Fluid comprising methane and a tracer, and processes for producing it and the use thereof

Patent metadata

Field	Value
Publication number	US-10544378-B2
Application number	US-201615770678-A
Country	US
Kind code	B2
Filing date	Oct 20, 2016
Priority date	Oct 26, 2015
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

A labelled methane, such as LNG, has methane and a tracer, in the form of a slush of liquids and solids. The invention especially relates to LNG having a tracer. The labelled methane may comprise, in addition to the tracer, an odorant, and a carrier for the odorant. The odorant is ethyl acetate and/or ethyl mercaptan. The carrier for the odorant is propane, n-butane, iso-butane, or a mixture of two or more thereof. A process for preparing the liquid or slush involves liquefying a gas comprising methane and tracer.

First claim

That which is claimed is:

1. A labelled methane comprising fluid comprising:
a methane comprising fluid,
methyl acetate, in a range of from 1 to 250 ppm, calculated on the total mass of the labelled methane comprising fluid;
an odorant in a range of from 1 to 100 ppm, and
a carrier in a range of from 0.1 to 10 m/m %, calculated on the total mass of the labelled methane comprising fluid;

wherein the carrier is propane, n-butane, iso-butane, or a mixture of two or more thereof, and
wherein the odorant is ethyl acrylate, ethyl mercaptan, or a mixture thereof,
wherein the labelled methane comprising fluid is a liquid, or a slush of liquid and solids.

2. The labelled methane comprising fluid according to claim 1 , wherein the labelled methane comprising fluid comprises 2 to 10 ppm odorant, calculated on the total mass of the labelled methane comprising fluid.

3. The labelled methane comprising fluid according to claim 1 , wherein the labelled methane comprising fluid comprises 4 to 6 ppm odorant, calculated on the total mass of the labelled methane comprising fluid.

4. The labelled methane comprising fluid according to claim 1 , wherein the carrier is iso-butane.

5. The labelled methane comprising fluid according to claim 1 , wherein the odorant is ethyl acrylate or a mixture of ethyl acrylate and ethyl mercaptan.

6. A fuel for automotive industry, marine industry, or for power generation, comprising an odorized methane comprising fluid according to claim 1 .

7. The labelled methane comprising fluid according to claim 1 , wherein the labelled methane comprising fluid is at a temperature in the range of from −62° C. to −185° C., and at a pressure in the range of from 20 mbara to 120 bara.

8. The labelled methane comprising fluid according to claim 7 , wherein the odorized methane is at a pressure of from 250 mbara to 76 bara.

9. A process for preparing a labelled methane comprising fluid comprising methyl acetate in a range of from 1 to 250 ppm, the process comprising the following steps:
a) adding methyl acetate to a methane comprising liquid, or a methane comprising slush of liquid and solids;
b) adding an odorant in a range of from 1 to 100 ppm, and a carrier in a range of from 0.1 to 10 m/m % wherein the odorant and the carrier are added separately and/or mixed, and
wherein the methyl acetate is added separately and/or mixed with the odorant and/or the carrier, and
wherein the carrier is propane, n-butane, iso-butane, or a mixture of two or more thereof, and
wherein the odorant is ethyl acrylate, ethyl mercaptan, or a mixture thereof.

10. The process according to claim 9 , comprising the following steps:
b1) adding the odorant to the carrier and
b2) adding at least a part of the mixture obtained in step b1) to a methane comprising liquid, or a methane comprising slush of liquid and solids, and adding methyl acetate separately and/or mixed with the odorant and the carrier.

11. The process according to claim 9 , wherein a stream comprising a tracer and/or the odorant is added to a gas stream, the liquid stream, or the stream of a slush of liquid and solids, using a flow controller or an injection pump and a PLC (programmable logic controller).

12. The process according to claim 9 , wherein the liquid or slush comprising methane is at a temperature in a range of from −62° C. to −185° C., and at a pressure in a range of from 20 mbara to 120 bara.

13. The process according to claim 12 , wherein the liquid or slush comprising methane is at a pressure in a range of from 250 mbara to 76 bara.

14. A process for preparing a labelled methane comprising fluid comprising methyl acetate in a range of from 1 to 250 ppm, the process comprising the following steps:
a) adding methyl acetate to a methane comprising gas;
b) adding an odorant in a range of from 1 to 100 ppm of an odorant, and in a range of from 0.1 to 10 m/m % of a carrier to methane comprising gas,
wherein the odorant and carrier are added separately and/or mixed, and
wherein the methyl acetate is added separately and/or mixed with the odorant and/or the carrier, and
wherein the carrier is propane, n-butane, iso-butane, or a mixture of two or more thereof, and
wherein the odorant is ethyl acrylate, ethyl mercaptan, or a mixture thereof; and
c) liquefying the mixture obtained in step a) to a temperature in a range of from −62° C. to −185° C. and a pressure in a range of from 20 mbara to 120 bara.

15. The process according to claim 14 , comprising the following steps:
b1) adding the odorant to the carrier, and
b2) adding at least a part of the mixture obtained in step b1) to the methane comprising gas,
wherein the methane comprising gas preferably is at a temperature in a range of from −40 to +200° C., and
adding the methyl acetate separately and/or mixed with the odorant and the carrier, and
c) liquefying the mixture obtained in step 2) to a temperature in a range of from −62° C. to −185° C. and a pressure in a range of from 20 mbara to 120 bara.

16. The process according to claim 14 , wherein the methane comprising gas is at a temperature in a range of from −25 to +85° C.

17. The process according to claim 14 , wherein the pressure in step (b) is in a range from 250 mbara to 76 bara.

Assignees

• Shell Oil Co

Inventors

• Van Der Veer Wouter Martinus
• Macdonald Stuart Meredith

Classifications

• C10L3/006 Primary

  detectable by the senses · CPC title

• C10L2290/06

  Heat exchange, direct or indirect · CPC title

• C10L2290/141

  of additive or catalyst · CPC title

• C10L2270/10

  for transport, e.g. in pipelines as a gas hydrate slurry · CPC title

• C10L1/1608

  Well defined compounds, e.g. hexane, benzene · CPC title