Method for preparing dimethyl disulphide

Patent metadata

Field	Value
Publication number	US-10550077-B2
Application number	US-201515323564-A
Country	US
Kind code	B2
Filing date	Jun 29, 2015
Priority date	Jul 4, 2014
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

The present invention relates to a method for preparing dimethyl disulphide, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a), such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and optionally hydrogen (H2); c) optionally, but preferably, recirculating said hydrogen sulphide (H2S) formed in step b) to step a); d) reacting the methyl mercaptan formed in step b) with sulphur such as to form dimethyl disulphide and hydrogen sulphide; e) optionally recirculating the hydrogen sulphide formed during step d) to step a); and f) recovering the dimethyl disulphide.

First claim

The invention claimed is:

1. A process for preparing dimethyl disulphide, batchwise or continuously, said process comprising at least the following steps:
a) reacting at least one hydrocarbon charge in the presence of hydrogen sulphide (H 2 S) and optionally of sulphur (S) to form carbon disulphide (CS 2 ) and hydrogen (H 2 ),
b) carrying out a hydrogenation reaction of said carbon disulphide (CS 2 ) in the presence of said hydrogen (H 2 ), both obtained in step a), to form methyl mercaptan (CH 3 SH), hydrogen sulphide (H 2 S) and optionally hydrogen (H 2 ),
c) optionally, recycling said hydrogen sulphide (H 2 S) formed in step b) to step a),
d) reacting the methyl mercaptan formed in step b) with sulphur to form dimethyl disulphide and hydrogen sulphide,
e) optionally recycling into step a) the hydrogen sulphide formed in step d), and
f) recovering the dimethyl disulphide.

2. The process according to claim 1 , wherein the hydrocarbon charge is a hydrocarbon charge in gaseous, liquid or solid form and comprises at least one hydrocarbon having a hydrocarbon chain in saturated or unsaturated linear, branched or cyclic form.

3. The process according to claim 1 , wherein the hydrocarbon charge comprises at least one alkane.

4. The process according to claim 1 , wherein the hydrocarbon charge is methane.

5. The process according to claim 1 , wherein the hydrogen sulphide formed in step b) is recycled into step a).

6. The process according to claim 1 , wherein hydrogen is formed in step b) and is reacted with sulphur to form hydrogen sulphide.

7. The process according to claim 1 , wherein the hydrogen sulphide formed in step d) is recycled into step a).

8. The process according to claim 1 , wherein the molar H 2 S/hydrocarbon charge ratio is between 0.5 and 10, endpoints included.

9. The process according to claim 1 , wherein step a) is carried out at a reaction temperature between 500° C. and 1300° C.

10. The process according to claim 1 , wherein step b) is carried out at a reaction temperature between 100° C. and 400° C.

11. The process according to claim 1 , wherein the co-produced hydrogen is wholly or partly converted to thermal energy.

12. The process according to claim 1 , wherein said hydrogen sulphide (H 2 S) formed in step b) is recycled to step a).

13. The process according to claim 1 , wherein the hydrocarbon charge comprises at least one alkane selected from the group consisting of methane (CH 4 ), ethane, propane and butane.

14. The process according to claim 1 , wherein the hydrocarbon charge is a hydrocarbon charge in gaseous form.

15. The process according to claim 1 , wherein the molar H 2 S/hydrocarbon charge ratio is between 1 and 3, endpoints included.

16. The process according to claim 1 , wherein step a) is carried out at a reaction temperature between 700° C. and 1100° C.

17. The process according to claim 1 , wherein step a) is carried out at a reaction temperature between 800° C. and 1000° C.

18. The process according to claim 1 , wherein step b) is carried out at a reaction temperature between 200° C. and 300° C.

19. The process according to claim 1 , wherein the co-produced hydrogen is wholly or partly converted to thermal energy, the thermal energy being used for the heating of the reaction or reactions of step a), of step b) and/or of step d).

20. The process according to claim 1 , wherein all of the hydrogen sulphide consumed in said process is produced in said process.

Assignees

• Arkema France

Inventors

• Fremy Georges
• Barre Patrice
• Raymond Jean-Michel

Classifications

• C07C319/02

  of thiols · CPC title

• C01B32/75

  Preparation by reacting sulfur or sulfur compounds with hydrocarbons · CPC title

• C07C319/24 Primary

  by reactions involving the formation of sulfur-to-sulfur bonds · CPC title

• C07C321/14

  of an acyclic saturated carbon skeleton · CPC title

• C07C321/04

  of an acyclic saturated carbon skeleton · CPC title