Integrated process for increasing olefin production by recycling and processing heavy cracker residue

Patent metadata

Field	Value
Publication number	US-10550342-B2
Application number	US-201716079422-A
Country	US
Kind code	B2
Filing date	Jan 31, 2017
Priority date	Feb 25, 2016
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

An integrated process for increasing olefin production is described through which heavy cracker residues of fluid catalytic cracking unit and steam cracking unit are completely mixed, and mixed stream is properly recycled and further combined with atmospheric tower bottoms. Combined stream is deasphalted and hydrotreated to produce a proper feedstock for steam cracking unit for manufacturing light olefin compounds. The integrated process produces higher amount of light olefins than a substantially similar process without processing the heavy cracker residues.

First claim

The invention claimed is:

1. An integrated process for increasing olefin production from heavy cracker residues, comprising:
hydrotreating a heavy hydrocarbon residue stream with a first hydrotreater to form a first hydrotreated residue stream;
catalytically cracking the first hydrotreated residue stream in a fluid catalytic cracking unit to form a liquefied petroleum gas stream, a naphtha stream, a dry gas stream, a clarified slurry oil stream and a light cycle oil stream;
hydrotreating the naphtha stream in a second hydrotreater to form a hydrotreated naphtha stream;
hydrocracking the light cycle oil stream in a hydrocracker to form a cracked hydrocarbon stream;
mixing the hydrotreated naphtha stream and the cracked hydrocarbon stream to form an aromatic blended hydrocarbon stream;
saturating the aromatic blended hydrocarbon stream in an aromatic saturating unit to form a saturated hydrocarbon stream;
steam cracking the saturated hydrocarbon stream in a steam cracking unit to form a first olefin stream, a pyrolysis oil stream, and a pyrolysis gasoline stream;
mixing the clarified slurry oil stream and the pyrolysis oil stream to form a recycle oil stream;
deasphalting the recycle oil stream in a solvent deasphalting unit to form a deasphalted oil stream and an asphaltene rich stream;
hydrotreating the deasphalted oil stream and the heavy hydrocarbon residue stream with the first hydrotreater to form a second hydrotreated residue stream; and
cracking the second hydrotreated residue stream to form a second olefin stream.

2. The process of claim 1 , further comprising:
combining the first olefin stream and the second olefin stream to give a final olefin yield that is higher than a substantially similar process without the deasphalting, and without hydrotreating the deasphalted oil stream and the heavy hydrocarbon residue stream.

3. The process of claim 1 , further comprising:
mixing the heavy hydrocarbon residue stream with the recycle oil stream prior to the deasphalting.

4. The process of claim 1 , further comprising:
collecting at least a portion of the asphaltene rich stream for processing into asphalt.

5. The process of claim 1 , wherein the steam cracking forms hydrogen gas in addition to the first olefin stream, the pyrolysis oil stream, and the pyrolysis gasoline stream.

6. The process of claim 5 , further comprising:
delivering at least a portion of the hydrogen gas to the first hydrotreater, the second hydrotreater, or both.

7. The process of claim 1 , wherein the light cycle oil stream is saturated prior to the hydrocracking.

8. The process of claim 1 , wherein the light cycle oil stream is hydrotreated prior to the hydrocracking.

9. The process of claim 1 , further comprising:
removing particulates from the clarified slurry oil stream, the recycle oil stream, or both.

10. The process of claim 1 , wherein the clarified slurry oil stream and the pyrolysis oil stream are mixed in the presence of a miscible organic solvent.

