Antimicrobial glass compositions, glasses and polymeric articles incorporating the same
US-9622483-B2 · Apr 18, 2017 · US
US10550270B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10550270-B2 |
| Application number | US-201615737410-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 22, 2016 |
| Priority date | Jun 26, 2015 |
| Publication date | Feb 4, 2020 |
| Grant date | Feb 4, 2020 |
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Aspects of this disclosure pertain to a colorless material that includes a carrier, copper-containing particles, and either one or both of sodium thiocyanate and titanium dioxide. In one or more embodiments, the material exhibits, in the CIE L*a*b* system, an L* value in the range from about 91 to about 100, and a C* value of less than about 7, wherein C* equals √(a*2+b*2). In some embodiments, the material exhibits a greater than 3 log reduction in a concentration of Staphylococcus aureus, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing conditions.
Opening claim text (preview).
What is claimed is: 1. A colorless material comprising a carrier; copper-containing particles; and sodium thiocyanate, wherein the material exhibits, in the CIE L*a*b* system, an L* value in the range from about 91 to about 100, and a C* value of less than about 7, wherein C* equals √(a* 2 +b* 2 ), and wherein the material exhibits a greater than 3 log reduction in a concentration of Staphylococcus aureus , under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing conditions. 2. The material of claim 1 , wherein the copper-containing particles comprise a copper-containing glass. 3. The material of claim 1 , wherein the copper-containing particles comprise cuprous oxide. 4. The material of claim 1 , wherein the copper-containing particles are present in an amount of about 200 g/gallon of the carrier or less. 5. The material of claim 1 , wherein the sodium thiocyanate is present in an amount of about 100 g/gallon or less. 6. The material of claim 1 , wherein the carrier comprises a polymer, a monomer, a binder or a solvent. 7. The material of claim 1 , wherein the carrier comprises paint. 8. The material of claim 2 , wherein the copper-containing glass comprises a cuprite phase comprising a plurality of Cu 1+ ions, and comprising at least one of B 2 O 3 , P 2 O 5 and R 2 O, wherein R is at least one of K, Na, Li, Rb, and Cs. 9. The material of claim 8 , further comprising a glass phase, wherein the glass phase comprises more than 40 mol % SiO 2 . 10. The material of claim 8 , wherein the cuprite phase is degradable and leaches in the presence of water. 11. A paint comprising: a plurality of cuprous ions, sodium thiocyanate, wherein the paint exhibits a 99% or greater reduction in a concentration of Staphylococcus aureus , under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing conditions, and wherein the paint exhibits, in the CIE L*a*b* system, an L* value in the range from about 90 to about 100, and a C* value of less than about 9, wherein C* equals √(a* 2 +b* 2 ). 12. The paint of claim 11 , further comprising copper-containing particles, wherein the particle comprise either one or both of copper-containing glass and cuprous oxide, wherein the copper-containing particles are present in an amount of about 200 g/gallon or less.
Glass · CPC title
inorganic · CPC title
Particles; Flakes · CPC title
the non-glass component being in the form of particles or flakes · CPC title
Cyanogen or compounds thereof, e.g. hydrogen cyanide, cyanic acid, cyanamide, thiocyanic acid · CPC title
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