Method for producing nickel powder

Patent metadata

Field	Value
Publication number	US-10549351-B2
Application number	US-201515544541-A
Country	US
Kind code	B2
Filing date	Mar 26, 2015
Priority date	Jan 22, 2015
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

A method for producing nickel powder sequentially includes: a mixing step of adding, to a nickel ammine sulfate complex solution, an insoluble solid as seed crystals and a polyacrylate or lignosulfonate as a dispersant to form a mixed slurry; and a reduction and precipitation step of charging a reaction vessel with the mixed slurry and blowing hydrogen gas into the mixed slurry in the reaction vessel to reduce nickel complex ions in the mixed slurry to form nickel precipitate on the surface of the insoluble solid, wherein the amount of the dispersant added in the mixing step is controlled to control the number of the nickel powder obtained by formation of the nickel precipitate in the reduction and precipitation step.

First claim

The invention claimed is:

1. A method for producing nickel powder, sequentially comprising:
a mixing step of adding, to a solution containing a nickel ammine sulfate complex, an insoluble solid that has a diameter of 0.05 to 3 mm and a shape with no edges as seed crystals, and a predetermined amount of a polyacrylate or lignosulfonate as a dispersant to form a mixed slurry;
a reduction and precipitation step of charging a reaction vessel with the mixed slurry and blowing hydrogen gas into the mixed slurry that is formed in the mixing step in the reaction vessel to reduce nickel complex ions in the mixed slurry to form precipitate of nickel particles on a surface of the insoluble solid; and
a separation step of separating the precipitate of nickel particles from the surface of the insoluble solid to form a separated nickel precipitate and sieving the separated nickel precipitate to obtain nickel powder, thereby producing nickel powder with the number of the nickel powder controlled.

2. The method for producing nickel powder according to claim 1 , wherein the shape of the insoluble solid is spherical.

3. The method for producing nickel powder according to claim 1 , wherein the shape of the insoluble solid is elliptical.

4. A method for producing nickel powder, sequentially comprising:
a mixing step of adding, to a solution containing a nickel ammine sulfate complex, an insoluble solid that has a diameter of 0.05 to 3 mm and a shape with no edges as seed crystals, and a polyacrylate or lignosulfonate as a dispersant to form a mixed slurry;
a reduction and precipitation step of charging a reaction vessel with the mixed slurry and blowing hydrogen gas into the mixed slurry that is formed in the mixing step, in the reaction vessel to reduce nickel complex ions in the mixed slurry to form nickel precipitate on a surface of the insoluble solid; and
a separation step of separating the nickel precipitate from the surface of the insoluble solid to form a separated nickel precipitate and sieving the separated nickel precipitate to obtain nickel powder, wherein
an amount of the dispersant added in the mixing step is controlled so that when the dispersant is the polyacrylate, an amount of the polyacrylate added is in a range of 1% by weight to 10% by weight of an amount of the insoluble solid added to the mixed slurry or when the dispersant is the lignosulfonate, an amount of the lignosulfonate added is in a range of 2% by weight to 20% by weight of the amount of the insoluble solid added to the mixed slurry, thereby to control the number of the nickel powder obtained by formation of the nickel precipitate in the reduction and precipitation step.

5. The method for producing nickel powder according to claim 4 , wherein an amount of the polyacrylate added as a dispersant is 2 to 6% by weight based on the weight of the insoluble solid as seed crystals.

6. The method for producing nickel powder according to claim 5 , wherein the polyacrylate as a dispersant is sodium polyacrylate (PAA).

7. The method for producing nickel powder according to claim 4 , wherein the polyacrylate as a dispersant is sodium polyacrylate (PAA).

8. The method for producing nickel powder according to claim 4 , wherein the shape of the insoluble solid is spherical.

9. The method for producing nickel powder according to claim 4 , wherein the shape of the insoluble solid is elliptical.

Assignees

• Sumitomo Metal Mining Co

Inventors

• HEGURI Shin-ichi
• Ozaki Yoshitomo
• Takaishi Kazuyuki
• Yoneyama Tomoaki
• Ohara Hideki
• Ikeda Osamu
• Kudo Yohei

Classifications

• B22F9/26 Primary

  using gaseous reductors · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title