Bio-based binder systems

Patent metadata

Field	Value
Publication number	US-10550294-B2
Application number	US-201816018607-A
Country	US
Kind code	B2
Filing date	Jun 26, 2018
Priority date	May 27, 2011
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

An environmentally friendly, bio-based binder system that is useful for the formation of fiberglass insulation, the system includes: A) an aqueous curable binder composition, which includes a carbohydrate and a crosslinking agent; and B) a dedust composition, which includes a blown, stripped plant-based oil and optionally at least one emulsifying agent. The bio-based binder system is typically heated to form a cured binder system.

First claim

What is claimed is:

1. A binder system comprising:
A) an aqueous curable binder composition comprising:
(i) at least one carbohydrate,
(ii) at least one crosslinking agent; and
(iii) partially neutralized citric acid or the reaction product of citric acid and trisodium citrate; and
B) a dedust composition comprising a blown, stripped plant-based oil;
wherein the binder system comprises 10 parts per million sulfur or less based on the weight of components A) and B), excluding water.

2. The binder system of claim 1 , wherein the binder system comprises 5 part per million sulfur or less based on the weight of components A) and B), excluding water.

3. The binder system of claim 1 , wherein the blown, stripped plant-based oil has a viscosity of at least 250 cSt at 40° C.

4. The binder system of claim 1 , wherein the blown, stripped plant-based oil has a viscosity of at least 200 cSt at 40° C., a flash point of at least 293° C., and an acid value less than 5.0 mg KOH/gram.

5. The binder system of claim 1 , further comprising at least one emulsifying component comprising a first emulsifying component contained in dedust composition B), and wherein the dedust composition has less than 100 part per million sulfur, based on the weight of component B), excluding water.

6. The binder composition of claim 5 , wherein the at least one emulsifying component is selected from the group consisting of non-ionic emulsifiers, ionic emulsifiers, and mixtures thereof.

7. The binder system of claim 5 , wherein the dedust composition B) further comprises an aqueous fraction and an organic fraction.

8. The binder system of claim 7 , wherein dedust composition B) comprises an oil in water emulsion and wherein the first emulsifying component is mixed into the blown, stripped plant-based oil of (i) before the emulsion is formed.

9. The binder system of claim 7 , wherein a second emulsifying component is mixed into an aqueous solution before an oil-in-water emulsion is formed.

10. The binder system of claim 9 , wherein the second emulsifying component is selected from the group consisting of carbohydrates, maltodextrin, carboxymethyl cellulose, polyols, and mixtures thereof.

11. The binder system of claim 1 , wherein the blown, stripped plant-based oil has an acid value less than 4.0 mg KOH/gram.

12. The binder system of claim 1 , wherein the blown, stripped plant-based oil comprises a blown, stripped, bodied plant-based oil.

13. The binder system of claim 1 , wherein system comprises from about 0.5 percent by weight to about 11 percent by weight, relative to the amount of the blown, stripped plant-based oil, of a refined, bleached, and deodorized plant based oil having greater than 0.0 percent by weight and less than 2 percent by weight 18:3 fatty acid content.

14. The binder system of claim 1 , wherein the blown, stripped plant-based oil has a hydroxyl number from about 1 mg KOH/gram to about 50 mg KOH/gram.

15. The binder system of claim 1 , wherein the blown, stripped plant based oil has less than 50 ppm sulfur.

16. The binder system of claim 1 , wherein said crosslinking agent is selected from the group consisting of polycarboxylic acids, salts of polycarboxylic acid, anhydrides, monomeric carboxylic acid with anhydride, polycarboxylic acid with anhydride, citric acid, salts of citric acid, adipic acid, salts of adipic acid, polyacrylic acid, salts of polyacrylic acid, polyacrylic acid based resins and combinations thereof.

17. The binder system of claim 1 , wherein the weight ratio of binder composition A) to dedust composition B) is from about 100:1 to 100:34.

18. A cured binder system resulting from heating the binder system of claim 1 at a temperature and for a period of time sufficient to react the carbohydrate (i) with the crosslinking agent (ii) of the binder composition A).

19. The cured binder system of claim 18 , wherein the cured binder system exhibits a lower odor profile than a comparable cured binder system resulting from curing a binder system having greater than 30 ppm sulfur based on the weight of the cured binder system.

20. The cured binder system of claim 18 , wherein the cured binder system is used for the formation of a fiberglass insulation product and the fiberglass insulation product exhibits a lower odor profile than a comparable insulation product, which results from curing a fibrous insulation mat containing a binder system having greater than 15 ppm sulfur.

Assignees

• Cargill Inc

Inventors

• Lochel Jr Frank P
• Tolfa John Carl

Classifications

• C03C25/321

  Starch; Starch derivatives · CPC title

• C08K5/0025

  Crosslinking or vulcanising agents; including accelerators · CPC title

• D04H1/64

  the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions · CPC title

• C09J103/04

  Starch derivatives · CPC title

• D04H3/004

  Glass yarns or filaments · CPC title