Method of leaching copper from copper sulfide ore and method of evaluating iodine loss content of column leaching test of the copper sulfide ore

Patent metadata

Field	Value
Publication number	US-10550450-B2
Application number	US-201615540689-A
Country	US
Kind code	B2
Filing date	Mar 14, 2016
Priority date	Mar 13, 2015
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

A method of leaching copper from a copper sulfide ore which includes adding a potential adjustment agent for lowering a potential of a leaching solution obtained after leaching copper from the copper sulfide ore by using iodide ion and iron (III) ion, the leaching solution being stored in a tank for storing the leaching solution.

First claim

The invention claimed is:

1. A method of leaching copper from a copper sulfide ore comprising adding a potential adjustment agent for lowering a potential of a leaching solution obtained after leaching copper from the copper sulfide ore by using iodide ion and iron (III) ion and controlling the potential of the leaching solution obtained after leaching copper from the copper sulfide ore at 450 mV (silver-silver chloride electrode reference) or lower, the leaching solution being stored in a tank for storing the leaching solution.

2. The method according to claim 1 , wherein the potential adjustment agent comprises a solution containing iron (II) ion.

3. The method according to claim 2 , comprising controlling a proportion of iron (III) ion concentration relative to a total iron concentration [Fe(III)/FeT ratio] in the leaching solution to 60% by mass or less.

4. The method according to claim 1 , wherein the potential adjustment agent comprises a sulfurous acid solution or an aqueous solution of sulfite.

5. The method according to claim 1 , comprising controlling a proportion of iron (III) ion concentration relative to a total iron concentration [Fe(III)/FeT ratio] in the leaching solution to 60% by mass or less.

6. The method of claim 1 , wherein a concentration of the iron (III) ion used in a step of leaching copper from the copper sulfide ore is more than 20 times as great as a concentration of the iodide ion and the concentration of the iron (III) ion is 2g/L or more.

7. A method of leaching copper from a copper sulfide ore comprising:
a copper leaching step for leaching copper from the copper sulfide ore by using iodide ion and iron (III) ion;
a step for adding a potential adjustment agent for lowering a potential of a leaching solution obtained by the copper leaching step, controlling the potential of the leaching solution obtained after leaching copper from the copper sulfide ore at 450 mV (silver-silver chloride electrode reference) or lower and storing the leaching solution;
a step for recovering a solution containing iodine from the leaching solution in which the potential adjustment agent is added; and
a step for supplying a solution containing recovered iodine to the copper leaching step.

8. The method according to claim 7 , wherein the step for recovering the solution containing iodine comprises a step for treating the leaching solution with an activated carbon and allowing the activated carbon to adsorb iodide ion in the leaching solution.

9. The method according to claim 8 , wherein the potential adjustment agent comprises a solution containing iron (II) ion.

10. The method according to claim 8 , wherein the potential adjustment agent comprises a sulfurous acid solution or an aqueous solution of sulfite.

11. The method according to claim 8 , comprising controlling a proportion of iron (III) ion concentration relative to a total iron concentration [Fe(III)/FeT ratio] in the leaching solution to 60% by mass or less.

12. The method according to claim 7 , comprising:
a step for recovering copper from acidic solution containing copper ion and iron (II) ion obtained in the step of recovering iodide ion contained in the leaching solution;
a step for oxidizing iron (II) ion in the acidic solution to iron (III) ion by treating the acidic solution after copper recovery with iron oxidizing microorganism; and
a step for supplying the iron (III) ion obtained in the step for the oxidization to iron (III) ion to the copper leaching step.

13. The method according to claim 7 , wherein the potential adjustment agent comprises a solution containing iron (II) ion.

14. The method according to claim 7 , wherein the potential adjustment agent comprises a sulfurous acid solution or an aqueous solution of sulfite.

15. The method according to claim 7 , comprising controlling a proportion of iron (III) ion concentration relative to a total iron concentration [Fe(III)/FeT ratio] in the leaching solution to 60% by mass or less.

16. The method of claim 7 , wherein a concentration of the iron (III) ion used in the copper leaching step is more than 20 times as great as a concentration of the iodide ion and the concentration of the iron (III) ion is 2g/L or more.

17. A method for measuring iodine loss content of a column leaching test of copper sulfide ore comprising:
conducting a column leaching test by supplying a leaching solution including iodide ion and iron (III) ion into a column in which copper sulfide ore to be examined is filled; and
measuring a difference between an amount of total iodine content supplied to the column and an amount of total iodine content in a leaching solution discharged from the column, to determine an amount of iodine loss in the column leaching test;
wherein the leaching solution discharged from the column comprises a potential adjustment agent for lowering a potential of the leaching solution so that the potential of the leaching solution is kept at 450 mV (silver-silver chloride electrode reference) or lower.

Assignees

• Jx Nippon Mining & Metals Corp

Inventors

• Kawashiro Shintaro
• Miura Akira

Classifications

• C22B3/06

  in inorganic acid solutions {, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions} · CPC title

• C22B3/04

  by leaching (C22B3/18 takes precedence) · CPC title

• C22B15/0095

  Process control or regulation methods · CPC title

• C22B15/0071 Primary

  containing sulfur · CPC title

• C22B15/0063

  Hydrometallurgy · CPC title