Systems, methods and materials for NOx decomposition with metal oxide materials

Patent metadata

Field	Value
Publication number	US-10549236-B2
Application number	US-201916260447-A
Country	US
Kind code	B2
Filing date	Jan 29, 2019
Priority date	Jan 29, 2018
Publication date	Feb 4, 2020
Grant date	Feb 4, 2020

Abstract

Systems and methods use oxygen uncoupling metal oxide material for decomposition of NO x . A gaseous input stream comprising NO x is contacted with a metal oxide particle, generating nitrogen (N 2 ) gas and an oxidized metal oxide particle. After contacting the first gaseous input stream with the metal oxide particle, a first gaseous product stream is collected. The first gaseous product stream includes substantially no NO x . A second gaseous input stream comprising at least one sweeping gas is also contacted with the oxidized metal oxide particle. After contacting the oxidized metal oxide particle, the sweeping gas includes oxygen (O 2 ) and a reduced metal oxide particle is generated. Then a second gaseous product stream is collected, where the second gaseous product stream includes oxygen (O 2 ) gas.

First claim

We claim:

1. A method comprising:
contacting a first gaseous input stream comprising NO x with a metal oxide particle, whereupon the NO x in the first gaseous input stream reacts with the metal oxide particle to generate nitrogen (N 2 ) gas and an oxidized metal oxide particle,
wherein contacting the first gaseous input stream with the metal oxide particle occurs at a first temperature of from 400° C. to 700° C.;

collecting a first gaseous product stream comprising substantially no NO x ;
contacting a second gaseous input stream comprising at least one sweeping gas with the oxidized metal oxide particle, whereupon the sweeping gas comprises oxygen (O 2 ) gas after contacting the oxidized metal oxide particle and a reduced metal oxide particle is generated,
wherein the at least one sweeping gas is oxygen (O 2 ) gas free;
wherein contacting the second gaseous input stream with the oxidized metal oxide particle occurs at a second temperature of from 600° C. to 1000° C.; and

collecting a second gaseous product stream comprising the oxygen (O 2 ) gas.

2. The method according to claim 1 , wherein contacting the first gaseous input stream with the metal oxide particle occurs in a first reactor operating at the first temperature; and
wherein contacting the second gaseous input stream with the oxidized metal oxide particle occurs in the first reactor operating at the second temperature.

3. The method according to claim 2 , further comprising:
monitoring NO x content in the first gaseous input stream;
upon the NO x content exceeding a predetermined threshold, stopping contacting the first gaseous input stream with the metal oxide particle;
after stopping contacting the first gaseous input stream with the metal oxide particle, heating the first reactor to the second temperature;
after heating the first reactor to the second temperature, contacting the second gaseous input stream with the oxidized metal oxide particle;
after a predetermined time, stopping contacting the second gaseous input stream with the oxidized metal oxide particle; and
lowering a first reactor temperature to the first temperature.

4. The method according to claim 3 , further comprising using the reduced metal oxide particle as the metal oxide particle during contacting the first gaseous input stream with the metal oxide particle.

5. The method according to claim 1 , further comprising:
providing the metal oxide particle to the first reactor,
wherein contacting the first gaseous input stream with the metal oxide particle occurs in the first reactor operating at the first temperature; and
wherein collecting the first gaseous product stream includes providing a first reactor outlet stream substantially free of NO x gas; and

providing the oxidized metal oxide particle to the second reactor,
wherein contacting the second gaseous input stream with the oxidized metal oxide particle occurs in a second reactor operating at the second temperature; and
wherein collecting the second gaseous product stream includes providing a second reactor outlet stream comprising the oxygen (O 2 ) gas.

6. The method according to claim 5 , further comprising using the reduced metal oxide particle as the metal oxide particle provided to the first reactor.

7. The method according to claim 1 , wherein the first gaseous product stream includes less than 0.001% by volume NO x .

Assignees

• Ohio State Innovation Foundation

Inventors

• Fan Liang-Shih
• Baser Deven Swapneshu
• Sandvik Peter
• Kathe Mandar
• Fryer Charles

Classifications

• B01D2251/40

  Alkaline earth metal or magnesium compounds · CPC title

• B01D53/565 Primary

  by treating the gases with solids · CPC title

• B01D2255/2047

  Magnesium · CPC title

• B01D2251/602

  Oxides · CPC title

• B01D2255/20746

  Cobalt · CPC title