Actinide and rare earth drawdown system for molten salt recycle

Patent metadata

Field	Value
Publication number	US-10550489-B2
Application number	US-201615206914-A
Country	US
Kind code	B2
Filing date	Jul 11, 2016
Priority date	Jul 11, 2016
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

A method for recycling molten salt from electrorefining processes, the method having the steps of collecting actinide metal using a first plurality of cathodes from an electrolyte bath, collecting rare earths metal using a second plurality of cathodes from the electrolyte bath, inserting the collected actinide metal and uranium into the bath, and chlorinating the inserted actinide metal and uranium. Also provided is a system for recycling molten salt, the system having a vessel adapted to receive and heat electrolyte salt, a first plurality of cathodes adapted to be removably inserted into the vessel, a second plurality of cathodes adapted to be removably inserted into the vessel, an anode positioned within the vessel so as to be coaxially aligned with the vessel, and a vehicle for inserting uranium into the salt.

First claim

The invention claimed is:

1. A method for recycling molten salt from electrorefining processes, the method comprising:
a) providing a single vessel containing a molten salt electrolyte bath comprising actinide metal ions therein;
b) collecting actinide metals onto a first plurality of cathodes immersed in the molten salt electrolyte bath, wherein the cathodes are maintained at a first voltage potential;
c) removing the first plurality of cathodes from the molten salt electrolyte bath and inserting a second plurality of cathodes into the molten salt electrolyte bath;
d) maintaining the second plurality of cathodes at a second voltage potential that is more negative than the first potential to cause rare earth metal to collect onto the second plurality of cathodes;
e) removing the second plurality of cathodes from the molten salt electrolyte bath;
f) inserting the first plurality of cathodes with collected actinide metals and adding uranium metal into the molten salt electrolyte bath; and
g) chlorinating the inserted actinide metals and added uranium metal within the single vessel, wherein actinide metal ions are replenished within the molten salt electrolyte bath.

2. The method as recited in claim 1 wherein the chlorinating step utilizes chlorine gas generated during the collecting steps.

3. The method as recited in claim 1 wherein the actinide metals are collected on the first plurality of cathodes at a first temperature.

4. The method as recited in claim 3 wherein the rare earth metal is collected on the second plurality of cathodes at a second temperature.

5. The method as recited in claim 4 wherein the second temperature is higher than the first temperature.

6. The method as recited in claim 2 wherein the chlorine gas is injected into the bottom of the molten salt electrolyte bath from interior regions of an anode while the first plurality of cathodes is in the molten salt electrolyte bath and electrically connected to the anode.

7. The method as recited in claim 1 wherein the first plurality of cathodes remains in the vessel and not immersed in the molten salt electrolyte bath while the second plurality of cathodes is in the molten salt electrolyte bath.

8. The method as recited in claim 1 wherein cathodes comprising the second plurality of cathodes are different from cathodes comprising the first plurality of cathodes.

9. The method as recited in claim 1 wherein the rare earth metal is used as feedstock for ceramic waste forms.

Assignees

• Willit James L
• Tylka Magdalena M
• Williamson Mark A
• Wiedmeyer Stanley G
• Figueroa Javier
• Uchicago Argonne Llc

Inventors

• Willit James L
• Tylka Magdalena M
• Williamson Mark A
• Wiedmeyer Stanley G
• Figueroa Javier

Classifications

• C25C7/005

  of cells for the electrolysis of melts (C25C7/02 - C25C7/06 take precedence) · CPC title

• C25D3/66

  from melts · CPC title

• C25C3/34 Primary

  of metals not provided for in groups C25C3/02 - C25C3/32 · CPC title

• C25C7/06

  Operating or servicing · CPC title

• G21C19/50

  of irradiated fluid fuel {, e.g. regeneration of fuels while the reactor is in operation} · CPC title