11. The process of claim 1 , wherein the fluid catalytic cracking unit is a residue fluid catalytic cracking unit.

12. An integrated process for increasing olefin production from heavy cracker residues, comprising:
hydrotreating a heavy hydrocarbon residue stream with a first hydrotreater to form a first hydrotreated residue stream;
catalytically cracking the first hydrotreated residue stream in a fluid catalytic cracking unit to form a liquefied petroleum gas stream, a naphtha stream, a dry gas stream, a clarified slurry oil stream and a light cycle oil stream;
hydrotreating the naphtha stream in a second hydrotreater to form a hydrotreated naphtha stream;
hydrocracking the light cycle oil stream in a hydrocracker to form a cracked hydrocarbon stream;
mixing the hydrotreated naphtha stream and the cracked hydrocarbon stream to form an aromatic blended hydrocarbon stream;
saturating the aromatic blended hydrocarbon stream in an aromatic saturating unit to form a saturated hydrocarbon stream;
steam cracking the saturated hydrocarbon stream in a steam cracking unit to form a first olefin stream, a pyrolysis oil stream, and a pyrolysis gasoline stream;
mixing the clarified slurry oil stream and the pyrolysis oil stream to form a recycle oil stream;
deasphalting the recycle oil stream in a solvent deasphalting unit to form a deasphalted oil stream and an asphaltene rich stream;
coking at least a portion of the asphaltene rich stream to form a light hydrocarbon stream;
steam cracking the light hydrocarbon stream to form a third olefin stream;
hydrotreating the deasphalted oil stream and the heavy hydrocarbon residue stream with the first hydrotreater to form a second hydrotreated residue stream; and
cracking the second hydrotreated residue stream to form a second olefin stream.

13. The process of claim 12 , further comprising:
combining the first olefin stream, the second olefin stream, and the third olefin stream to give a final olefin yield that is higher than a substantially similar process without the deasphalting, the coking, steam cracking the light hydrocarbon stream, and hydrotreating the deasphalted oil stream and the heavy hydrocarbon residue stream.

14. The process of claim 12 , further comprising:
mixing the heavy hydrocarbon residue stream with the recycle oil stream prior to the deasphalting.

15. The process of claim 12 , further comprising:
removing particulates from the clarified slurry oil stream, the recycle oil stream, or both.

16. An integrated process for increasing olefin production from heavy cracker residues, comprising:
hydrotreating a heavy hydrocarbon residue stream with a first hydrotreater to form a first hydrotreated residue stream;
catalytically cracking the first hydrotreated residue stream in a fluid catalytic cracking unit to form a liquefied petroleum gas stream, a naphtha stream, a dry gas stream, a clarified slurry oil stream and a light cycle oil stream;
hydrotreating the naphtha stream in a second hydrotreater to form a hydrotreated naphtha stream;
hydrocracking the light cycle oil stream in a hydrocracker to form a cracked hydrocarbon stream;
mixing the hydrotreated naphtha stream and the cracked hydrocarbon stream to form an aromatic blended hydrocarbon stream;
saturating the aromatic blended hydrocarbon stream in an aromatic saturating unit to form a saturated hydrocarbon stream;
steam cracking the saturated hydrocarbon stream in a steam cracking unit to form a first olefin stream, a pyrolysis oil stream, and a pyrolysis gasoline stream;
mixing the clarified slurry oil stream and the pyrolysis oil stream to form a recycle oil stream;
deasphalting the recycle oil stream in a solvent deasphalting unit to form a deasphalted oil stream and an asphaltene rich stream;
partially oxidizing at least a portion of the asphaltene rich stream to produce a synthesis gas stream;
hydrotreating the deasphalted oil stream and the heavy hydrocarbon residue stream with the first hydrotreater to form a second hydrotreated residue stream; and
cracking the second hydrotreated residue stream to form a second olefin stream.

17. The process of claim 16 , wherein the synthesis gas stream comprises hydrogen gas and the process further comprises separating at least a portion of the hydrogen gas from the synthesis gas stream and delivering it to the first hydrotreater, the second hydrotreater, or both.

18. The process of claim 16 , further comprising:
delivering at least a portion of the synthesis gas stream to a processing unit for manufacturing oxo-alde

Assignees

• Sabic Global Technologies Bv

Inventors

• Salazar-Guillen Jose Armando
• Huckman Michael
• Stevenson Scott

Classifications

• C10G2300/1074

  Vacuum distillates · CPC title

• C10G69/04

  including at least one step of catalytic cracking in the absence of hydrogen · CPC title

• C10G67/0454

  Solvent desasphalting · CPC title

• C10G2300/107

  Atmospheric residues having a boiling point of at least about 538 °C · CPC title

• C10G67/14

  including at least two different refining steps in the absence of hydrogen · CPC title