Metallic image forming method

Patent metadata

Field	Value
Publication number	US-10557050-B2
Application number	US-201515310669-A
Country	US
Kind code	B2
Filing date	Apr 28, 2015
Priority date	May 14, 2014
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

A metallic image forming method is a method for forming a metallic image with a metallic ink containing an organic coloring agent capable of exhibiting a metallic color on a recording medium provided with an undercoat layer thereon having a black color or an opposite color to the color of diffused light from the metallic ink. The method includes applying the metallic ink onto the recording medium so as to cover at least part of the undercoat layer.

First claim

The invention claimed is:

1. A metallic image forming method for forming an image having a metallic hue derived from an organic coloring agent, the method comprising:
preparing a metallic ink containing the organic coloring agent,
preparing a recording medium provided with an undercoat layer thereon having (i) a black color for absorbing diffusion light of the metal particles or (ii) an opposite color to the color of diffused light from the organic coloring agent for cancelling the diffusion light of the organic coloring agent, and
printing with the metallic ink onto the recording medium so as to cover at least part of the undercoat layer,
wherein the undercoat layer has the opposite color to the color of diffused light from the organic coloring agent, and
wherein the ink having the opposite color to the color of the diffusion light from the organic coloring agent contains a coloring material capable of exhibiting the opposite color to the color of diffused light from the organic coloring agent.

2. The metallic image forming method according to claim 1 , wherein the undercoat layer having the opposite color is formed by applying an undercoat ink onto the recording medium, the undercoat ink having an opposite color to the color of diffused light from the organic coloring agent.

3. The metallic image forming method according to claim 1 , wherein the black color absorbs light having wavelengths over the entire range of 380 nm to 780 nm and has a lightness L* of 35 or less in the CIE L*a*b* color system.

4. The metallic image forming method according to claim 1 , wherein the opposite color satisfies the following relationship:
hue angle of diffused light from an image formed with the metallic ink+162°≤hue angle of diffused light from an image formed with the opposite color≤hue angle of diffused light from the image formed with the metallic ink+198°.

5. The metallic image forming method according to claim 1 , wherein the metallic image has an uneven profile having an waviness including recesses and projections, and the waviness has an average pitch in the range of 1 μm to 10000 μm, a difference in height between the bottom of the recesses and the top of the projections in the range of 0.10 μm to 1000 μm, and an arithmetic average surface roughness Ra in the range of 0.20 μm to 25.0 μm, the average pitch, the difference in height, and the arithmetic average surface roughness each being specified in JIS B0601:2001.

6. The metallic image forming method according to claim 1 , wherein the metallic ink is printed onto the recording medium using an ink jet recording head.

7. The metallic image forming method according to claim 2 , wherein the ink having an opposite color to the color of diffused light from the organic coloring agent is applied onto the recording medium using an ink jet recording head.

8. The metallic image forming method according to claim 1 , wherein the recording medium is opaque, and the printing with the metallic ink is performed in such a manner that the metallic ink is printed to the side of the recording medium on which the undercoat layer has been formed.

9. The metallic image forming method according to claim 1 , wherein the recording medium is transparent, and the printing with the metallic ink is performed in such a manner that the metallic ink is printed to the side of the recording medium opposite the undercoat layer.

10. The metallic image forming method according to claim 1 , wherein the undercoat layer has the black color.

11. The metallic image forming method according to claim 10 , wherein the undercoat layer having the black color is formed by applying a black ink onto the recording medium or mixing a yellow ink, a magenta ink, and a cyan ink onto the recording medium.

12. The metallic image forming method according to claim 11 , wherein the black ink is applied onto the recording medium using an ink jet recording head.

13. The metallic image forming method according to claim 11 , wherein the thickness of a layer derived from the ink forming the undercoat layer is 0.05 μm or more to 1 μm or less.

14. The metallic image forming method according to claim 1 , wherein the thickness of a layer derived from the metallic ink formed on the recording medium is 0.05 μm or more to 1 μm or less.

15. The metallic image forming method according to claim 1 , wherein the recording medium is a surface-treated permeable medium.

16. The metallic image forming method according to claim 15 , wherein the permeable medium is selected from the group consisting of plain paper, coat paper, art paper, and cast-coated paper.

17. The metallic image forming method according to claim 1 , wherein the printing with the ink is performed by a printing method selected from the group consisting of gravure printing, flexography, offset printing, screen printing, relief printing, and on-demand small size printing.

18. The metallic image forming method according to claim 1 , wherein the organic coloring agent is selected from the group consisting of an aniline-based coloring agent, a pyrrole-based coloring agent, a phthalocyanine-based coloring agent, a xanthene-based coloring agent, and an azamethine-based coloring agent.

19. The metallic image forming method according to claim 18 , wherein the organic coloring agent is the aniline-based coloring agent, and the undercoat layer is formed by applying the cyan ink and the magenta ink onto the recording medium.

20. The metallic image forming method according to claim 18 , wherein the organic coloring agent is the azamethine-based coloring agent, and the undercoat layer is formed by applying a gray ink onto the recording medium.

Assignees

• Canon Kk

Inventors

• Iida Kenichi
• Okubo Taketoshi

Classifications

• B41M1/34

  on glass or ceramic surfaces {(ink-jet printing on glass or ceramic surfaces B41M5/00)} · CPC title

• B41M5/0047

  by ink-jet printing · CPC title

• B41M5/0064

  on plastics, horn, rubber, or other organic polymers · CPC title

• C09D11/107

  from unsaturated acids or derivatives thereof · CPC title

• B41J2/01

  Ink jet · CPC title