Corrosion resistant magnet assembly

Patent metadata

Field	Value
Publication number	US-10553352-B2
Application number	US-201715464077-A
Country	US
Kind code	B2
Filing date	Mar 20, 2017
Priority date	Mar 18, 2016
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

Embodiments of the disclosure pertain to methods of plating magnets with a stack of layers such that the resulting magnet assembly has improved corrosion resistance. Embodiments of the disclosure are also directed to magnet assemblies formed by such methods. Some embodiments include a High Phosphorus Electroless Nickel (HiPEN) layer with Phosphorus content greater than 11% by weight.

First claim

What is claimed is:

1. A receiver magnet assembly comprising:
a magnet; and
a stack of layers disposed over the magnet comprising, in order:
a barrier metal layer;
a catalyst layer comprising palladium or semi-bright nickel; and
a High Phosphorus Electroless Nickel (HiPEN) layer having Phosphorus content that is greater than 11% by weight, wherein the HiPEN layer is the outermost layer of the receiver magnet.

2. The receiver magnet assembly of claim 1 further comprising a stress separation layer disposed between the barrier metal layer and the catalyst layer.

3. The receiver magnet assembly of claim 2 , wherein the barrier metal layer comprises a first transition metal, and the stress separation layer comprises a second transition metal different from the first transition metal.

4. The receiver magnet assembly of claim 3 , wherein the first transition metal is zinc, the second transition metal is copper.

5. The receiver magnet assembly of claim 1 , wherein the magnet is a rare earth magnet.

6. The receiver magnet assembly of claim 1 , wherein the catalyst layer comprises a monolayer of palladium.

7. The receiver magnet assembly of claim 1 , wherein the stack of layers encloses the magnet.

8. The receiver magnet assembly of claim 1 , wherein the catalyst layer increases the deposition rate of the HiPEN layer.

9. A receiver magnet assembly, comprising:
a magnet; and
a stack of layers disposed over the magnet comprising, in order:
a barrier metal layer;
a metal alloy layer;
a metallic passivation layer comprising palladium or semi-bright nickel; and
a High Phosphorus Electroless Nickel (HiPEN) layer having Phosphorus content that is greater than 11% by weight, wherein the HiPEN layer is the outermost layer of the receiver magnet.

10. The receiver magnet assembly of claim 9 wherein the barrier metal layer comprises nickel, the metal alloy layer comprises nickel and zinc, and the metallic passivation layer comprises chromium.

11. The receiver magnet assembly of claim 9 , wherein the metallic passivation layer increases a scratch resistance of the stack of layers.

12. The receiver magnet assembly of claim 9 wherein the magnet is a rare earth magnet.

13. The receiver magnet assembly of claim 9 , wherein the stack of layers encloses the magnet.

14. The receiver magnet assembly of claim 9 , wherein the barrier metal layer comprises a first transition metal and the stack of layers further comprises a stress separation layer comprising a second transition metal different from the first transition metal.

15. A receiver magnet assembly comprising:
a magnet; and
a stack of layers disposed over the magnet comprising, in order:
a first metallic layer;
a second metallic layer different from the first metallic layer, the second metallic layer serving to reduce stress-induced corrosion;
a catalyst layer comprising palladium or semi-bright nickel; and
a High Phosphorus Electroless Nickel (HiPEN) layer having Phosphorus content that is greater than 11% by weight, wherein the HiPEN layer forms an exterior surface of the magnet assembly.

16. The receiver magnet assembly of claim 15 wherein the first metallic layer comprises nickel, the second metallic layer comprises copper, and the catalyst layer comprises semi-bright nickel.

17. The receiver magnet assembly of claim 15 wherein the magnet is a rare earth magnet.

18. The receiver magnet assembly of claim 15 wherein the stack of layers further comprises a metallic passivation layer that comprises chromium.

19. The receiver magnet assembly of claim 15 ,
wherein the receiver magnet is mounted in a yoke of an acoustic receiver.

20. The receiver magnet assembly of claim 15 , wherein the catalyst layer increases the deposition rate of the HiPEN layer.

Assignees

• Apple Inc

Inventors

• Kwok Wai Man Raymund
• Wah Melissa

Classifications

• H01F27/23

  Corrosion protection · CPC title

• H04R2499/11

  Transducers incorporated or for use in hand-held devices, e.g. mobile phones, PDA's, camera's · CPC title

• H04R9/06

  Loudspeakers · CPC title

• H01F7/0221

  Mounting means for PM, supporting, coating, encapsulating PM · CPC title

• H04R9/025 Primary

  Magnetic circuit · CPC title