Rubber composition and tire

Patent metadata

Field	Value
Publication number	US-10550248-B2
Application number	US-201414913638-A
Country	US
Kind code	B2
Filing date	Aug 11, 2014
Priority date	Aug 23, 2013
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

The present invention provides a rubber composition capable of producing a rubber molded article that is excellent in rolling resistance performance, steering stability, mechanical strength and abrasion resistance, and a tire obtained by using the rubber composition in at least a part thereof. The present invention relates to a rubber composition including (A) a rubber component including at least one rubber selected from the group consisting of a synthetic rubber and a natural rubber, (B) silica and (C) a modified polymer of farnesene obtained by introducing a functional group into a polymer of farnesene, in which a content of the silica (B) in the rubber composition is from 20 to 150 parts by mass on the basis of 100 parts by mass of the rubber component (A), and a content of the modified farnesene polymer (C) in the rubber composition is from 2 to 10 parts by mass on the basis of 100 parts by mass of the silica (B).

First claim

The invention claimed is:

1. A rubber composition comprising (A) a rubber component comprising at least one rubber selected from the group consisting of a styrene-butadiene rubber, a butadiene rubber, an isoprene rubber, a butyl rubber, a halogenated butyl rubber, an ethylene propylene diene rubber, a butadiene acrylonitrile copolymer rubber, a chloroprene rubber and a natural rubber, (B) silica and (C) a modified polymer consisting of farnesene units, optionally other monomer units, and a functional group on the modified polymer,
wherein the functional group is selected from the group consisting of an amino group, an ammonium group, an amide group, an imino group, an imidazole group, a urea group, an alkoxysilyl group, a silanol group, a hydroxy group, an epoxy group, an ether group, a carboxy group, a carbonyl group, a carboxylate group, a sulfonic group, a sulfonate group, a phosphoric group, a phosphate group, a mercapto group, an isocyanate group, a nitrile group, a silicon halide group, a tin halide group and a functional group derived from an acid anhydride,
in which a content of the silica (B) in the rubber composition is from 20 to 150 parts by mass on the basis of 100 parts by mass of the rubber component (A), and a content of the modified polymer (C) in the rubber composition is from 2 to 10 parts by mass on the basis of 100 parts by mass of the silica (B), and
wherein the other monomer units are one or more of a conjugated diene having not more than 12 carbon atoms selected from the group consisting of butadiene, isoprene, 2,3-dimethyl-butadiene, 2-phenyl-butadiene, 1,3-pentadiene, 2-methyl-1,3-pentadiene, 1,3-hexadiene, 1,3-octadiene, 1,3-cyclohexadiene, 2-methyl-1,3-octadiene, 1,3,7-octatriene, myrcene and chloroprene.

2. The rubber composition according to claim 1 , wherein the functional group of the modified polymer (C) is at least one group selected from the group consisting of a carboxy group, an amino group, a hydroxy group and a functional group derived from an acid anhydride.

3. The rubber composition according to claim 1 , wherein the silica (B) has an average particle size of from 0.5 to 200 nm.

4. The rubber composition according to claim 1 , wherein the modified polymer (C) has a melt viscosity of from 0.1 to 3,000 Pa·s as measured at 38° C.

5. The rubber composition according to claim 1 , wherein the modified polymer (C) has a weight-average molecular weight (Mw) of from 2,000 to 500,000.

6. The rubber composition according to claim 1 , wherein the modified polymer (C) is a copolymer constituted of (c1) a monomer unit derived fromβ-farnesene and (c2) a monomer unit derived from a monomer other than β-farnesene.

7. The rubber composition according to claim 1 , further comprising a silane coupling agent in an amount of from 0.1 to 30 parts by mass on the basis of 100 parts by mass of the silica (B).

8. The rubber composition according to claim 1 , wherein the rubber component (A) comprises at least one rubber selected from the group consisting of a styrene-butadiene rubber, a butadiene rubber, an isoprene rubber and a natural rubber.

9. The rubber composition according to claim 1 , wherein the other monomer units are selected from the group consisting of butadiene, isoprene, and myrcene.

10. The rubber composition according to claim 1 , wherein the functional group is a functional group derived from an acid anhydride.

11. The rubber composition according to claim 10 , wherein the functional group derived from an acid anhydride is selected from the group consisting of a carboxylic acid anhydride group, a dicarboxylic acid group obtained by ring-opening reaction of carboxylic anhydride, a dicarboxylic acid monoester group obtained by ring-opening reaction of carboxylic anhydride and a dicarboxylic acid monoamide group obtained by ring-opening reaction of carboxylic anhydride.

12. The rubber composition according to claim 1 , wherein the rubber component (A) comprises at least one rubber selected from the group consisting of a styrene-butadiene rubber and a natural rubber.

13. The rubber composition according to claim 12 , wherein the rubber component (A) comprises the styrene-butadiene rubber, which has a weight-average molecular weight of from 100,000 to 2,500,000.

14. The rubber composition according to claim 12 , wherein the rubber component (A) comprises the styrene-butadiene rubber, which has a styrene content of from 0.1 to 70% by mass.

15. A tire comprising the rubber composition according to claim 1 in at least a part thereof.

Assignees

• Kuraray Co
• Amyris Inc

Inventors

• Koda Daisuke
• Hirata Kei

Classifications

• C08K3/36

  Silica · CPC title

• C08L9/06 Primary

  Copolymers with styrene · CPC title

• C08K5/54

  Silicon-containing compounds {(C08K5/0091 takes precedence)} · CPC title

• C08L7/00 Primary

  Compositions of natural rubber · CPC title

• B60C1/00 Primary

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title