Process for drying polymers

Patent metadata

Field	Value
Publication number	US-10556971-B2
Application number	US-201715727925-A
Country	US
Kind code	B2
Filing date	Oct 9, 2017
Priority date	Nov 9, 2016
Publication date	Feb 11, 2020
Grant date	Feb 11, 2020

Abstract

A method for controlling the temperature of the inner surface of a transfer line dryer, and thus controlling the temperature of a polymer product flowing through the transfer line dryer, is explained. Also provided is a transfer line dryer apparatus that is useful for implementing the disclosed method.

First claim

The invention claimed is:

1. A process for drying a polymer product comprising providing a transfer line dryer (TLD) having at least an upstream steam jacket and a downstream steam jacket, supplying steam to the upstream steam jacket of the TLD at a first steam delivery rate or pressure at a point D1 at or adjacent to a polymer product inlet to the TLD and supplying steam to the downstream steam jacket of the TLD at a second, lower rate or pressure at a point D2 downstream of the polymer product inlet, in which the first steam delivery rate or pressure is a full steam delivery rate or pressure that is applied to a portion of the TLD between D1 and D2 and a second steam delivery rate or pressure is 0.6 of full steam delivery rate or pressure, or less, throughout a portion of the TLD distal from D2; and flowing the polymer product through the TLD to obtain a dried polymer.

2. The process of claim 1 , further comprising:
sensing or calculating a temperature T1 of a polymer product stream at a point D1 as it enters the TLD;
sensing a second temperature T2 of a polymer product stream or of an inner surface of the TLD, or calculating T2 from a decline in temperature dT from T1 resulting from evaporation of liquid from the polymer product stream as the polymer product stream flows through the TLD, at least at a point D2 along the TLD downstream from D1; and
regulating, based upon T2, a pressure of steam delivered to the steam jacket of the TLD at the point D2 or downstream therefrom so as to maintain a temperature of the inner surface of the TLD below a melting or softening temperature of the polymer product throughout a length of the TLD.

3. The process of claim 1 , in which the upstream steam jacket and downstream steam jacket of the TLD are composed of a plurality of sections configured to receive steam at a controlled delivery rate or pressure at a point in each section of the steam jacket.

4. The process of claim 1 , further comprising a step of regulating the first steam delivery rate or pressure that comprises calculating as the first steam delivery rate or pressure, a rate or pressure required to maintain a temperature to evaporate a liquid volume of the polymer product entering the TLD at D1 over a time t1 for the polymer product to traverse a distance from D1 to D2.

5. The process of claim 4 , in which the distance from D1 to D2 is one-half the total length of the TLD.

6. The process of claim 1 , in which the polymer product is in the form of a slurry comprising solid polymer and monomer or monomer and co-monomer liquid.

7. The process of claim 6 , in which the slurry further comprises a liquid diluent.

8. A transfer line dryer (TLD) comprising
an upstream section of pipe and a downstream section of pipe each jacketed to contain steam, each jacket configured to receive steam from a steam supply and to maintain a desired pressure so as to maintain a desired temperature of an inner surface of the pipe;
a steam feed to the jackets of each of the upstream section of pipe and downstream section of pipe, a pressure controller disposed between a steam feed to a jacket of the upstream section of pipe and a steam feed to a jacket of the downstream section of pipe, the pressure controller controlling the steam feed to a jacket of the downstream section of pipe;
a parallel steam feed joining a point of the steam supply downstream from the pressure controller to the jacket of the upstream section of pipe;
a digital on/off valve disposed in a steam feed to a jacket of the upstream section;
a pressure control valve controlled by the pressure controller and disposed in the steam feed between the digital on/off valve and a point where the parallel steam feed joins the steam feed; and
a check valve disposed in a parallel steam feed to prevent bypass flow around the pressure controller when the digital on/off valve is open.

9. The transfer line dryer of claim 8 , in which the digital on/off valve is actuated by a software application that is programmed to monitor a pressure indicator/controller output (OP) value and if the OP>X % for Z1 seconds and the digital on/off valve is closed, the digital on/off valve is opened to expose the upstream section of pipe to full steam pressure or full steam delivery rate and OP is simultaneously reset to (X−X0)% to maintain stable performance of the TLD, and if the OP<Y % for Z2 seconds and the digital on/off valve is open, the digital on/off valve is closed to expose the upstream section of pipe to controlled steam pressure or controlled steam delivery rate and OP is simultaneously reset to (Y+Y0)% to maintain stable performance of the TLD.

10. The transfer line dryer of claim 9 , in which the software application reads the temperature of a vapor phase of a high pressure separator downstream from the TLD.

11. The transfer line dryer of claim 9 , in which X is from 70 to 90, X0 is from 15 to 25, Z1 is from 40 to 80, Y is from 20 to 60, Y0 is from 10 to 30 and Z2 is from 5 to 15.

12. The transfer line dryer of claim 8 , in which the digital on/off valve is actuated by an application that monitors a TLD steam pressure and a temperature of a product at an end of the TLD, and when both of (a) and (b) are true for a first set time:
a) a TLD steam pressure exceeds a maximum desired pressure, and
b) a temperature of a product at an end of the TLD is below a desired temperature; then the digital on/off valve is closed; or when either of (c) or (d), or both, is/are true for a second set time:
c) a TLD steam pressure is below a maximum desired pressure by a set pressure differential; or
d) a temperature of a product at an end of the TLD is above a desired temperature by a set temperature differential; and then the digital on/off valve is opened.

13. The transfer line dryer of claim 12 , in which the first set time is from 30 to 90 seconds, a second set time is from 5 to 15 seconds, the set pressure differential is from 2 to 8 psi and the set temperature differential is from 1 to 4° C.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Lawson Kevin W

Classifications

• B01D1/0047

  in a closed circuit (B01D3/007 takes precedence) · CPC title

• C08F6/12 Primary

  Separation of polymers from solutions · CPC title

• B01D1/0082

  Regulation; Control · CPC title