Zeolite catalysts, methods for producing zeolite catalysts, and methods for producing lower olefins

Patent metadata

Field	Value
Publication number	US-10549267-B2
Application number	US-201916402506-A
Country	US
Kind code	B2
Filing date	May 3, 2019
Priority date	Jul 26, 2012
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

Provided are zeolite catalysts that allow reactions to proceed at temperatures as low as possible when lower olefins are produced from hydrocarbon feedstocks with low boiling points such as light naphtha, make it possible to make propylene yield higher than ethylene yield in the production of lower olefins, and have long lifetime. The zeolite catalysts are used in the production of lower olefins from hydrocarbon feedstocks with low boiling points such as light naphtha. The zeolite catalysts are MFI-type crystalline aluminosilicates containing iron atoms and have molar ratios of iron atoms to total moles of iron atoms and aluminum atoms in the range from 0.4 to 0.7. The use of the zeolite catalysts make it possible to increase propylene yield, to lower reaction temperatures, and to extend catalyst lifetime.

First claim

The invention claimed is:

1. A method for producing lower olefins having 2 to 4 carbon atoms from hydrocarbon feedstocks with low boiling points having a range of boiling points from 35° C. to 200° C., the method comprising:
performing reactions to produce the lower olefins from the hydrocarbon feedstocks with low boiling points in the presence of a zeolite catalyst at a reaction temperature in the range of from 525° C. to 575° C.,
wherein the zeolite catalyst comprises a MFI-type crystalline aluminosilicate containing iron atoms in a skeleton resulting from a hydrothermal synthesis reaction based on an iron source, a silicon source, and an aluminum source, and
wherein the zeolite catalyst has a molar ratio of iron atoms to total moles of iron atoms and aluminum atoms in the range of from 0.4 to 0.7.

2. The method according to claim 1 ,
wherein the lower olefins are produced from the hydrocarbon feedstocks with low boiling points which are diluted with at least one of inert gas and steam, and
wherein the zeolite catalyst has an acid density, defined as molar ratios of silicon atoms to total moles of iron atoms and aluminum atoms, in the range of from 12.0 to 45.0.

3. The method according to claim 1 ,
wherein the lower olefins are produced from the hydrocarbon feedstocks with low boiling points which are not diluted, and
wherein the zeolite catalyst has an acid density, defined as molar ratios of silicon atoms to total moles of iron atoms and aluminum atoms, in the range of from 75.0 to 200.0.

Assignees

• Chiyoda Corp

Inventors

• Hodoshima Shinya
• Yagi Fuyuki
• Motomiya Azusa
• Wakamatsu Shuhei
• Asaoka Sachio

Classifications

• B01J29/87

  Gallosilicates; Aluminogallosilicates; Galloborosilicates {(B01J29/005 takes precedence)} · CPC title

• B01J29/405

  containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead · CPC title

• C01B39/065

  Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates · CPC title

• B01J29/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively · CPC title

• C07C2529/42

  containing iron group metals, noble metals or copper · CPC title