Flame retardant resin composition and method for producing the same

Patent metadata

Field	Value
Publication number	US-10557016-B2
Application number	US-201715716083-A
Country	US
Kind code	B2
Filing date	Sep 26, 2017
Priority date	Sep 30, 2016
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

A flame retardant resin composition includes a thermoplastic resin, flame retardant reinforced fibers, and a flame retardant. The flame retardant reinforced fibers include cellulosic fibers, a phosphorus compound that is grafted to the surface of the cellulosic fibers, and a polyamine compound that is bound to the phosphorus compound. The flame retardant is a phosphorus-based flame retardant. A method for producing the flame retardant resin composition includes the following: grafting a vinyl phosphate compound to cellulosic fibers by bringing the vinyl phosphate compound into contact with the cellulosic fibers after the cellulosic fibers have been irradiated with an electron beam, optionally followed by electron beam irradiation; binding a polyamine compound to the vinyl phosphate compound, which is grafted to the cellulosic fibers, to form flame retardant reinforced fibers; grinding the flame retardant reinforced fibers; and melt-kneading and pelletizing a thermoplastic resin, the flame retardant reinforced fibers, and a component containing a phosphorus-based flame retardant. This can provide a non-halogen flame retardant resin composition with sufficient flame resistance.

First claim

What is claimed is:

1. A flame retardant resin composition comprising:
a thermoplastic resin;
flame retardant reinforced fibers dispersed in the thermoplastic resin; and
a flame retardant,
wherein the flame retardant reinforced fibers include cellulosic fibers, a phosphorus compound that is grafted to a surface of the cellulosic fibers, and a polyamine compound that is bound to the phosphorous compound,
the flame retardant reinforced fibers have an average fiber length of 1 to 25 mm, and
the flame retardant is a phosphorus-based flame retardant, and
the flame retardant resin composition has flame resistance of V-0 or higher in accordance with the UL-94 standard without the presence of a drip inhibitor.

2. The flame retardant resin composition according to claim 1 , wherein the flame retardant resin composition does not contain a halogen-based flame retardant.

3. The flame retardant resin composition according to claim 1 , wherein a phosphorous content in the flame retardant resin composition is 1.0 to 5.0% by mass with respect to 100% by mass of the flame retardant resin composition.

4. The flame retardant resin composition according to claim 1 , wherein an ionic bond is formed between the polyamine compound and the phosphorus compound that is grafted to the surface of the cellulosic fibers in the flame retardant reinforced fibers.

5. The flame retardant resin composition according to claim 1 , wherein a content of the phosphorus-based flame retardant is 1 to 20% by mass with respect to 100% by mass of the flame retardant resin composition.

6. A method for producing a flame retardant resin composition comprising a thermoplastic resin, flame retardant reinforced fibers dispersed in the thermoplastic resin, and a flame retardant,
the method comprising:
grafting a vinyl phosphate compound to cellulosic fibers by bringing the vinyl phosphate compound into contact with the cellulosic fibers after the cellulosic fibers have been irradiated with an electron beam, and/or irradiating the cellulosic fibers that have been in contact with the vinyl phosphate compound with an electron beam;
binding a polyamine compound to the vinyl phosphate compound, grafted to the cellulosic fibers, to form flame retardant reinforced fibers;
grinding the flame retardant reinforced fibers so that the flame retardant reinforced fibers have an average fiber length of 1 to 25 mm; and
melt-kneading and pelletizing the thermoplastic resin, the flame retardant reinforced fibers, and a component containing a phosphorus-based flame retardant,
wherein the flame retardant resin composition has flame resistance of V-0 or higher in accordance with the UL-94 standard without the presence of a drip inhibitor.

7. The method according to claim 6 , wherein the vinyl phosphate compound is mono(2-acryloyloxyethyl) phosphate.

8. The method according to claim 6 , wherein the polyamine compound is polyallylamine.

9. The method according to claim 6 , wherein the flame retardant resin composition does not contain a halogen-based flame retardant.

10. The method according to claim 6 , wherein a phosphorous content in the flame retardant resin composition is 1.0 to 5.0% by mass with respect to 100% by mass of the flame retardant resin composition.

11. The method according to claim 6 , wherein an ionic bond is formed between the polyamine compound and the phosphorus compound that is grafted to the cellulosic fibers in the flame retardant reinforced fibers.

12. The method according to claim 6 , wherein a content of the phosphorus-based flame retardant is 1 to 20% by mass with respect to 100% by mass of the flame retardant resin composition.

Assignees

• Toyota Auto Body Co Ltd
• Kurashiki Boseki Kk

Inventors

• Akihama Asuka
• Sugiyama Minoru

Classifications

• C08K5/0066 Primary

  Flame-proofing or flame-retarding additives · CPC title

• C08K7/02

  Fibres or whiskers · CPC title

• D06M15/3564

  containing phosphorus · CPC title

• D06M14/22

  of vegetal origin, e.g. cellulose or derivatives thereof · CPC title

• C08L2201/02

  Flame or fire retardant/resistant · CPC title