Encapsulated nanocompositions for increasing hydrocarbon recovery

Patent metadata

Field	Value
Publication number	US-10550311-B2
Application number	US-201816037314-A
Country	US
Kind code	B2
Filing date	Jul 17, 2018
Priority date	Apr 9, 2015
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

A method for increasing production in a liquid hydrocarbon reservoir formation comprising the steps of introducing a nanoencapsulated composition solution capable of reducing the surface tension of a liquid hydrocarbon fraction, where the nanoencapsulated composition solution comprises a nanocapsule and a carrier fluid, such that the nanocapsule is dispersed in the carrier fluid; allowing the nanoencapsulated composition solution to interact with the liquid hydrocarbon fraction such that the surface tension of the liquid hydrocarbon fraction is reduced such that at least a portion of the liquid hydrocarbon fraction is capable of being displaced; introducing a water fraction into the wellbore under conditions such that at least a portion of the liquid hydrocarbon fraction is displaced from the liquid hydrocarbon reservoir formation; and recovering the at least a portion of the liquid hydrocarbon fraction and at least a portion of the nanoencapsulated composition solution using the wellbore.

First claim

What is claimed is:

1. A coacervation method of forming a nanocapsule for use in a nanocapsulated composition solution, the coacervation method comprising the steps of:
(a) mixing an aqueous-phase chemical with water to form an aqueous phase, wherein the aqueous-phase chemical comprises gelatin;
(b) mixing a solvent-phase monomer with a solvent and one or more surfactants to form a solvent phase;
(c) mixing the solvent phase in the aqueous phase, such that the solvent phase forms droplets dispersed in the aqueous phase to form a mixture, wherein the droplets have a surface;
(d) adding a precipitating agent to the mixture, the precipitating agent operable to reduce a solubility of the aqueous-phase chemical in the mixture such that the aqueous-phase chemical is capable of precipitating from the mixture;
(e) allowing the aqueous-phase chemical to precipitate from the mixture to form a precipitating aqueous-phase chemical, wherein the precipitating aqueous-phase chemical deposits on the surface of the droplets to form a deposited aqueous-phase chemical; and
(f) allowing the deposited aqueous-phase chemical to form a polymer shell around the droplets, wherein the polymer shell is formed by the crosslinking of the deposited aqueous-phase chemical.

2. The method of claim 1 , wherein an amount of the one or more surfactants in the solvent phase is in a range from between 1 wt % to 50 wt %.

3. The method of claim 1 , wherein the one or more surfactants are selected from the group consisting of a sulfonate based surfactant, a sulfate based surfactant and a phosphate based surfactant.

4. The method of claim 1 , wherein the one or more surfactants comprises petroleum sulfonate.

5. The method of claim 1 , wherein an amount of the solvent-phase monomer in the solvent phase is in a range from between 1 wt % to 30 wt %.

6. The method of claim 1 , wherein the solvent is selected from the group consisting of iso-octane, acetone, dibutyl sebacate, and combinations thereof.

7. The method of claim 1 , wherein an amount of the aqueous-phase chemical in the aqueous phase is in a range from between 1 wt % to 30 wt %.

8. The method of claim 1 , wherein the aqueous-phase chemical is selected from the group consisting of monomer, gelling agent, chemical soluble in the aqueous phase and insoluble in the solvent phase, and combinations of the same.

9. The method of claim 1 , wherein the precipitating agent is selected from the group consisting of salts, ammonium sulfate, and combinations of the same.

10. The method of claim 1 , wherein the nanocapsules are characterized by individual diameters of between 200 nanometers and 1000 nanometers.

11. The method of claim 1 , further comprising the step of:
adding an amount of a crosslinking agent, wherein the crosslinking agent can control a degree of the crosslinking of the polymer shell.

12. The method of claim 10 , where the crosslinking agent comprises glutaraldehyde.

Assignees

• Saudi Arabian Oil Co

Inventors

• Chang Yun

Classifications

• C09K8/584 Primary

  characterised by the use of specific surfactants · CPC title

• B01J13/16

  Interfacial polymerisation · CPC title

• B01J13/14

  Polymerisation; cross-linking · CPC title

• E21B43/267

  reinforcing fractures by propping · CPC title

• C09K2208/10

  Nanoparticle-containing well treatment fluids · CPC title