Process for production of cross-linked polyethylene articles

Patent metadata

Field	Value
Publication number	US-10550206-B2
Application number	US-201414484840-A
Country	US
Kind code	B2
Filing date	Sep 12, 2014
Priority date	Feb 21, 2012
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

A method of producing a sliane cross-linked polyethylene is disclosed which includes maleating a polyethylene polymer to form a maleated polyethylene and reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene. The method further includes treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked polyethylene.

First claim

What is claimed is:

1. A silane cross-linked maleated polyethylene article consisting of a silane cross-linked maleated polyethylene, wherein the silane cross-linked maleated polyethylene is a maleated high density polyethylene having no more than two maleic anhydride groups on each side chain of the maleated polyethylene, and wherein the silane cross-linked maleated polyethylene is made by the process consisting of:
maleating a high density polyethylene polymer to form the maleated polyethylene, wherein maleating the polyethylene polymer comprises combining the high density polyethylene polymer, a free radical initiator, and maleic anhydride to form a reaction mixture, wherein the maleic anhydride concentration is at least 1.8 wt % percent of the reaction mixture;
optionally passing an inert gas over or through the maleated polyethylene;
reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene;
optionally adding a silane crosslinking catalyst; and
treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked maleated polyethylene.

2. The article of claim 1 , wherein the article is pipe, wire coatings, insulation jacketing for voltage cables, insulation foams, and heat shrinkable products.

3. The article of claim 1 , wherein the maleic anhydride concentration is at least 3 wt % percent of the reaction mixture.

4. The article of claim 1 , wherein the maleic anhydride concentration is about 4 to about 7 wt % percent of the reaction mixture.

5. The article of claim 1 , wherein the primary or secondary amino silane is 3-aminopropyltriethoxysilane.

6. The article of claim 1 , wherein the primary or secondary amino silane is N-(n-butyl)-3-amino-propyltrimethoxysilane.

7. The article of claim 1 , wherein the step of maleating the polyethylene polymer is performed in a screw extruder or a continuously stirred reactor.

8. The article of claim 1 , wherein the free radical initiator is selected from the group consisting of di-t-butylperoxide, di-(t-butylperoxyisopropyl)benzene, 2,5-dimethyl-2,5-di-(t-butylperoxy)-3-hexene, benzoyl peroxide, and 2,5-dimethyl-2,5-di(t-butylperoxy)hexane.

9. The article of claim 1 , wherein the free radical initiator is a peroxide, and wherein the peroxide concentration is at least 0.5 wt % of the reaction mixture.

10. The article of claim 9 , wherein the peroxide concentration is from about 0.6 to 0.8 wt % of the reaction mixture.

11. The article of claim 1 , wherein the step of maleating the polyethylene polymer is performed at a temperature of from about 130° C. to about 190° C.

12. The article of claim 1 , wherein the silane cross-linked maleated polyethylene is made by the process consisting of:
maleating a high density polyethylene polymer to form the maleated polyethylene, wherein maleating the polyethylene polymer comprises combining the high density polyethylene polymer, a free radical initiator, and maleic anhydride to form a reaction mixture, wherein the maleic anhydride concentration is at least 1.8 wt % percent of the reaction mixture;
passing an inert gas over or through the maleated polyethylene;
reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene;
optionally adding a silane crosslinking catalyst; and
treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked maleated polyethylene.

13. The article of claim 1 , wherein the step of reacting the maleated polyethylene with a primary or secondary amino silane is performed at between 180° C. and 250° C.

14. The article of claim 1 , wherein the moisture curing process is performed by subjecting the silane-grafted polyethylene to a water bath or a steam sauna.

15. The article of claim 1 , wherein the silane cross-linked maleated polyethylene is made by the process consisting of:
maleating a high density polyethylene polymer to form the maleated polyethylene, wherein maleating the polyethylene polymer comprises combining the high density polyethylene polymer, a free radical initiator, and maleic anhydride to form a reaction mixture, wherein the maleic anhydride concentration is at least 1.8 wt % percent of the reaction mixture;
optionally passing an inert gas over or through the maleated polyethylene;
reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene;
adding a silane crosslinking catalyst; and
treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked maleated polyethylene.

16. The article of claim 15 , wherein the silane crosslinking catalyst is a metal carboxylate, an organic base, an inorganic acid, or an organic acid.

17. The article of claim 15 , wherein the silane crosslinking catalyst is dibutyl tin dilaurate, dibutyl tin diacetate, dioctyl tin dilaurate, stannous acetate, stannous caprylate, lead naphthenate, zinc caprylate, cobalt naphthenate, ethyl amines, dibutyl amine, hexylamines, pyridine, sulphuric acid, hydrochloric acid, toluene sulphonic acid, acetic acid, or stearic acid.

18. The article of claim 1 , wherein each side chain of the silane cross-linked maleated polyethylene has only one or two silane groups.

Assignees

• Fina Technology
• Total American Services Inc

Inventors

• Li Fengkui
• Ashbaugh John
• Clark Jason

Classifications

• C08F2810/20

  leading to a crosslinking, either explicitly or inherently · CPC title

• C08F10/02

  Ethene · CPC title

• C08F255/02 Primary

  on to polymers of olefins having two or three carbon atoms · CPC title

• C08F222/04

  Anhydrides, e.g. cyclic anhydrides · CPC title

• C08F255/023

  On to modified polymers, e.g. chlorinated polymers · CPC title