Epoxy resin-epoxy curing systems with a latent thickening tendency

Patent metadata

Field	Value
Publication number	US-10557015-B2
Application number	US-201515320517-A
Country	US
Kind code	B2
Filing date	Jun 23, 2015
Priority date	Jun 24, 2014
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

The invention relates to a two-component or multi-component system having at least one epoxy resin component (1) that comprises i. at least one epoxy resin, ii. at least one inorganic thickener (a1) and iii. at least one wetting and dispersing agent (a2) that inhibits the thickening effect of said inorganic thickener (a1); as well as a curing component (2) which comprises i.) at least one component (b1) that at least partially cancels the inhibition of the thickening effect of the inorganic thickener (a1); said wetting and dispersing agent (a2) being non-reactive to the at least one epoxy resin, and the curing component (2) being reactive to said epoxy resin component (1). The invention also relates to substrates coated with a two-component or multi-component system according to the invention. The invention also relates to the use of a combination of (a1) and (a2) in epoxy resin compositions, in order to give the formulation a latent thickening effect.

First claim

The invention claimed is:

1. An adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system comprising
at least one epoxy resin component 1 which comprises
i. at least one epoxy resin,
ii. at least one inorganic thickener (a1), and
iii. at least one wetting and dispersing agent (a2) which inhibits the thickening effect of the inorganic thickener (a1);

with
a curing agent component 2 which comprises
i.) at least one component (b1) which at least partly eliminates the inhibition of the thickening effect of the inorganic thickener (a1);
the wetting and dispersing agent (a2) being nonreactive toward the at least one epoxy resin and the curing agent component 2 being reactive toward the epoxy resin component 1;
wherein the at least one component (b1) is a polymer;
wherein in the resulting mixture of the epoxy resin component 1 and the curing agent component 2 the weight ratio of wetting and dispersing agent (a2) to component (b1) is 15:1 to 1:5;
wherein the curing agent component 2 comprises a curing agent different from and in addition to the at least one component (b1), said curing agent employed substantially stoichiometrically relative to the at least one epoxy resin; and
wherein the at least one epoxy resin component 1 and the curing agent component 2 of the two-component or multicomponent system represent two spatially separate individual components stored separately before mixing.

2. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , the inorganic thickener (a1) being selected from the group consisting of phyllosilicates, precipitated silicas, and fumed silicas.

3. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , the inorganic thickener (a1) being non-organically modified fumed silica or hydrophobically modified fumed silica.

4. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , the inorganic thickener (a1) being a phyllosilicate mixture which has been surface-treated with quaternary alkylammonium salts and which comprises 50 to 95 wt %, based on the phyllosilicate mixture, of a clay mineral selected from the group consisting of sepiolite and palygorskite or mixtures thereof and less than 50 wt %, based on the phyllosilicate mixture, of at least one smectite.

5. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , the epoxy resin of the epoxy resin component 1 being selected from the group of glycidyl ethers, glycidyl esters, glycidyl amines, cycloaliphatic epoxides, and glycidyl isocyanurates.

6. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , the curing agent component 2 comprising a curing agent which is selected from the group consisting of diamines, polyamines, polyamides, and cyclic carboxylic anhydrides.

7. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , the wetting and dispersing agent (a2) and the component (b1) being selected such that they comprise one or more of the following functional groups selected from
group 1: consisting of
imidazolyl groups, with the structural element N—C═N,
amino groups with the structural elements N for tertiary amines, NH for secondary amines, and NH 2 for primary amines, and
ammonium groups with the structural element NH + X − for ammonium salts of tertiary amines, with the structural element NH 2 + X − for ammonium salts of secondary amines, and NH 3 + X − for ammonium salts of primary amines, X − in each case being the anion of an acid;

and/or
group 2: consisting of
hydroxyl groups with the structural element OH,
urea groups with the structural element HNC(O)CNH for ureas of primary amines and NC(O)CN for ureas of secondary amines,
amide groups, with the structural element C(O)N for amides of secondary amines, C(O)NH for amides of primary amines, and C(O)NH 2 for amides of ammonia,
carboxylic acid groups with the structural element COOH, and
organic phosphoric ester groups with the structural element OP(O)(OH) 2 ,

and
(A) the weight percentage fraction of structural elements in the wetting and dispersing agent (a2), selected from the functional groups of groups 1 and 2, based on the weight of the wetting and dispersing agent (a2), being lower than the weight percentage fraction of structural elements in component (b1), selected from the functional groups of groups 1 and 2, based on the weight of the component (b1);
and/or
(B) component (b1) comprising a higher weight percentage fraction of structural elements from the functional groups selected from group 1, based on the weight of component (b1), than that of the structural elements from the functional groups selected from group 1 in the wetting and dispersing agent (a2), based on the weight of the wetting and dispersing agent (a2).

8. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 7 ,
(A) the weight percentage fraction of structural elements selected from the functional groups of groups 1 and 2, based on the weight of the wetting and dispersing agent (a2), being less than 11 wt %, and
the weight percentage fraction of structural elements selected from the functional groups of groups 1 and 2, based on the weight of component (b1), being greater than or equal to 11 wt %.

9. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 7 , the difference in the weight percentage fractions of the structural elements between the wetting and dispersing agent (a2) and component (b1), in case (A) and/or in case (B), being at least 2 wt %.

10. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , the wetting and dispersing agent (a2) binding reversibly to the surface of the inorganic thickener (a1).

11. The adhesive, sealant, a coating material or a molding compound obtained from a two-component or multicomponent system as claimed in claim 1 , wherein the component (b1) is a polymer and is able to bind to the surface of the inorganic thickener (a1) with at least partial displacement of (a2).

12. A substrate coated with the adhesive, sealant, or coating material obtained from a two-component or multicomponent system of claim 1 .

Assignees

• Byk Chemie Gmbh

Inventors

• Piestert Frederik
• Pritschins Wolfgang
• Kockoth Sascha
• Omeis Jürgen

Classifications

• C08K3/34 Primary

  Silicon-containing compounds · CPC title

• C09J11/04

  inorganic · CPC title

• C09D7/43

  Thickening agents · CPC title

• C08G59/40 Primary

  characterised by the curing agents used · CPC title

• C09D163/00

  Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title