The method of claim 9 , wherein controlling a temperature of the one or more components via a temperature controller in communication with the flue gas analyzer and based at least in part on the measurement such that the temperature of the one or more components is above an acid dew point of the flue gas comprises: controlling the temperature of the one or more components via the temperature controller to stay at or near a set-temperature that is based at least in part on a desired margin of safety and the acid dew point. 11. The method of claim 9 , wherein the acid-forming compound is sulfur-trioxide. 12. The method of claim 9 , wherein the flue gas analyzer obtains the measurement of the amount of the acid-forming compound when the flue gas has a temperature of 500° C. 13. The method of claim 9 , wherein the flue gas analyzer obtains the measurement of the acid-forming compound via a Raman process. 14. The method of claim 13 , wherein the Raman process is a stimulated Raman process and the flue gas analyzer comprises two or more laser diodes. 15. The method of claim 9 , wherein the flue gas analyzer obtains the measurement of the acid-forming compound via IR absorption. 16. The method of claim 9 , wherein the steam generator is at least one of a heat recovery steam generator, a gas-fired boiler, an oil-fired boiler, and a coal-fired boiler. 17. The method of claim 9 , wherein controlling a temperature of the one or more components via a temperature controller in communication with the flue gas analyzer and based at least in part on the measurement such that the temperature of the one or more components is above an acid dew point of the flue gas comprises: controlling a temperature of a working-medium contained within a conduit formed by the one or more components via the temperature controller. 18. A combined cycle power generation plant that regulates condensation of a flue gas, the combined cycle power generation plant comprising: a primary generator that generates the flue gas by combusting a fuel; a heat recovery steam generator fluidly connected to the primary generator such that the flue gas flows from the primary generator to the heat recovery steam generator; one or more components disposed in at least one of the primary generator and the heat recovery steam generator, the one or more components configured to be in heating-contact with the flue gas; a temperature controller configured to control a temperature of the one or more components, the temperature controller comprising a heater in heating contact with a working medium of the heat recovery steam generator; a flue gas analyzer in communication with the temperature controller and configured to obtain a measurement of an acid-forming compound in the flue gas at a predetermined location where the temperature of the flue gas is between 400° C. and 800° C.; and wherein the temperature controller adjusts the temperature of the one or more components based at least in part on the measurement such that the temperature of the one or more components is above an acid dew point of the flue gas when the one or more components are in heating-contact with the flue gas. 19. The combined cycle power generation plant of claim 18 , wherein the flue gas analyzer is further configured to obtain, via a stimulated Raman process, the measurement of the amount of the acid-forming compound at the predetermined location, and the acid-forming compound is sulfur-trioxide. 20. The combined cycle power generation plant of claim 18 , wherein the flue gas analyzer is further configured to obtain, via IR absorption, the measurement of the amount of the acid-forming compound at the predetermined location.
Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT] · CPC title
Arrangements of devices for treating smoke or fumes · CPC title
Raman scattering · CPC title
for analysing gases, e.g. multi-gas analysis · CPC title
Devices and methods for diminishing corrosion, e.g. by preventing cooling beneath the dew point · CPC title
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