Core-shell particle, method of producing core shell particle, and film

Patent metadata

Field	Value
Publication number	US-10550323-B2
Application number	US-201816200596-A
Country	US
Kind code	B2
Filing date	Nov 26, 2018
Priority date	May 27, 2016
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

An object of the present invention is to provide a core shell particle having high luminous efficacy and excellent durability; a method of producing the same; and a film formed of the core shell particle. The core shell particle of the present invention includes: a core which contains a Group III element and a Group V element; a first shell which covers at least a part of a surface of the core; and a second shell which covers at least a part of the first shell, in which the core shell particle includes a protective layer containing a metal oxide that covers at least a part of the second shell, and at least a part of a surface of the protective layer includes coordination molecules.

First claim

What is claimed is:

1. A core shell particle comprising:
a core which contains a Group III element and a Group V element;
a first shell which covers at least a part of a surface of the core, wherein the first shell is a Group III-V semiconductor which contains Ga as a Group III element and P as a Group V element; and
a second shell which covers at least a part of the first shell,
wherein the core shell particle includes a protective layer containing a metal oxide that covers at least a part of the second shell,
at least a part of a surface of the protective layer includes coordination molecules, and
among the core, the first shell, and the second shell, a band gap of the core is the smallest, and the core and the first shell respectively have a type 1 band structure.

2. The core shell particle according to claim 1 ,
wherein the metal oxide is an oxide containing a Group 12 or Group 13 metal element in the periodic table.

3. The core shell particle according to claim 1 ,
wherein the metal oxide is an oxide containing at least one metal element selected from the group consisting of zinc, indium, and gallium.

4. The core shell particle according to claim 1 ,
wherein the metal oxide is an oxide containing indium.

5. The core shell particle according to claim 1 ,
wherein the Group III element contained in the core is In, and
the Group V element contained in the core is any of P, N, or As.

6. The core shell particle according to claim 1 ,
wherein the Group III element contained in the core is In, and
the Group V element contained in the core is P.

7. The core shell particle according to claim 1 ,
wherein the core further contains a Group II element.

8. The core shell particle according to claim 7 ,
wherein the Group II element contained in the core is Zn.

9. The core shell particle according to claim 1 ,
wherein the second shell is a Group II-VI semiconductor which contains a Group II element and a Group VI element or a Group III-V semiconductor which contains a Group III element and a Group V element.

10. The core shell particle according to claim 9 ,
wherein the second shell is the Group II-VI semiconductor,
the Group II element is Zn, and
the Group VI element is S.

11. The core shell particle according to claim 1 ,
wherein the core, the first shell, and the second shell respectively have a crystal system having a zinc blende structure.

12. A method of producing a core shell particle for synthesizing the core shell particle according to claim 1 , the method comprising:
a first step of heating and stirring a solution obtained by adding a Group III raw material which contains a Group III element to a solvent containing coordination molecules;
a second step of forming a core by adding a Group V raw material which contains a Group V element to the solution after the first step;
a third step of forming a first shell by adding a raw material of the first shell to the solution after the second step, wherein the first shell is a Group III-V semiconductor which contains Ga as a Group III element and P as a Group V element;
a fourth step of adding a raw material of a second shell to the solution after the third step to form the second shell and synthesizing a core shell particle; and
a fifth step of adding a metal raw material to the solution after the fourth step and heating the solution.

13. The method of producing a core shell particle according to claim 12 ,
wherein a thiol compound is further added in the fifth step.

14. The method of producing a core shell particle according to claim 12 ,
wherein the metal raw material is a fatty acid metal salt.

15. The method of producing a core shell particle according to claim 12 ,
wherein the metal raw material is a carboxylate of indium.

16. The method of producing a core shell particle according to claim 12 ,
wherein the heating temperature in the fifth step is in a range of 140° C. to 220° C.

17. The method of producing a core shell particle according to claim 12 ,
wherein the heating temperature in the fifth step is in a range of 160° C. to 220° C.

18. A film which contains the core shell particle according to claim 1 .

Assignees

• Fujifilm Corp

Inventors

• Ono Masashi

Classifications

• C09K11/025

  non-luminescent particle coatings or suspension media · CPC title

• C01P2004/84

  one phase coated with the other · CPC title

• C09K11/56

  containing sulfur · CPC title

• C01P2004/80

  Particles consisting of a mixture of two or more inorganic phases · CPC title

• C09K11/70

  containing phosphorus · CPC title