Carbon fiber-reinforced polymer composite and method of preparing the same

Patent metadata

Field	Value
Publication number	US-10557019-B2
Application number	US-201715830635-A
Country	US
Kind code	B2
Filing date	Dec 4, 2017
Priority date	Sep 1, 2017
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

Provided herein, inter alia, are a carbon fiber-reinforced polymer composite and a method for manufacturing the same. The carbon fiber-reinforced polymer composite may improve interfacial bonding force by modifying the surface of carbon fibers with an amphiphilic block copolymer and then forming a composite of the surface-modified carbon fibers with a polymer.

First claim

What is claimed is:

1. A carbon fiber-reinforced polymer composite comprising:
a polymer; and
carbon fibers that are modified with a block copolymer represented by Formula 1 or Formula 2:

wherein, in Formula 1, a is an integer of 10 to 50 and b is an integer satisfying a≤b≤50 and R 1 is methyl or ethyl and n is an integer of 1 to 10,

wherein, in Formula 2, x is an integer of 50 to 90 and y is an integer satisfying 10≤y≤x≤90 and n is an integer of 1 to 10,
wherein the carbon fibers are dispersed in the polymer.

2. The polymer composite material of claim 1 , wherein the polymer is a thermoplastic or thermosetting polymer.

3. The polymer composite material of claim 1 , wherein the block copolymer has a weight average molecular weight of about 10,000 to 50,000 g/mol.

4. The polymer composite material of claim 1 , comprising:
an amount of about 45% by weight to 95% by weight of the polymer; and
an amount of about 5% by weight to 55% by weight of the surface-modified carbon fibers,
all the % by weights based on the total weight of the polymer composite material.

5. The polymer composite material of claim 1 , further comprising an additive which is dispersed in the polymer and is selected from the group consisting of maleic anhydride-grafted polypropylene, a glass fiber, an antioxidant and a combination thereof.

6. A component for a vehicle comprising the carbon fiber-reinforced polymer composite of claim 1 .

7. The component of claim 6 , wherein the component is selected from the group consisting of a seat frame, a roof frame, a cross beam and a combination thereof.

8. A method of manufacturing a carbon fiber-reinforced polymer composite comprising:
modifying carbon fibers with a block copolymer represented by the following Formula 1 or 2; and
mixing the modified carbon fibers with a polymer,

wherein in Formula 1, a is an integer of 10 to 50 and b is an integer satisfying a≤b≤50; and R 1 is C 1 -C 20 alkyl and n is an integer of 1 to 10,

wherein Formula 2, x is an integer of 50 to 90 and y is an integer satisfying 10≤y≤x≤90; and n is an integer of 1 to 10.

9. The method of claim 8 , wherein R 1 is methyl or ethyl.

10. The method of claim 8 , wherein the carbon fibers include at least one epoxy group on surfaces thereof or include no epoxy group on the surfaces thereof.

11. The method of claim 10 , wherein, when the carbon fibers have at least one epoxy group, the carbon fibers are modified with about 100 parts by weight to 500 parts by weight of the block copolymer, based on 100 parts by weight of the epoxy group.

12. The method of claim 8 , wherein the block copolymer has a weight average molecular weight of about 10,000 to 50,000 g/mol.

13. The method of claim 8 , wherein the carbon fibers are modified by steps comprising:
dispersing the carbon fibers in a first solvent to form a dispersion;
dissolving the block copolymer in a second solvent to form a polymer solution;
mixing the dispersion with the polymer solution to form a mixture; and
stirring the mixture at a temperature of about 70° C. to 90° C. for about 2 to 4 hours.

14. The method of claim 8 , wherein the carbon fibers are modified by steps comprising:
dissolving the block copolymer in a second solvent having a polarity of about 2.4 to 9.0 to form a polymer solution;
spraying the polymer solution on surfaces of the carbon fibers; and
mixing the carbon fibers with the solution at a temperature of about 70° C. to 90° C. for about 2 to 4 hours.

15. The method of claim 8 , wherein the polymer is a thermoplastic or thermosetting polymer.

16. The method of claim 8 , wherein an amount of about 5% by weight to 55% by weight of the modified carbon fibers are mixed with an amount of about 45% by weight to 95% by weight of the polymer, all the % by weight based on the total weight of the carbon fiber-reinforced polymer composite.

17. The method of claim 8 , wherein the fibers are modified at a temperature of about 150° C. to 300° C. for about 30 minutes to 2 hours.

18. The method according to claim 8 , further comprising:
mixing the modified carbon fibers and the polymer with an additive selected from the group consisting of maleic anhydride-grafted polypropylene, a glass fiber, an antioxidant and a combination thereof.

19. A carbon fiber-reinforced polymer composite obtained by a method of claim 8 .

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Univ Korea Res & Bus Found

Inventors

• Lee Sung Hyun
• Jung Soon Joon
• Seo Won Jin
• Lee Dong Uk
• Yoon Ho Gyu
• Seo Heun Young
• Yeom Yong Sik
• Lee Jae Young

Classifications

• C08J5/06 Primary

  using pretreated fibrous materials · CPC title

• C08K9/08 Primary

  Ingredients agglomerated by treatment with a binding agent · CPC title

• C08K3/04

  Carbon · CPC title

• C08J2451/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• D06M15/267

  of unsaturated carboxylic esters having amino or quaternary ammonium groups · CPC title